Octabutylbis(μ2-2-chloro-5-nitrobenzoato)bis(2-chloro-5-nitrobenzoato)di-μ3-oxido-tetratin(IV)
The title complex, [Sn4(C4H9)8(C7H3ClNO4)4O2], is a cluster formed by a crystallographic inversion center around the central Sn2O2 ring. Both of the two independent Sn atoms are five-coordinated, with distorted trigonal–bipyramidal SnC2O3 geometries. One Sn atom is coordinated by two b...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810049317 |
| _version_ | 1818773023690326016 |
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| author | Hoong-Kun Fun Chen-Shang Choong Jia Hao Goh Sie-Tiong Ha Yip-Foo Win |
| author_facet | Hoong-Kun Fun Chen-Shang Choong Jia Hao Goh Sie-Tiong Ha Yip-Foo Win |
| author_sort | Hoong-Kun Fun |
| collection | DOAJ |
| description | The title complex, [Sn4(C4H9)8(C7H3ClNO4)4O2], is a cluster formed by a crystallographic inversion center around the central Sn2O2 ring. Both of the two independent Sn atoms are five-coordinated, with distorted trigonal–bipyramidal SnC2O3 geometries. One Sn atom is coordinated by two butyl groups, one O atom of the benzoate anion and two bridging O atoms, whereas the other Sn atom is coordinated by two butyl groups, two O atoms of the benzoate anions and a bridging O atom. The O atoms of the bridging benzoate anion are disordered over two sites with an occupancy ratio of 0.862 (12):0.138 (12). One of the butyl groups coordinated to the Sn2O2 ring is disordered over two sites with an occupancy ratio of 0.780 (8):0.220 (8), whereas both of the two butyl groups coordinated to the other Sn atom are disordered over two sites with occupancy ratios of 0.788 (5):0.212 (5) and 0.827 (10):0.173 (10). All the butyl groups are equatorial with respect to the SnO3 trigonal plane. In the crystal, complex molecules are stacked down [010] with weak intermolecular C—H...π interactions stabilizing the crystal structure. |
| first_indexed | 2024-12-18T10:18:40Z |
| format | Article |
| id | doaj.art-071a12a388024638ad5b6dc84a12e45f |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-18T10:18:40Z |
| publishDate | 2010-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-071a12a388024638ad5b6dc84a12e45f2022-12-21T21:11:11ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-12-016612m1698m169910.1107/S1600536810049317Octabutylbis(μ2-2-chloro-5-nitrobenzoato)bis(2-chloro-5-nitrobenzoato)di-μ3-oxido-tetratin(IV)Hoong-Kun FunChen-Shang ChoongJia Hao GohSie-Tiong HaYip-Foo WinThe title complex, [Sn4(C4H9)8(C7H3ClNO4)4O2], is a cluster formed by a crystallographic inversion center around the central Sn2O2 ring. Both of the two independent Sn atoms are five-coordinated, with distorted trigonal–bipyramidal SnC2O3 geometries. One Sn atom is coordinated by two butyl groups, one O atom of the benzoate anion and two bridging O atoms, whereas the other Sn atom is coordinated by two butyl groups, two O atoms of the benzoate anions and a bridging O atom. The O atoms of the bridging benzoate anion are disordered over two sites with an occupancy ratio of 0.862 (12):0.138 (12). One of the butyl groups coordinated to the Sn2O2 ring is disordered over two sites with an occupancy ratio of 0.780 (8):0.220 (8), whereas both of the two butyl groups coordinated to the other Sn atom are disordered over two sites with occupancy ratios of 0.788 (5):0.212 (5) and 0.827 (10):0.173 (10). All the butyl groups are equatorial with respect to the SnO3 trigonal plane. In the crystal, complex molecules are stacked down [010] with weak intermolecular C—H...π interactions stabilizing the crystal structure.http://scripts.iucr.org/cgi-bin/paper?S1600536810049317 |
| spellingShingle | Hoong-Kun Fun Chen-Shang Choong Jia Hao Goh Sie-Tiong Ha Yip-Foo Win Octabutylbis(μ2-2-chloro-5-nitrobenzoato)bis(2-chloro-5-nitrobenzoato)di-μ3-oxido-tetratin(IV) Acta Crystallographica Section E |
| title | Octabutylbis(μ2-2-chloro-5-nitrobenzoato)bis(2-chloro-5-nitrobenzoato)di-μ3-oxido-tetratin(IV) |
| title_full | Octabutylbis(μ2-2-chloro-5-nitrobenzoato)bis(2-chloro-5-nitrobenzoato)di-μ3-oxido-tetratin(IV) |
| title_fullStr | Octabutylbis(μ2-2-chloro-5-nitrobenzoato)bis(2-chloro-5-nitrobenzoato)di-μ3-oxido-tetratin(IV) |
| title_full_unstemmed | Octabutylbis(μ2-2-chloro-5-nitrobenzoato)bis(2-chloro-5-nitrobenzoato)di-μ3-oxido-tetratin(IV) |
| title_short | Octabutylbis(μ2-2-chloro-5-nitrobenzoato)bis(2-chloro-5-nitrobenzoato)di-μ3-oxido-tetratin(IV) |
| title_sort | octabutylbis amp 956 2 2 chloro 5 nitrobenzoato bis 2 chloro 5 nitrobenzoato di amp 956 3 oxido tetratin iv |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810049317 |
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