Synthesis and characterization of ZnBTC-based MOFs: effect of solvents and salt

In this work, we studied the optimization of synthetic approaches to creating structurally modified metal-organic frameworks under various synthesis conditions. We investigated the influence of the various solvents and zinc salts on the structural characteristics of the metal-organic framework based...

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Bibliographic Details
Main Authors: Maria V. Timofeeva, Andrey N. Yankin
Format: Article
Language:English
Published: Uralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina 2022-12-01
Series:Chimica Techno Acta
Subjects:
Online Access:https://journals.urfu.ru/index.php/chimtech/article/view/6331
Description
Summary:In this work, we studied the optimization of synthetic approaches to creating structurally modified metal-organic frameworks under various synthesis conditions. We investigated the influence of the various solvents and zinc salts on the structural characteristics of the metal-organic framework based on benzene-1,3,5-tricarboxylic acid (H3BTC). The results indicate that the variation of the types of both solvent and salt is a parameter affecting the crystallinity, phase purity, and morphology of the metal-organic framework. This was confirmed by comprehensive structural characterization (SEM, EDX, PXRD).
ISSN:2411-1414