Simultaneous photo-removal of hexavalent chromium and methyl orange by fabrication of graphitic carbon nitride loaded on fibrous silica iron

Simultaneous removal of heavy metal and organic compounds by photocatalysis has gained attention due to its ability to remove multiple pollutants in a single system that provides high efficiency at low energy consumption. Graphitic carbon nitride (g-C3N4)/fibrous silica iron (FSFe) catalyst was succ...

Full description

Bibliographic Details
Main Authors: Hazril Nur Izzati Hannani, Abdullah Tuan Amran Tuan, Abd Aziz Fazilah Farhana, Fauzi Anees Ameera
Format: Article
Language:English
Published: EDP Sciences 2024-01-01
Series:E3S Web of Conferences
Online Access:https://www.e3s-conferences.org/articles/e3sconf/pdf/2024/46/e3sconf_concept2024_03002.pdf
_version_ 1797202646946283520
author Hazril Nur Izzati Hannani
Abdullah Tuan Amran Tuan
Abd Aziz Fazilah Farhana
Fauzi Anees Ameera
author_facet Hazril Nur Izzati Hannani
Abdullah Tuan Amran Tuan
Abd Aziz Fazilah Farhana
Fauzi Anees Ameera
author_sort Hazril Nur Izzati Hannani
collection DOAJ
description Simultaneous removal of heavy metal and organic compounds by photocatalysis has gained attention due to its ability to remove multiple pollutants in a single system that provides high efficiency at low energy consumption. Graphitic carbon nitride (g-C3N4)/fibrous silica iron (FSFe) catalyst was successfully synthesized via impregnation and hydrothermal methods without calcination process. The XRD, FTIR and UV-Vis DRS were used to understand the physicochemical properties such as the crystallinity, the functional group present and the band gap in both gC3N4/FSFe and FSFe photocatalysts. The band gap of the FSFe photocatalyst (1.95 eV) was reduced to 1.9 eV after the loading of g-C3N4 material. The simultaneous photo-removal of Cr (VI) and methyl orange (MO) was improved up to 38.16% and 98.08% respectively. The efficient photocatalytic activity of Cr (VI) and MO could be due to the decreased bandgap of the synthesized catalysts. Hence, the modification of FSFe photocatalyst framework with the addition of g-C3N4 offers a great opportunity for the study of simultaneous photocatalytic removal of heavy metals and organic pollutants to be expanded.
first_indexed 2024-04-24T08:06:45Z
format Article
id doaj.art-070750f35ef841049a3c86e0045b833f
institution Directory Open Access Journal
issn 2267-1242
language English
last_indexed 2024-04-24T08:06:45Z
publishDate 2024-01-01
publisher EDP Sciences
record_format Article
series E3S Web of Conferences
spelling doaj.art-070750f35ef841049a3c86e0045b833f2024-04-17T09:12:30ZengEDP SciencesE3S Web of Conferences2267-12422024-01-015160300210.1051/e3sconf/202451603002e3sconf_concept2024_03002Simultaneous photo-removal of hexavalent chromium and methyl orange by fabrication of graphitic carbon nitride loaded on fibrous silica ironHazril Nur Izzati Hannani0Abdullah Tuan Amran Tuan1Abd Aziz Fazilah Farhana2Fauzi Anees Ameera3Faculty of Chemical and Energy Engineering, Universiti Teknologi MalaysiaCentre of Hydrogen Energy, Institute of Future EnergyInstitute of Fuel Cell, Universiti Kebangsaan MalaysiaResearch Center for Biomass and Bioproduct, National Research and Innovation Agency (BRIN)Simultaneous removal of heavy metal and organic compounds by photocatalysis has gained attention due to its ability to remove multiple pollutants in a single system that provides high efficiency at low energy consumption. Graphitic carbon nitride (g-C3N4)/fibrous silica iron (FSFe) catalyst was successfully synthesized via impregnation and hydrothermal methods without calcination process. The XRD, FTIR and UV-Vis DRS were used to understand the physicochemical properties such as the crystallinity, the functional group present and the band gap in both gC3N4/FSFe and FSFe photocatalysts. The band gap of the FSFe photocatalyst (1.95 eV) was reduced to 1.9 eV after the loading of g-C3N4 material. The simultaneous photo-removal of Cr (VI) and methyl orange (MO) was improved up to 38.16% and 98.08% respectively. The efficient photocatalytic activity of Cr (VI) and MO could be due to the decreased bandgap of the synthesized catalysts. Hence, the modification of FSFe photocatalyst framework with the addition of g-C3N4 offers a great opportunity for the study of simultaneous photocatalytic removal of heavy metals and organic pollutants to be expanded.https://www.e3s-conferences.org/articles/e3sconf/pdf/2024/46/e3sconf_concept2024_03002.pdf
spellingShingle Hazril Nur Izzati Hannani
Abdullah Tuan Amran Tuan
Abd Aziz Fazilah Farhana
Fauzi Anees Ameera
Simultaneous photo-removal of hexavalent chromium and methyl orange by fabrication of graphitic carbon nitride loaded on fibrous silica iron
E3S Web of Conferences
title Simultaneous photo-removal of hexavalent chromium and methyl orange by fabrication of graphitic carbon nitride loaded on fibrous silica iron
title_full Simultaneous photo-removal of hexavalent chromium and methyl orange by fabrication of graphitic carbon nitride loaded on fibrous silica iron
title_fullStr Simultaneous photo-removal of hexavalent chromium and methyl orange by fabrication of graphitic carbon nitride loaded on fibrous silica iron
title_full_unstemmed Simultaneous photo-removal of hexavalent chromium and methyl orange by fabrication of graphitic carbon nitride loaded on fibrous silica iron
title_short Simultaneous photo-removal of hexavalent chromium and methyl orange by fabrication of graphitic carbon nitride loaded on fibrous silica iron
title_sort simultaneous photo removal of hexavalent chromium and methyl orange by fabrication of graphitic carbon nitride loaded on fibrous silica iron
url https://www.e3s-conferences.org/articles/e3sconf/pdf/2024/46/e3sconf_concept2024_03002.pdf
work_keys_str_mv AT hazrilnurizzatihannani simultaneousphotoremovalofhexavalentchromiumandmethylorangebyfabricationofgraphiticcarbonnitrideloadedonfibroussilicairon
AT abdullahtuanamrantuan simultaneousphotoremovalofhexavalentchromiumandmethylorangebyfabricationofgraphiticcarbonnitrideloadedonfibroussilicairon
AT abdazizfazilahfarhana simultaneousphotoremovalofhexavalentchromiumandmethylorangebyfabricationofgraphiticcarbonnitrideloadedonfibroussilicairon
AT fauzianeesameera simultaneousphotoremovalofhexavalentchromiumandmethylorangebyfabricationofgraphiticcarbonnitrideloadedonfibroussilicairon