(Nitrito-κ2O,O′)bis[tris(4-methylphenyl)phosphane-κP]silver(I)
The molecular structure of the title compound, [Ag(NO2)(C21H21P)2], exhibits a pseudo-tetrahedral coordination around the central AgI atom. The compound crystallizes with one molecule in the asymmetric unit in the monoclinic space group P21/n with a rather long b axis [33.8752 (2) Å]. Weak C—H...O a...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2022-12-01
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| Series: | IUCrData |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314622011488 |
| _version_ | 1797960464760569856 |
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| author | Frederick P. Malan Kariska Potgieter Reinout Meijboom |
| author_facet | Frederick P. Malan Kariska Potgieter Reinout Meijboom |
| author_sort | Frederick P. Malan |
| collection | DOAJ |
| description | The molecular structure of the title compound, [Ag(NO2)(C21H21P)2], exhibits a pseudo-tetrahedral coordination around the central AgI atom. The compound crystallizes with one molecule in the asymmetric unit in the monoclinic space group P21/n with a rather long b axis [33.8752 (2) Å]. Weak C—H...O and C—H...N interactions consolidate the crystal packing. The nitrite-O atoms each occupy a single position in the coordination geometry. |
| first_indexed | 2024-04-11T00:45:19Z |
| format | Article |
| id | doaj.art-075b3a71652d47cab1d3fa5433a9eea0 |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-04-11T00:45:19Z |
| publishDate | 2022-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-075b3a71652d47cab1d3fa5433a9eea02023-01-05T15:20:37ZengInternational Union of CrystallographyIUCrData2414-31462022-12-01712x22114810.1107/S2414314622011488wm4174(Nitrito-κ2O,O′)bis[tris(4-methylphenyl)phosphane-κP]silver(I)Frederick P. Malan0Kariska Potgieter1Reinout Meijboom2Department of Chemistry, University of Pretoria, Lynnwood Road, Hatfield, Pretoria, 0002, South AfricaDepartment of Chemical Sciences, University of Johannesburg, PO Box 524, Auckland Park, 2006, Johannesburg, South AfricaDepartment of Chemical Sciences, University of Johannesburg, PO Box 524, Auckland Park, 2006, Johannesburg, South AfricaThe molecular structure of the title compound, [Ag(NO2)(C21H21P)2], exhibits a pseudo-tetrahedral coordination around the central AgI atom. The compound crystallizes with one molecule in the asymmetric unit in the monoclinic space group P21/n with a rather long b axis [33.8752 (2) Å]. Weak C—H...O and C—H...N interactions consolidate the crystal packing. The nitrite-O atoms each occupy a single position in the coordination geometry.http://scripts.iucr.org/cgi-bin/paper?S2414314622011488crystal structuresilver(i) complexp-tolyl phosphine |
| spellingShingle | Frederick P. Malan Kariska Potgieter Reinout Meijboom (Nitrito-κ2O,O′)bis[tris(4-methylphenyl)phosphane-κP]silver(I) IUCrData crystal structure silver(i) complex p-tolyl phosphine |
| title | (Nitrito-κ2O,O′)bis[tris(4-methylphenyl)phosphane-κP]silver(I) |
| title_full | (Nitrito-κ2O,O′)bis[tris(4-methylphenyl)phosphane-κP]silver(I) |
| title_fullStr | (Nitrito-κ2O,O′)bis[tris(4-methylphenyl)phosphane-κP]silver(I) |
| title_full_unstemmed | (Nitrito-κ2O,O′)bis[tris(4-methylphenyl)phosphane-κP]silver(I) |
| title_short | (Nitrito-κ2O,O′)bis[tris(4-methylphenyl)phosphane-κP]silver(I) |
| title_sort | nitrito κ2o o bis tris 4 methylphenyl phosphane κp silver i |
| topic | crystal structure silver(i) complex p-tolyl phosphine |
| url | http://scripts.iucr.org/cgi-bin/paper?S2414314622011488 |
| work_keys_str_mv | AT frederickpmalan nitritok2oobistris4methylphenylphosphanekpsilveri AT kariskapotgieter nitritok2oobistris4methylphenylphosphanekpsilveri AT reinoutmeijboom nitritok2oobistris4methylphenylphosphanekpsilveri |