Near Surface CO2 Triple Oxygen Isotope Composition
The isotopic composition of carbon dioxide in the atmosphere is a powerful tool for constraining its sources and sinks. In particular, the 17O oxygen anomaly [Δ17O = 1000 × ln(1 + δ17O/1000) - 0.516 × 1000 × ln(1 + δ18O/1000)], with a value > 0.5‰ produced in the middle atmosphere, provides an id...
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Springer
2016-02-01
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Series: | Terrestrial, Atmospheric and Oceanic Sciences |
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Online Access: | http://tao.cgu.org.tw/index.php/articles/archive/atmospheric-science/item/download/2080_b6015196be6a9b14c517458a540a57d6 |
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author | Sasadhar Mahata Chung-Ho Wang Sourendra Kumar Bhattacharya Mao-Chang Liang |
author_facet | Sasadhar Mahata Chung-Ho Wang Sourendra Kumar Bhattacharya Mao-Chang Liang |
author_sort | Sasadhar Mahata |
collection | DOAJ |
description | The isotopic composition of carbon dioxide in the atmosphere is a powerful tool for constraining its sources and sinks. In particular, the 17O oxygen anomaly [Δ17O = 1000 × ln(1 + δ17O/1000) - 0.516 × 1000 × ln(1 + δ18O/1000)], with a value > 0.5‰ produced in the middle atmosphere, provides an ideal tool for probing the exchange of carbon dioxide between the biosphere/hydrosphere and atmosphere. The biosphere/hydrosphere and anthropogenic emissions give values ≤ 0.3‰. Therefore, any anomaly in near surface CO2 would reflect the balance between stratospheric input and exchange with the aforementioned surface sources. We have analyzed Δ17O values of CO2 separated from air samples collected in Taipei, Taiwan, located in the western Pacific region. The obtained mean anomaly is 0.42 ± 0.14‰ (1-σ standard deviation), in good agreement with model prediction and a published decadal record. Apart from typically used δ13C and δ18O values, the Δ17O value could provide an additional tracer for constraining the carbon cycle. |
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id | doaj.art-07677e881336464a8e255b9feafabac8 |
institution | Directory Open Access Journal |
issn | 1017-0839 1017-0839 |
language | English |
last_indexed | 2024-04-13T20:01:49Z |
publishDate | 2016-02-01 |
publisher | Springer |
record_format | Article |
series | Terrestrial, Atmospheric and Oceanic Sciences |
spelling | doaj.art-07677e881336464a8e255b9feafabac82022-12-22T02:32:10ZengSpringerTerrestrial, Atmospheric and Oceanic Sciences1017-08391017-08392016-02-012719910610.3319/TAO.2015.09.16.01(A)Near Surface CO2 Triple Oxygen Isotope CompositionSasadhar MahataChung-Ho WangSourendra Kumar BhattacharyaMao-Chang LiangThe isotopic composition of carbon dioxide in the atmosphere is a powerful tool for constraining its sources and sinks. In particular, the 17O oxygen anomaly [Δ17O = 1000 × ln(1 + δ17O/1000) - 0.516 × 1000 × ln(1 + δ18O/1000)], with a value > 0.5‰ produced in the middle atmosphere, provides an ideal tool for probing the exchange of carbon dioxide between the biosphere/hydrosphere and atmosphere. The biosphere/hydrosphere and anthropogenic emissions give values ≤ 0.3‰. Therefore, any anomaly in near surface CO2 would reflect the balance between stratospheric input and exchange with the aforementioned surface sources. We have analyzed Δ17O values of CO2 separated from air samples collected in Taipei, Taiwan, located in the western Pacific region. The obtained mean anomaly is 0.42 ± 0.14‰ (1-σ standard deviation), in good agreement with model prediction and a published decadal record. Apart from typically used δ13C and δ18O values, the Δ17O value could provide an additional tracer for constraining the carbon cycle.http://tao.cgu.org.tw/index.php/articles/archive/atmospheric-science/item/download/2080_b6015196be6a9b14c517458a540a57d6Oxygen anomalyBiogeochemistryCarbon and water cycling |
spellingShingle | Sasadhar Mahata Chung-Ho Wang Sourendra Kumar Bhattacharya Mao-Chang Liang Near Surface CO2 Triple Oxygen Isotope Composition Terrestrial, Atmospheric and Oceanic Sciences Oxygen anomaly Biogeochemistry Carbon and water cycling |
title | Near Surface CO2 Triple Oxygen Isotope Composition |
title_full | Near Surface CO2 Triple Oxygen Isotope Composition |
title_fullStr | Near Surface CO2 Triple Oxygen Isotope Composition |
title_full_unstemmed | Near Surface CO2 Triple Oxygen Isotope Composition |
title_short | Near Surface CO2 Triple Oxygen Isotope Composition |
title_sort | near surface co2 triple oxygen isotope composition |
topic | Oxygen anomaly Biogeochemistry Carbon and water cycling |
url | http://tao.cgu.org.tw/index.php/articles/archive/atmospheric-science/item/download/2080_b6015196be6a9b14c517458a540a57d6 |
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