Bis(μ-3,5-dinitrobenzoato-κ2O1:O1′)bis(μ-3,5-dinitrobenzoato)-κ3O1,O1′:O1;κ3O1:O1,O1′-bis[(3,5-dinitrobenzoato-κ2O1,O1′)(1,10-phenanthroline-κ2N,N)dysprosium(III)]
In the binuclear title complex, [Dy2(C7H3N2O6)6(C12H8N2)2], the DyIII ions exhibit a distorted monocapped square-antiprismatic geometry and are coordinated by seven O atoms of four 3,5-dinitrobenzoate (DNBA) anions and two N atoms of a phenanthroline ligand. The carboxylate groups of the DNBA anions...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-01-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810052001 |
| _version_ | 1818773023932547072 |
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| author | Gai-Qing Xi Ning Ren Da-Hai Zhang Chun-Hua Dong Juan-Juan Hao |
| author_facet | Gai-Qing Xi Ning Ren Da-Hai Zhang Chun-Hua Dong Juan-Juan Hao |
| author_sort | Gai-Qing Xi |
| collection | DOAJ |
| description | In the binuclear title complex, [Dy2(C7H3N2O6)6(C12H8N2)2], the DyIII ions exhibit a distorted monocapped square-antiprismatic geometry and are coordinated by seven O atoms of four 3,5-dinitrobenzoate (DNBA) anions and two N atoms of a phenanthroline ligand. The carboxylate groups of the DNBA anions exhibit three coordination modes: bidentate chelating, bidentate chelating–bridging and tridentate chelating–bridging. The center of the molecule is located on a crystallographic center of inversion. |
| first_indexed | 2024-12-18T10:18:40Z |
| format | Article |
| id | doaj.art-0792283c326a4699b5fc6f46d09a2e78 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-18T10:18:40Z |
| publishDate | 2011-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-0792283c326a4699b5fc6f46d09a2e782022-12-21T21:11:11ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-01-01671m102m10210.1107/S1600536810052001Bis(μ-3,5-dinitrobenzoato-κ2O1:O1′)bis(μ-3,5-dinitrobenzoato)-κ3O1,O1′:O1;κ3O1:O1,O1′-bis[(3,5-dinitrobenzoato-κ2O1,O1′)(1,10-phenanthroline-κ2N,N)dysprosium(III)]Gai-Qing XiNing RenDa-Hai ZhangChun-Hua DongJuan-Juan HaoIn the binuclear title complex, [Dy2(C7H3N2O6)6(C12H8N2)2], the DyIII ions exhibit a distorted monocapped square-antiprismatic geometry and are coordinated by seven O atoms of four 3,5-dinitrobenzoate (DNBA) anions and two N atoms of a phenanthroline ligand. The carboxylate groups of the DNBA anions exhibit three coordination modes: bidentate chelating, bidentate chelating–bridging and tridentate chelating–bridging. The center of the molecule is located on a crystallographic center of inversion.http://scripts.iucr.org/cgi-bin/paper?S1600536810052001 |
| spellingShingle | Gai-Qing Xi Ning Ren Da-Hai Zhang Chun-Hua Dong Juan-Juan Hao Bis(μ-3,5-dinitrobenzoato-κ2O1:O1′)bis(μ-3,5-dinitrobenzoato)-κ3O1,O1′:O1;κ3O1:O1,O1′-bis[(3,5-dinitrobenzoato-κ2O1,O1′)(1,10-phenanthroline-κ2N,N)dysprosium(III)] Acta Crystallographica Section E |
| title | Bis(μ-3,5-dinitrobenzoato-κ2O1:O1′)bis(μ-3,5-dinitrobenzoato)-κ3O1,O1′:O1;κ3O1:O1,O1′-bis[(3,5-dinitrobenzoato-κ2O1,O1′)(1,10-phenanthroline-κ2N,N)dysprosium(III)] |
| title_full | Bis(μ-3,5-dinitrobenzoato-κ2O1:O1′)bis(μ-3,5-dinitrobenzoato)-κ3O1,O1′:O1;κ3O1:O1,O1′-bis[(3,5-dinitrobenzoato-κ2O1,O1′)(1,10-phenanthroline-κ2N,N)dysprosium(III)] |
| title_fullStr | Bis(μ-3,5-dinitrobenzoato-κ2O1:O1′)bis(μ-3,5-dinitrobenzoato)-κ3O1,O1′:O1;κ3O1:O1,O1′-bis[(3,5-dinitrobenzoato-κ2O1,O1′)(1,10-phenanthroline-κ2N,N)dysprosium(III)] |
| title_full_unstemmed | Bis(μ-3,5-dinitrobenzoato-κ2O1:O1′)bis(μ-3,5-dinitrobenzoato)-κ3O1,O1′:O1;κ3O1:O1,O1′-bis[(3,5-dinitrobenzoato-κ2O1,O1′)(1,10-phenanthroline-κ2N,N)dysprosium(III)] |
| title_short | Bis(μ-3,5-dinitrobenzoato-κ2O1:O1′)bis(μ-3,5-dinitrobenzoato)-κ3O1,O1′:O1;κ3O1:O1,O1′-bis[(3,5-dinitrobenzoato-κ2O1,O1′)(1,10-phenanthroline-κ2N,N)dysprosium(III)] |
| title_sort | bis amp 956 3 5 dinitrobenzoato amp 954 2o1 o1 amp 8242 bis amp 956 3 5 dinitrobenzoato amp 954 3o1 o1 amp 8242 o1 amp 954 3o1 o1 o1 amp 8242 bis 3 5 dinitrobenzoato amp 954 2o1 o1 amp 8242 1 10 phenanthroline amp 954 2n n dysprosium iii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810052001 |
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