Synthesis, Characterization, Electrochemistry, Photoluminescence and Magnetic Properties of a Dinuclear Erbium(III)-Containing Monolacunary Dawson-Type Tungstophosphate: [{Er(H<sub>2</sub>O)(CH<sub>3</sub>COO)(P<sub>2</sub>W<sub>17</sub>O<sub>61</sub>)}<sub>2</sub>]<sup>16−</sup>
Reaction of the trilacunary Wells−Dawson anion {α-P<sub>2</sub>W<sub>15</sub>O<sub>56</sub>}<sup>12−</sup> with Er<sup>III</sup> ion in a 1 M LiOAc/HOAc buffer (pH 4.8) solution produces a dinuclear erbium(III) substituted sandwich-type str...
| Main Authors: | , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2020-09-01
|
| Series: | Molecules |
| Subjects: | |
| Online Access: | https://www.mdpi.com/1420-3049/25/18/4229 |
| _version_ | 1797553624349409280 |
|---|---|
| author | Masooma Ibrahim Ananya Baksi Yan Peng Firas Khalil Al-Zeidaneen Israël M. Mbomekallé Pedro de Oliveira Christopher E. Anson |
| author_facet | Masooma Ibrahim Ananya Baksi Yan Peng Firas Khalil Al-Zeidaneen Israël M. Mbomekallé Pedro de Oliveira Christopher E. Anson |
| author_sort | Masooma Ibrahim |
| collection | DOAJ |
| description | Reaction of the trilacunary Wells−Dawson anion {α-P<sub>2</sub>W<sub>15</sub>O<sub>56</sub>}<sup>12−</sup> with Er<sup>III</sup> ion in a 1 M LiOAc/HOAc buffer (pH 4.8) solution produces a dinuclear erbium(III) substituted sandwich-type structure [{Er(H<sub>2</sub>O)(CH<sub>3</sub>COO)(P<sub>2</sub>W<sub>17</sub>O<sub>61</sub>)}<sub>2</sub>]<sup>16−</sup> (<b>1</b>). The isolated compound was structurally characterized using single crystal and powder X-ray diffraction, FTIR spectroscopy, mass spectrometry and thermogravimetric analysis. The electrochemical, electrocatalytic, photoluminescence and magnetic properties of <b>1</b> were investigated. |
| first_indexed | 2024-03-10T16:19:12Z |
| format | Article |
| id | doaj.art-06dc824c332a49ad84fc38d559ea637f |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-03-10T16:19:12Z |
| publishDate | 2020-09-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-06dc824c332a49ad84fc38d559ea637f2023-11-20T13:47:57ZengMDPI AGMolecules1420-30492020-09-012518422910.3390/molecules25184229Synthesis, Characterization, Electrochemistry, Photoluminescence and Magnetic Properties of a Dinuclear Erbium(III)-Containing Monolacunary Dawson-Type Tungstophosphate: [{Er(H<sub>2</sub>O)(CH<sub>3</sub>COO)(P<sub>2</sub>W<sub>17</sub>O<sub>61</sub>)}<sub>2</sub>]<sup>16−</sup>Masooma Ibrahim0Ananya Baksi1Yan Peng2Firas Khalil Al-Zeidaneen3Israël M. Mbomekallé4Pedro de Oliveira5Christopher E. Anson6Institute of Nanotechnology, Karlsruhe Institute of Technology, Hermann von-Helmholtz Platz 1, 76344 Eggenstein-Leopoldshafen, GermanyInstitute of Nanotechnology, Karlsruhe Institute of Technology, Hermann von-Helmholtz Platz 1, 76344 Eggenstein-Leopoldshafen, GermanyInstitute of Inorganic Chemistry, Karlsruhe Institute of Technology, Engesserstrasse 15, 76131 Karlsruhe, GermanyInstitute of Inorganic Chemistry, Karlsruhe Institute of Technology, Engesserstrasse 15, 76131 Karlsruhe, GermanyEquipe d’Electrochimie et de Photo-électrochimie, Institut de Chimie Physique, Université Paris-Saclay, UMR 8000 CNRS, F-91405 Orsay, FranceEquipe d’Electrochimie et de Photo-électrochimie, Institut de Chimie Physique, Université Paris-Saclay, UMR 8000 CNRS, F-91405 Orsay, FranceInstitute of Inorganic Chemistry, Karlsruhe Institute of Technology, Engesserstrasse 15, 76131 Karlsruhe, GermanyReaction of the trilacunary Wells−Dawson anion {α-P<sub>2</sub>W<sub>15</sub>O<sub>56</sub>}<sup>12−</sup> with Er<sup>III</sup> ion in a 1 M LiOAc/HOAc buffer (pH 4.8) solution produces a dinuclear erbium(III) substituted sandwich-type structure [{Er(H<sub>2</sub>O)(CH<sub>3</sub>COO)(P<sub>2</sub>W<sub>17</sub>O<sub>61</sub>)}<sub>2</sub>]<sup>16−</sup> (<b>1</b>). The isolated compound was structurally characterized using single crystal and powder X-ray diffraction, FTIR spectroscopy, mass spectrometry and thermogravimetric analysis. The electrochemical, electrocatalytic, photoluminescence and magnetic properties of <b>1</b> were investigated.https://www.mdpi.com/1420-3049/25/18/4229polyoxometalatescatalysismass spectrometrymolecular magnetismelectrochemistrylanthanide |
| spellingShingle | Masooma Ibrahim Ananya Baksi Yan Peng Firas Khalil Al-Zeidaneen Israël M. Mbomekallé Pedro de Oliveira Christopher E. Anson Synthesis, Characterization, Electrochemistry, Photoluminescence and Magnetic Properties of a Dinuclear Erbium(III)-Containing Monolacunary Dawson-Type Tungstophosphate: [{Er(H<sub>2</sub>O)(CH<sub>3</sub>COO)(P<sub>2</sub>W<sub>17</sub>O<sub>61</sub>)}<sub>2</sub>]<sup>16−</sup> Molecules polyoxometalates catalysis mass spectrometry molecular magnetism electrochemistry lanthanide |
| title | Synthesis, Characterization, Electrochemistry, Photoluminescence and Magnetic Properties of a Dinuclear Erbium(III)-Containing Monolacunary Dawson-Type Tungstophosphate: [{Er(H<sub>2</sub>O)(CH<sub>3</sub>COO)(P<sub>2</sub>W<sub>17</sub>O<sub>61</sub>)}<sub>2</sub>]<sup>16−</sup> |
| title_full | Synthesis, Characterization, Electrochemistry, Photoluminescence and Magnetic Properties of a Dinuclear Erbium(III)-Containing Monolacunary Dawson-Type Tungstophosphate: [{Er(H<sub>2</sub>O)(CH<sub>3</sub>COO)(P<sub>2</sub>W<sub>17</sub>O<sub>61</sub>)}<sub>2</sub>]<sup>16−</sup> |
| title_fullStr | Synthesis, Characterization, Electrochemistry, Photoluminescence and Magnetic Properties of a Dinuclear Erbium(III)-Containing Monolacunary Dawson-Type Tungstophosphate: [{Er(H<sub>2</sub>O)(CH<sub>3</sub>COO)(P<sub>2</sub>W<sub>17</sub>O<sub>61</sub>)}<sub>2</sub>]<sup>16−</sup> |
| title_full_unstemmed | Synthesis, Characterization, Electrochemistry, Photoluminescence and Magnetic Properties of a Dinuclear Erbium(III)-Containing Monolacunary Dawson-Type Tungstophosphate: [{Er(H<sub>2</sub>O)(CH<sub>3</sub>COO)(P<sub>2</sub>W<sub>17</sub>O<sub>61</sub>)}<sub>2</sub>]<sup>16−</sup> |
| title_short | Synthesis, Characterization, Electrochemistry, Photoluminescence and Magnetic Properties of a Dinuclear Erbium(III)-Containing Monolacunary Dawson-Type Tungstophosphate: [{Er(H<sub>2</sub>O)(CH<sub>3</sub>COO)(P<sub>2</sub>W<sub>17</sub>O<sub>61</sub>)}<sub>2</sub>]<sup>16−</sup> |
| title_sort | synthesis characterization electrochemistry photoluminescence and magnetic properties of a dinuclear erbium iii containing monolacunary dawson type tungstophosphate er h sub 2 sub o ch sub 3 sub coo p sub 2 sub w sub 17 sub o sub 61 sub sub 2 sub sup 16 sup |
| topic | polyoxometalates catalysis mass spectrometry molecular magnetism electrochemistry lanthanide |
| url | https://www.mdpi.com/1420-3049/25/18/4229 |
| work_keys_str_mv | AT masoomaibrahim synthesischaracterizationelectrochemistryphotoluminescenceandmagneticpropertiesofadinuclearerbiumiiicontainingmonolacunarydawsontypetungstophosphateerhsub2subochsub3subcoopsub2subwsub17subosub61subsub2subsup16sup AT ananyabaksi synthesischaracterizationelectrochemistryphotoluminescenceandmagneticpropertiesofadinuclearerbiumiiicontainingmonolacunarydawsontypetungstophosphateerhsub2subochsub3subcoopsub2subwsub17subosub61subsub2subsup16sup AT yanpeng synthesischaracterizationelectrochemistryphotoluminescenceandmagneticpropertiesofadinuclearerbiumiiicontainingmonolacunarydawsontypetungstophosphateerhsub2subochsub3subcoopsub2subwsub17subosub61subsub2subsup16sup AT firaskhalilalzeidaneen synthesischaracterizationelectrochemistryphotoluminescenceandmagneticpropertiesofadinuclearerbiumiiicontainingmonolacunarydawsontypetungstophosphateerhsub2subochsub3subcoopsub2subwsub17subosub61subsub2subsup16sup AT israelmmbomekalle synthesischaracterizationelectrochemistryphotoluminescenceandmagneticpropertiesofadinuclearerbiumiiicontainingmonolacunarydawsontypetungstophosphateerhsub2subochsub3subcoopsub2subwsub17subosub61subsub2subsup16sup AT pedrodeoliveira synthesischaracterizationelectrochemistryphotoluminescenceandmagneticpropertiesofadinuclearerbiumiiicontainingmonolacunarydawsontypetungstophosphateerhsub2subochsub3subcoopsub2subwsub17subosub61subsub2subsup16sup AT christophereanson synthesischaracterizationelectrochemistryphotoluminescenceandmagneticpropertiesofadinuclearerbiumiiicontainingmonolacunarydawsontypetungstophosphateerhsub2subochsub3subcoopsub2subwsub17subosub61subsub2subsup16sup |