Synthesis of furans using biosynthesized Ag nanostructures as a highly effective and easily retrievable catalyst
Nano-Ag as a green heterogeneous catalyst was utilized for the synthesis of furans by the three-component reaction of phenylglyoxal, dimethyl acetylenedicarboxylate, and primary amines. The best results were obtained in the presence of 4 mol% of nano-Ag in CH2Cl2 at room temperature. The nanocatalys...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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Iranian Chemical Society
2023-01-01
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| Series: | Nanochemistry Research |
| Subjects: | |
| Online Access: | http://www.nanochemres.org/article_165688_7d5d392852bd92f7d9d90cf11192c16b.pdf |
| _version_ | 1828041846342811648 |
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| author | Yasir Waleed Abdulhameed Hossein Shahbazi-Alavi Baram Ahmed Hamah Ameen |
| author_facet | Yasir Waleed Abdulhameed Hossein Shahbazi-Alavi Baram Ahmed Hamah Ameen |
| author_sort | Yasir Waleed Abdulhameed |
| collection | DOAJ |
| description | Nano-Ag as a green heterogeneous catalyst was utilized for the synthesis of furans by the three-component reaction of phenylglyoxal, dimethyl acetylenedicarboxylate, and primary amines. The best results were obtained in the presence of 4 mol% of nano-Ag in CH2Cl2 at room temperature. The nanocatalyst was characterized by UV-VIS, FT-IR, XRD, SEM and EDS. Ag nanostructures were prepared using extract of Echium amoenum. Some of the substantial features of this method include experimental simplicity, wide range of products, excellent yields in short reaction times, reusability of the catalyst, and low catalyst loading. |
| first_indexed | 2024-04-10T17:22:16Z |
| format | Article |
| id | doaj.art-0793c4436c9f4b51a2bb08719d26dc87 |
| institution | Directory Open Access Journal |
| issn | 2538-4279 2423-818X |
| language | English |
| last_indexed | 2024-04-10T17:22:16Z |
| publishDate | 2023-01-01 |
| publisher | Iranian Chemical Society |
| record_format | Article |
| series | Nanochemistry Research |
| spelling | doaj.art-0793c4436c9f4b51a2bb08719d26dc872023-02-05T07:25:35ZengIranian Chemical SocietyNanochemistry Research2538-42792423-818X2023-01-0181233010.22036/ncr.2023.01.002165688Synthesis of furans using biosynthesized Ag nanostructures as a highly effective and easily retrievable catalystYasir Waleed Abdulhameed0Hossein Shahbazi-Alavi1Baram Ahmed Hamah Ameen2College of Languages & Human Sciences, University of Garmian Iraq.Young Researchers and Elite Club, Kashan Branch, Islamic Azad University, Kashan, Iran.Chemistry Department, College of Science, University of Sulaimani, Sulaimaniyah, Kurdistan Region of Iraq.Nano-Ag as a green heterogeneous catalyst was utilized for the synthesis of furans by the three-component reaction of phenylglyoxal, dimethyl acetylenedicarboxylate, and primary amines. The best results were obtained in the presence of 4 mol% of nano-Ag in CH2Cl2 at room temperature. The nanocatalyst was characterized by UV-VIS, FT-IR, XRD, SEM and EDS. Ag nanostructures were prepared using extract of Echium amoenum. Some of the substantial features of this method include experimental simplicity, wide range of products, excellent yields in short reaction times, reusability of the catalyst, and low catalyst loading.http://www.nanochemres.org/article_165688_7d5d392852bd92f7d9d90cf11192c16b.pdfnano-ag, one-potphenylglyoxalfurancarboxylatenanocatalyst |
| spellingShingle | Yasir Waleed Abdulhameed Hossein Shahbazi-Alavi Baram Ahmed Hamah Ameen Synthesis of furans using biosynthesized Ag nanostructures as a highly effective and easily retrievable catalyst Nanochemistry Research nano-ag, one-pot phenylglyoxal furancarboxylate nanocatalyst |
| title | Synthesis of furans using biosynthesized Ag nanostructures as a highly effective and easily retrievable catalyst |
| title_full | Synthesis of furans using biosynthesized Ag nanostructures as a highly effective and easily retrievable catalyst |
| title_fullStr | Synthesis of furans using biosynthesized Ag nanostructures as a highly effective and easily retrievable catalyst |
| title_full_unstemmed | Synthesis of furans using biosynthesized Ag nanostructures as a highly effective and easily retrievable catalyst |
| title_short | Synthesis of furans using biosynthesized Ag nanostructures as a highly effective and easily retrievable catalyst |
| title_sort | synthesis of furans using biosynthesized ag nanostructures as a highly effective and easily retrievable catalyst |
| topic | nano-ag, one-pot phenylglyoxal furancarboxylate nanocatalyst |
| url | http://www.nanochemres.org/article_165688_7d5d392852bd92f7d9d90cf11192c16b.pdf |
| work_keys_str_mv | AT yasirwaleedabdulhameed synthesisoffuransusingbiosynthesizedagnanostructuresasahighlyeffectiveandeasilyretrievablecatalyst AT hosseinshahbazialavi synthesisoffuransusingbiosynthesizedagnanostructuresasahighlyeffectiveandeasilyretrievablecatalyst AT baramahmedhamahameen synthesisoffuransusingbiosynthesizedagnanostructuresasahighlyeffectiveandeasilyretrievablecatalyst |