Synthesis and characterization of ZnBTC-based MOFs: effect of solvents and salt
In this work, we studied the optimization of synthetic approaches to creating structurally modified metal-organic frameworks under various synthesis conditions. We investigated the influence of the various solvents and zinc salts on the structural characteristics of the metal-organic framework based...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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Uralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina
2022-12-01
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| Series: | Chimica Techno Acta |
| Subjects: | |
| Online Access: | https://journals.urfu.ru/index.php/chimtech/article/view/6331 |
| _version_ | 1797843820090490880 |
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| author | Maria V. Timofeeva Andrey N. Yankin |
| author_facet | Maria V. Timofeeva Andrey N. Yankin |
| author_sort | Maria V. Timofeeva |
| collection | DOAJ |
| description | In this work, we studied the optimization of synthetic approaches to creating structurally modified metal-organic frameworks under various synthesis conditions. We investigated the influence of the various solvents and zinc salts on the structural characteristics of the metal-organic framework based on benzene-1,3,5-tricarboxylic acid (H3BTC). The results indicate that the variation of the types of both solvent and salt is a parameter affecting the crystallinity, phase purity, and morphology of the metal-organic framework. This was confirmed by comprehensive structural characterization (SEM, EDX, PXRD). |
| first_indexed | 2024-04-09T17:12:08Z |
| format | Article |
| id | doaj.art-06d141832fe5482d887d9e13be2d0d85 |
| institution | Directory Open Access Journal |
| issn | 2411-1414 |
| language | English |
| last_indexed | 2024-04-09T17:12:08Z |
| publishDate | 2022-12-01 |
| publisher | Uralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina |
| record_format | Article |
| series | Chimica Techno Acta |
| spelling | doaj.art-06d141832fe5482d887d9e13be2d0d852023-04-20T04:42:06ZengUralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. ElʹcinaChimica Techno Acta2411-14142022-12-0110110.15826/chimtech.2023.10.1.054737Synthesis and characterization of ZnBTC-based MOFs: effect of solvents and saltMaria V. Timofeeva0Andrey N. Yankin1ITMO UniversityITMO UniversityIn this work, we studied the optimization of synthetic approaches to creating structurally modified metal-organic frameworks under various synthesis conditions. We investigated the influence of the various solvents and zinc salts on the structural characteristics of the metal-organic framework based on benzene-1,3,5-tricarboxylic acid (H3BTC). The results indicate that the variation of the types of both solvent and salt is a parameter affecting the crystallinity, phase purity, and morphology of the metal-organic framework. This was confirmed by comprehensive structural characterization (SEM, EDX, PXRD).https://journals.urfu.ru/index.php/chimtech/article/view/6331metal-organic frameworksolvothermal synthesismof synthesistrimesic acid |
| spellingShingle | Maria V. Timofeeva Andrey N. Yankin Synthesis and characterization of ZnBTC-based MOFs: effect of solvents and salt Chimica Techno Acta metal-organic framework solvothermal synthesis mof synthesis trimesic acid |
| title | Synthesis and characterization of ZnBTC-based MOFs: effect of solvents and salt |
| title_full | Synthesis and characterization of ZnBTC-based MOFs: effect of solvents and salt |
| title_fullStr | Synthesis and characterization of ZnBTC-based MOFs: effect of solvents and salt |
| title_full_unstemmed | Synthesis and characterization of ZnBTC-based MOFs: effect of solvents and salt |
| title_short | Synthesis and characterization of ZnBTC-based MOFs: effect of solvents and salt |
| title_sort | synthesis and characterization of znbtc based mofs effect of solvents and salt |
| topic | metal-organic framework solvothermal synthesis mof synthesis trimesic acid |
| url | https://journals.urfu.ru/index.php/chimtech/article/view/6331 |
| work_keys_str_mv | AT mariavtimofeeva synthesisandcharacterizationofznbtcbasedmofseffectofsolventsandsalt AT andreynyankin synthesisandcharacterizationofznbtcbasedmofseffectofsolventsandsalt |