Construction of bis-, tris- and tetrahydrazones by addition of azoalkenes to amines and ammonia

Exhaustive Michael-type alkylations of amines and ammonia with azoalkenes (generated from α-halohydrazones) were demonstrated as an efficient approach to poly(hydrazonomethyl)amines – a novel class of polynitrogen ligands. An intramolecular cyclotrimerization of C=N bonds in tris(hydrazonomethyl)ami...

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Détails bibliographiques
Auteurs principaux: Artem N. Semakin, Aleksandr O. Kokuev, Yulia V. Nelyubina, Alexey Yu. Sukhorukov, Petr A. Zhmurov, Sema L. Ioffe, Vladimir A. Tartakovsky
Format: Article
Langue:English
Publié: Beilstein-Institut 2016-11-01
Collection:Beilstein Journal of Organic Chemistry
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Accès en ligne:https://doi.org/10.3762/bjoc.12.241