(μ-trans-1,2-Di-4-pyridylethylene-κ2N:N′)bis[bis(N,N-diisopropyldithiocarbamato-κ2S,S′)zinc(II)]
The dinuclear title compound, [Zn2(C7H14NS2)4(C12H10N2)], is centrosymmetric about the central C=C bond. The five-coordinate Zn atom is bonded to two asymmetrically chelating dithiocarbamate ligands and a pyridine N atom to define an NS4 coordination geometry tending towards a square pyramid, with t...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809044250 |
| _version_ | 1819280132494327808 |
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| author | Hadi D. Arman Pavel Poplaukhin Edward R. T. Tiekink |
| author_facet | Hadi D. Arman Pavel Poplaukhin Edward R. T. Tiekink |
| author_sort | Hadi D. Arman |
| collection | DOAJ |
| description | The dinuclear title compound, [Zn2(C7H14NS2)4(C12H10N2)], is centrosymmetric about the central C=C bond. The five-coordinate Zn atom is bonded to two asymmetrically chelating dithiocarbamate ligands and a pyridine N atom to define an NS4 coordination geometry tending towards a square pyramid, with the N atom in the apical site. In the crystal structure, C—H...S contacts lead to supramolecular chains. |
| first_indexed | 2024-12-24T00:38:56Z |
| format | Article |
| id | doaj.art-06e545313c85415fa2118ecece2f6bcc |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T00:38:56Z |
| publishDate | 2009-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-06e545313c85415fa2118ecece2f6bcc2022-12-21T17:24:00ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-11-016511m1475m147510.1107/S1600536809044250(μ-trans-1,2-Di-4-pyridylethylene-κ2N:N′)bis[bis(N,N-diisopropyldithiocarbamato-κ2S,S′)zinc(II)]Hadi D. ArmanPavel PoplaukhinEdward R. T. TiekinkThe dinuclear title compound, [Zn2(C7H14NS2)4(C12H10N2)], is centrosymmetric about the central C=C bond. The five-coordinate Zn atom is bonded to two asymmetrically chelating dithiocarbamate ligands and a pyridine N atom to define an NS4 coordination geometry tending towards a square pyramid, with the N atom in the apical site. In the crystal structure, C—H...S contacts lead to supramolecular chains.http://scripts.iucr.org/cgi-bin/paper?S1600536809044250 |
| spellingShingle | Hadi D. Arman Pavel Poplaukhin Edward R. T. Tiekink (μ-trans-1,2-Di-4-pyridylethylene-κ2N:N′)bis[bis(N,N-diisopropyldithiocarbamato-κ2S,S′)zinc(II)] Acta Crystallographica Section E |
| title | (μ-trans-1,2-Di-4-pyridylethylene-κ2N:N′)bis[bis(N,N-diisopropyldithiocarbamato-κ2S,S′)zinc(II)] |
| title_full | (μ-trans-1,2-Di-4-pyridylethylene-κ2N:N′)bis[bis(N,N-diisopropyldithiocarbamato-κ2S,S′)zinc(II)] |
| title_fullStr | (μ-trans-1,2-Di-4-pyridylethylene-κ2N:N′)bis[bis(N,N-diisopropyldithiocarbamato-κ2S,S′)zinc(II)] |
| title_full_unstemmed | (μ-trans-1,2-Di-4-pyridylethylene-κ2N:N′)bis[bis(N,N-diisopropyldithiocarbamato-κ2S,S′)zinc(II)] |
| title_short | (μ-trans-1,2-Di-4-pyridylethylene-κ2N:N′)bis[bis(N,N-diisopropyldithiocarbamato-κ2S,S′)zinc(II)] |
| title_sort | amp 956 trans 1 2 di 4 pyridylethylene amp 954 2n n amp 8242 bis bis n n diisopropyldithiocarbamato amp 954 2s s amp 8242 zinc ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809044250 |
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