Bis(μ-3,5-dinitrobenzoato-κ2O1:O1′)bis(μ-3,5-dinitrobenzoato)-κ3O1,O1′:O1;κ3O1:O1,O1′-bis[(3,5-dinitrobenzoato-κ2O1,O1′)(1,10-phenanthroline-κ2N,N)dysprosium(III)]
In the binuclear title complex, [Dy2(C7H3N2O6)6(C12H8N2)2], the DyIII ions exhibit a distorted monocapped square-antiprismatic geometry and are coordinated by seven O atoms of four 3,5-dinitrobenzoate (DNBA) anions and two N atoms of a phenanthroline ligand. The carboxylate groups of the DNBA anions...
| Principais autores: | , , , , |
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| Formato: | Artigo |
| Idioma: | English |
| Publicado em: |
International Union of Crystallography
2011-01-01
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| coleção: | Acta Crystallographica Section E |
| Acesso em linha: | http://scripts.iucr.org/cgi-bin/paper?S1600536810052001 |
| Resumo: | In the binuclear title complex, [Dy2(C7H3N2O6)6(C12H8N2)2], the DyIII ions exhibit a distorted monocapped square-antiprismatic geometry and are coordinated by seven O atoms of four 3,5-dinitrobenzoate (DNBA) anions and two N atoms of a phenanthroline ligand. The carboxylate groups of the DNBA anions exhibit three coordination modes: bidentate chelating, bidentate chelating–bridging and tridentate chelating–bridging. The center of the molecule is located on a crystallographic center of inversion. |
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| ISSN: | 1600-5368 |