Synthesis and characterization of ZnBTC-based MOFs: effect of solvents and salt
In this work, we studied the optimization of synthetic approaches to creating structurally modified metal-organic frameworks under various synthesis conditions. We investigated the influence of the various solvents and zinc salts on the structural characteristics of the metal-organic framework based...
Main Authors: | , |
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Format: | Article |
Language: | English |
Published: |
Uralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina
2022-12-01
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Series: | Chimica Techno Acta |
Subjects: | |
Online Access: | https://journals.urfu.ru/index.php/chimtech/article/view/6331 |
Summary: | In this work, we studied the optimization of synthetic approaches to creating structurally modified metal-organic frameworks under various synthesis conditions. We investigated the influence of the various solvents and zinc salts on the structural characteristics of the metal-organic framework based on benzene-1,3,5-tricarboxylic acid (H3BTC). The results indicate that the variation of the types of both solvent and salt is a parameter affecting the crystallinity, phase purity, and morphology of the metal-organic framework. This was confirmed by comprehensive structural characterization (SEM, EDX, PXRD). |
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ISSN: | 2411-1414 |