Plantain peel adsorbent: Simple preparation, and adsorption at phosphate concentrations similar to those of water sources at risk of eutrophication

There are several investigations on the use of food waste to remove contaminants by adsorption. However, a simple route, without chemical activation reagents, is needed for the development of adsorbents. The aim of this study was to develop an adsorbent from plantain peel, using a simple procedure,...

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Main Authors: Eliana Contreras-López, Eida Quispe-Mitma, Ana María Muñoz, Ricardo Yuli-Posadas, Marcelo Portuguez-Maurtua, Félix Hugo Milla Flores
Format: Article
Language:English
Published: Universidad Nacional de Trujillo 2023-05-01
Series:Scientia Agropecuaria
Subjects:
Online Access:https://revistas.unitru.edu.pe/index.php/scientiaagrop/article/view/4935
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author Eliana Contreras-López
Eida Quispe-Mitma
Ana María Muñoz
Ricardo Yuli-Posadas
Marcelo Portuguez-Maurtua
Félix Hugo Milla Flores
author_facet Eliana Contreras-López
Eida Quispe-Mitma
Ana María Muñoz
Ricardo Yuli-Posadas
Marcelo Portuguez-Maurtua
Félix Hugo Milla Flores
author_sort Eliana Contreras-López
collection DOAJ
description There are several investigations on the use of food waste to remove contaminants by adsorption. However, a simple route, without chemical activation reagents, is needed for the development of adsorbents. The aim of this study was to develop an adsorbent from plantain peel, using a simple procedure, and to evaluate its capacity to remove phosphate from aqueous solutions at phosphate concentrations similar to those of water sources at risk of eutrophication (0.30 mg/L). The simple pyrolysis method was used in an electric muffle, without chemical activation, using plantain peel as precursor. The variables evaluated were pyrolysis temperature and solution pH. The specific surface area BET, zero loading point of the developed treatments, was determined. Phosphate adsorption was studied in a batch experiment in the presence of calcium ions in solution. Phosphate adsorption was favorable at all three pyrolysis temperature levels (500, 600 and 700 °C) and two solution pH levels (pH 7 and 10). the pseudo-second order kinetic model was the best fit for the experimental data to describe the adsorption mechanism. The best fit to the experimental equilibrium data was obtained with the Langmuir isotherm model. It was found that a 1 g/L dose of the adsorbent was able to reduce 92% of phosphate in water, with a removal capacity 0.14 mg/g at pH 10 and pyrolysis temperature of 700 °C. This study lays the groundwork for future research on the use of this type of adsorbent in water treatment to facilitate access to clean water for rural populations.
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spelling doaj.art-06e35c85876549c7a70827361e30e7f72023-06-16T12:39:47ZengUniversidad Nacional de TrujilloScientia Agropecuaria2077-99172306-67412023-05-0114210.17268/sci.agropecu.2023.017Plantain peel adsorbent: Simple preparation, and adsorption at phosphate concentrations similar to those of water sources at risk of eutrophicationEliana Contreras-López0Eida Quispe-Mitma1Ana María Muñoz2Ricardo Yuli-Posadas3Marcelo Portuguez-Maurtua4Félix Hugo Milla Flores5Research Group of the Revaluation of Natural Sources and Functional Foods (REVALF), Universidad Nacional Mayor de San Marcos, Jr Puno 1002, Lima.Research Group of the Revaluation of Natural Sources and Functional Foods (REVALF), Universidad Nacional Mayor de San Marcos, Jr Puno 1002, Lima.Institute of Food Science and Nutrition, Health Nutrition Research Unit, Functional Foods and Nutraceuticals. Universidad San Ignacio de Loyola, Pachacamac Campus, Section B, Plot 1, Fundo La Carolina, Pachacamac, Lima.Research Group of the Revaluation of Natural Sources and Functional Foods (REVALF), Universidad Nacional Mayor de San Marcos, Jr Puno 1002, Lima.Water Resources Department, College of Agricultural Engineering, Universidad Nacional Agraria La Molina, Av. La Molina s/n Lima.Research Group of the Revaluation of Natural Sources and Functional Foods (REVALF), Universidad Nacional Mayor de San Marcos, Jr Puno 1002, Lima. There are several investigations on the use of food waste to remove contaminants by adsorption. However, a simple route, without chemical activation reagents, is needed for the development of adsorbents. The aim of this study was to develop an adsorbent from plantain peel, using a simple procedure, and to evaluate its capacity to remove phosphate from aqueous solutions at phosphate concentrations similar to those of water sources at risk of eutrophication (0.30 mg/L). The simple pyrolysis method was used in an electric muffle, without chemical activation, using plantain peel as precursor. The variables evaluated were pyrolysis temperature and solution pH. The specific surface area BET, zero loading point of the developed treatments, was determined. Phosphate adsorption was studied in a batch experiment in the presence of calcium ions in solution. Phosphate adsorption was favorable at all three pyrolysis temperature levels (500, 600 and 700 °C) and two solution pH levels (pH 7 and 10). the pseudo-second order kinetic model was the best fit for the experimental data to describe the adsorption mechanism. The best fit to the experimental equilibrium data was obtained with the Langmuir isotherm model. It was found that a 1 g/L dose of the adsorbent was able to reduce 92% of phosphate in water, with a removal capacity 0.14 mg/g at pH 10 and pyrolysis temperature of 700 °C. This study lays the groundwork for future research on the use of this type of adsorbent in water treatment to facilitate access to clean water for rural populations. https://revistas.unitru.edu.pe/index.php/scientiaagrop/article/view/4935Batch adsorptionKineticsFood residuesIsothermsmodeling
spellingShingle Eliana Contreras-López
Eida Quispe-Mitma
Ana María Muñoz
Ricardo Yuli-Posadas
Marcelo Portuguez-Maurtua
Félix Hugo Milla Flores
Plantain peel adsorbent: Simple preparation, and adsorption at phosphate concentrations similar to those of water sources at risk of eutrophication
Scientia Agropecuaria
Batch adsorption
Kinetics
Food residues
Isotherms
modeling
title Plantain peel adsorbent: Simple preparation, and adsorption at phosphate concentrations similar to those of water sources at risk of eutrophication
title_full Plantain peel adsorbent: Simple preparation, and adsorption at phosphate concentrations similar to those of water sources at risk of eutrophication
title_fullStr Plantain peel adsorbent: Simple preparation, and adsorption at phosphate concentrations similar to those of water sources at risk of eutrophication
title_full_unstemmed Plantain peel adsorbent: Simple preparation, and adsorption at phosphate concentrations similar to those of water sources at risk of eutrophication
title_short Plantain peel adsorbent: Simple preparation, and adsorption at phosphate concentrations similar to those of water sources at risk of eutrophication
title_sort plantain peel adsorbent simple preparation and adsorption at phosphate concentrations similar to those of water sources at risk of eutrophication
topic Batch adsorption
Kinetics
Food residues
Isotherms
modeling
url https://revistas.unitru.edu.pe/index.php/scientiaagrop/article/view/4935
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