Methyl α-l-sorboside monohydrate
Methyl l-sorboside monohydrate, C7H14O6·H2O, was prepared from the rare sugar l-sorbose, C6H12O6, and crystallized. It was confirmed that methyl l-sorboside formed α-pyranose with a 2C5 conformation and crystallized with one water molecule of crystallization. In the crystal, molecules are linked by...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2021-12-01
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| Series: | IUCrData |
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314621013250 |
| _version_ | 1819283454270898176 |
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| author | Mao Matsumoto Natsumi Nagayama Ryo Hirose Kei Takeshita Tomohiko Ishii |
| author_facet | Mao Matsumoto Natsumi Nagayama Ryo Hirose Kei Takeshita Tomohiko Ishii |
| author_sort | Mao Matsumoto |
| collection | DOAJ |
| description | Methyl l-sorboside monohydrate, C7H14O6·H2O, was prepared from the rare sugar l-sorbose, C6H12O6, and crystallized. It was confirmed that methyl l-sorboside formed α-pyranose with a 2C5 conformation and crystallized with one water molecule of crystallization. In the crystal, molecules are linked by O—H...O hydrogen bonds, forming a three-dimensional network. The unit-cell volume of the title compound, methyl l-sorboside monohydrate, is 481.13 (2) Å3 (Z = 2), which is about 108.16 Å3 (29.0%) greater than that of half the amount of the chemical α-l-sorbose [745.94 (2) Å3 (Z = 4)]. |
| first_indexed | 2024-12-24T01:31:44Z |
| format | Article |
| id | doaj.art-07517756067f45a296130446e7b2d7a9 |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-12-24T01:31:44Z |
| publishDate | 2021-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-07517756067f45a296130446e7b2d7a92022-12-21T17:22:20ZengInternational Union of CrystallographyIUCrData2414-31462021-12-01612x21132510.1107/S2414314621013250bv4043Methyl α-l-sorboside monohydrateMao Matsumoto0Natsumi Nagayama1Ryo Hirose2Kei Takeshita3Tomohiko Ishii4Department of Advanced Materials Science, Graduate School of Engineering, Kagawa University, 2217-20 Hayashi-cho, Takamatsu, Kagawa 761-0396, JapanDepartment of Advanced Materials Science, Graduate School of Engineering, Kagawa University, 2217-20 Hayashi-cho, Takamatsu, Kagawa 761-0396, JapanDepartment of Advanced Materials Science, Graduate School of Engineering, Kagawa University, 2217-20 Hayashi-cho, Takamatsu, Kagawa 761-0396, JapanFushimi Pharmaceutical Co Ltd, 307 Minatomachi, Marugame, Kagawa 763-8605, JapanDepartment of Advanced Materials Science, Graduate School of Engineering, Kagawa University, 2217-20 Hayashi-cho, Takamatsu, Kagawa 761-0396, JapanMethyl l-sorboside monohydrate, C7H14O6·H2O, was prepared from the rare sugar l-sorbose, C6H12O6, and crystallized. It was confirmed that methyl l-sorboside formed α-pyranose with a 2C5 conformation and crystallized with one water molecule of crystallization. In the crystal, molecules are linked by O—H...O hydrogen bonds, forming a three-dimensional network. The unit-cell volume of the title compound, methyl l-sorboside monohydrate, is 481.13 (2) Å3 (Z = 2), which is about 108.16 Å3 (29.0%) greater than that of half the amount of the chemical α-l-sorbose [745.94 (2) Å3 (Z = 4)].http://scripts.iucr.org/cgi-bin/paper?S2414314621013250crystal structurehydrogen bondingrare sugaralkyl sorboside |
| spellingShingle | Mao Matsumoto Natsumi Nagayama Ryo Hirose Kei Takeshita Tomohiko Ishii Methyl α-l-sorboside monohydrate IUCrData crystal structure hydrogen bonding rare sugar alkyl sorboside |
| title | Methyl α-l-sorboside monohydrate |
| title_full | Methyl α-l-sorboside monohydrate |
| title_fullStr | Methyl α-l-sorboside monohydrate |
| title_full_unstemmed | Methyl α-l-sorboside monohydrate |
| title_short | Methyl α-l-sorboside monohydrate |
| title_sort | methyl α l sorboside monohydrate |
| topic | crystal structure hydrogen bonding rare sugar alkyl sorboside |
| url | http://scripts.iucr.org/cgi-bin/paper?S2414314621013250 |
| work_keys_str_mv | AT maomatsumoto methylalsorbosidemonohydrate AT natsuminagayama methylalsorbosidemonohydrate AT ryohirose methylalsorbosidemonohydrate AT keitakeshita methylalsorbosidemonohydrate AT tomohikoishii methylalsorbosidemonohydrate |