Semiconducting chalcogenide Ge-Se-Sb-Cu as new prospective thermoelectric materials

This work examines the electrical and thermoelectric characteristics of Ge25Se65Sb10-xCux (0 ≤ x ≤ 10 at.%) thin films within the temperature range of 300–450 K. In order to get thin films from the bulk specimens, thermal evaporation technique was employed. The electrical conductivity increases from...

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Main Author: H.H. Hegazy
Format: Article
Language:English
Published: Elsevier 2019-09-01
Series:Results in Physics
Online Access:http://www.sciencedirect.com/science/article/pii/S2211379719317814
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author H.H. Hegazy
author_facet H.H. Hegazy
author_sort H.H. Hegazy
collection DOAJ
description This work examines the electrical and thermoelectric characteristics of Ge25Se65Sb10-xCux (0 ≤ x ≤ 10 at.%) thin films within the temperature range of 300–450 K. In order to get thin films from the bulk specimens, thermal evaporation technique was employed. The electrical conductivity increases from 2.89 × 10−9 Ω−1 m−1 to 6.39 × 10−7 Ω−1 m−1 as the Cu content increases from 0 to 10 at.%. During this investigation, A p-type Ge25Se65Sb10-xCux films were considered, to keep the thermoelectric power positive throughout the temperature range. In addition to that, the dc electrical conductivity and thermoelectric power readings were taken into account to ascertain the level of free carriers presence. As the Cu content increases, the activation energy falls even though power factor; an important thermoelectric parameter, rises. The outcome of the chalcogenide glassy composition investigation revealed that it is a likely source for acquiring high action thermoelectric materials. Keywords: Electrical properties, Seebeck coefficient, Chalcogenide thin films, Thermoelectric materials
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spelling doaj.art-072fcd94ffcf4fff80122f4c912831052022-12-22T02:19:50ZengElsevierResults in Physics2211-37972019-09-0114Semiconducting chalcogenide Ge-Se-Sb-Cu as new prospective thermoelectric materialsH.H. Hegazy0Address: Department of Physics, Faculty of Science, King Khalid University, P.O. Box 9004, Abha, Saudi Arabia.; Department of Physics, Faculty of Science, King Khalid University, P.O. Box 9004, Abha, Saudi Arabia; Department of Physics, Faculty of Science, Al-Azhar University, Assiut Branch, 71524 Assiut, EgyptThis work examines the electrical and thermoelectric characteristics of Ge25Se65Sb10-xCux (0 ≤ x ≤ 10 at.%) thin films within the temperature range of 300–450 K. In order to get thin films from the bulk specimens, thermal evaporation technique was employed. The electrical conductivity increases from 2.89 × 10−9 Ω−1 m−1 to 6.39 × 10−7 Ω−1 m−1 as the Cu content increases from 0 to 10 at.%. During this investigation, A p-type Ge25Se65Sb10-xCux films were considered, to keep the thermoelectric power positive throughout the temperature range. In addition to that, the dc electrical conductivity and thermoelectric power readings were taken into account to ascertain the level of free carriers presence. As the Cu content increases, the activation energy falls even though power factor; an important thermoelectric parameter, rises. The outcome of the chalcogenide glassy composition investigation revealed that it is a likely source for acquiring high action thermoelectric materials. Keywords: Electrical properties, Seebeck coefficient, Chalcogenide thin films, Thermoelectric materialshttp://www.sciencedirect.com/science/article/pii/S2211379719317814
spellingShingle H.H. Hegazy
Semiconducting chalcogenide Ge-Se-Sb-Cu as new prospective thermoelectric materials
Results in Physics
title Semiconducting chalcogenide Ge-Se-Sb-Cu as new prospective thermoelectric materials
title_full Semiconducting chalcogenide Ge-Se-Sb-Cu as new prospective thermoelectric materials
title_fullStr Semiconducting chalcogenide Ge-Se-Sb-Cu as new prospective thermoelectric materials
title_full_unstemmed Semiconducting chalcogenide Ge-Se-Sb-Cu as new prospective thermoelectric materials
title_short Semiconducting chalcogenide Ge-Se-Sb-Cu as new prospective thermoelectric materials
title_sort semiconducting chalcogenide ge se sb cu as new prospective thermoelectric materials
url http://www.sciencedirect.com/science/article/pii/S2211379719317814
work_keys_str_mv AT hhhegazy semiconductingchalcogenidegesesbcuasnewprospectivethermoelectricmaterials