Near Surface CO2 Triple Oxygen Isotope Composition

The isotopic composition of carbon dioxide in the atmosphere is a powerful tool for constraining its sources and sinks. In particular, the 17O oxygen anomaly [Δ17O = 1000 × ln(1 + δ17O/1000) - 0.516 × 1000 × ln(1 + δ18O/1000)], with a value > 0.5‰ produced in the middle atmosphere, provides an id...

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Main Authors: Sasadhar Mahata, Chung-Ho Wang, Sourendra Kumar Bhattacharya, Mao-Chang Liang
Format: Article
Language:English
Published: Springer 2016-02-01
Series:Terrestrial, Atmospheric and Oceanic Sciences
Subjects:
Online Access:http://tao.cgu.org.tw/index.php/articles/archive/atmospheric-science/item/download/2080_b6015196be6a9b14c517458a540a57d6
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author Sasadhar Mahata
Chung-Ho Wang
Sourendra Kumar Bhattacharya
Mao-Chang Liang
author_facet Sasadhar Mahata
Chung-Ho Wang
Sourendra Kumar Bhattacharya
Mao-Chang Liang
author_sort Sasadhar Mahata
collection DOAJ
description The isotopic composition of carbon dioxide in the atmosphere is a powerful tool for constraining its sources and sinks. In particular, the 17O oxygen anomaly [Δ17O = 1000 × ln(1 + δ17O/1000) - 0.516 × 1000 × ln(1 + δ18O/1000)], with a value > 0.5‰ produced in the middle atmosphere, provides an ideal tool for probing the exchange of carbon dioxide between the biosphere/hydrosphere and atmosphere. The biosphere/hydrosphere and anthropogenic emissions give values ≤ 0.3‰. Therefore, any anomaly in near surface CO2 would reflect the balance between stratospheric input and exchange with the aforementioned surface sources. We have analyzed Δ17O values of CO2 separated from air samples collected in Taipei, Taiwan, located in the western Pacific region. The obtained mean anomaly is 0.42 ± 0.14‰ (1-σ standard deviation), in good agreement with model prediction and a published decadal record. Apart from typically used δ13C and δ18O values, the Δ17O value could provide an additional tracer for constraining the carbon cycle.
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spelling doaj.art-07677e881336464a8e255b9feafabac82022-12-22T02:32:10ZengSpringerTerrestrial, Atmospheric and Oceanic Sciences1017-08391017-08392016-02-012719910610.3319/TAO.2015.09.16.01(A)Near Surface CO2 Triple Oxygen Isotope CompositionSasadhar MahataChung-Ho WangSourendra Kumar BhattacharyaMao-Chang LiangThe isotopic composition of carbon dioxide in the atmosphere is a powerful tool for constraining its sources and sinks. In particular, the 17O oxygen anomaly [Δ17O = 1000 × ln(1 + δ17O/1000) - 0.516 × 1000 × ln(1 + δ18O/1000)], with a value > 0.5‰ produced in the middle atmosphere, provides an ideal tool for probing the exchange of carbon dioxide between the biosphere/hydrosphere and atmosphere. The biosphere/hydrosphere and anthropogenic emissions give values ≤ 0.3‰. Therefore, any anomaly in near surface CO2 would reflect the balance between stratospheric input and exchange with the aforementioned surface sources. We have analyzed Δ17O values of CO2 separated from air samples collected in Taipei, Taiwan, located in the western Pacific region. The obtained mean anomaly is 0.42 ± 0.14‰ (1-σ standard deviation), in good agreement with model prediction and a published decadal record. Apart from typically used δ13C and δ18O values, the Δ17O value could provide an additional tracer for constraining the carbon cycle.http://tao.cgu.org.tw/index.php/articles/archive/atmospheric-science/item/download/2080_b6015196be6a9b14c517458a540a57d6Oxygen anomalyBiogeochemistryCarbon and water cycling
spellingShingle Sasadhar Mahata
Chung-Ho Wang
Sourendra Kumar Bhattacharya
Mao-Chang Liang
Near Surface CO2 Triple Oxygen Isotope Composition
Terrestrial, Atmospheric and Oceanic Sciences
Oxygen anomaly
Biogeochemistry
Carbon and water cycling
title Near Surface CO2 Triple Oxygen Isotope Composition
title_full Near Surface CO2 Triple Oxygen Isotope Composition
title_fullStr Near Surface CO2 Triple Oxygen Isotope Composition
title_full_unstemmed Near Surface CO2 Triple Oxygen Isotope Composition
title_short Near Surface CO2 Triple Oxygen Isotope Composition
title_sort near surface co2 triple oxygen isotope composition
topic Oxygen anomaly
Biogeochemistry
Carbon and water cycling
url http://tao.cgu.org.tw/index.php/articles/archive/atmospheric-science/item/download/2080_b6015196be6a9b14c517458a540a57d6
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AT chunghowang nearsurfaceco2tripleoxygenisotopecomposition
AT sourendrakumarbhattacharya nearsurfaceco2tripleoxygenisotopecomposition
AT maochangliang nearsurfaceco2tripleoxygenisotopecomposition