QUANTITATIVE CORRELATION «STRUCTURE OF ALKYNES C2H2-C9H16 – THE HEAT OF VAPORIZATION »
For series alkynes CnH2n-2 based on group additive method (which based on the first environment of atoms), one obtained 8-constant additive scheme of calculation of their physical and chemical properties. It is shown that within the accepted classification of structural elements in the molecules of...
| Main Authors: | , |
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| Format: | Article |
| Language: | Russian |
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Tver State University
2013-11-01
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| Series: | Физико-химические аспекты изучения кластеров, наноструктур и наноматериалов |
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| Online Access: | http://physchemaspects.ru/archives/2013/%D0%A4%D0%A5-2013%20%D0%93%D1%80%D0%B5%D0%B1%D0%B5%D1%88%D0%BA%D0%BE%D0%B2%20%D0%92%D0%92.pdf |
| _version_ | 1819076589994901504 |
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| author | V.V. Grebeshkov V.M. Smolyakov |
| author_facet | V.V. Grebeshkov V.M. Smolyakov |
| author_sort | V.V. Grebeshkov |
| collection | DOAJ |
| description | For series alkynes CnH2n-2 based on group additive method (which based on the first environment of atoms), one obtained 8-constant additive scheme of calculation of their physical and chemical properties. It is shown that within the accepted classification of structural elements in the molecules of alkynes demonstrate a linear relationship. According to the obtained formula, numerical calculations of the heats of vaporization at normal boiling point Hvap of alkynes C2H2-C9H16 not studied experimentally were carried out. |
| first_indexed | 2024-12-21T18:43:43Z |
| format | Article |
| id | doaj.art-07a6f915215647ab93960a148f0b83fc |
| institution | Directory Open Access Journal |
| issn | 2226-4442 2658-4360 |
| language | Russian |
| last_indexed | 2024-12-21T18:43:43Z |
| publishDate | 2013-11-01 |
| publisher | Tver State University |
| record_format | Article |
| series | Физико-химические аспекты изучения кластеров, наноструктур и наноматериалов |
| spelling | doaj.art-07a6f915215647ab93960a148f0b83fc2022-12-21T18:53:56ZrusTver State UniversityФизико-химические аспекты изучения кластеров, наноструктур и наноматериалов2226-44422658-43602013-11-0156772QUANTITATIVE CORRELATION «STRUCTURE OF ALKYNES C2H2-C9H16 – THE HEAT OF VAPORIZATION »V.V. Grebeshkov0V.M. Smolyakov1Tver State UniversityTver State UniversityFor series alkynes CnH2n-2 based on group additive method (which based on the first environment of atoms), one obtained 8-constant additive scheme of calculation of their physical and chemical properties. It is shown that within the accepted classification of structural elements in the molecules of alkynes demonstrate a linear relationship. According to the obtained formula, numerical calculations of the heats of vaporization at normal boiling point Hvap of alkynes C2H2-C9H16 not studied experimentally were carried out.http://physchemaspects.ru/archives/2013/%D0%A4%D0%A5-2013%20%D0%93%D1%80%D0%B5%D0%B1%D0%B5%D1%88%D0%BA%D0%BE%D0%B2%20%D0%92%D0%92.pdfadditive schemesalkynesthe heat of vaporizationmultiple non-bonded interactionsadditive-group method |
| spellingShingle | V.V. Grebeshkov V.M. Smolyakov QUANTITATIVE CORRELATION «STRUCTURE OF ALKYNES C2H2-C9H16 – THE HEAT OF VAPORIZATION » Физико-химические аспекты изучения кластеров, наноструктур и наноматериалов additive schemes alkynes the heat of vaporization multiple non-bonded interactions additive-group method |
| title | QUANTITATIVE CORRELATION «STRUCTURE OF ALKYNES C2H2-C9H16 – THE HEAT OF VAPORIZATION » |
| title_full | QUANTITATIVE CORRELATION «STRUCTURE OF ALKYNES C2H2-C9H16 – THE HEAT OF VAPORIZATION » |
| title_fullStr | QUANTITATIVE CORRELATION «STRUCTURE OF ALKYNES C2H2-C9H16 – THE HEAT OF VAPORIZATION » |
| title_full_unstemmed | QUANTITATIVE CORRELATION «STRUCTURE OF ALKYNES C2H2-C9H16 – THE HEAT OF VAPORIZATION » |
| title_short | QUANTITATIVE CORRELATION «STRUCTURE OF ALKYNES C2H2-C9H16 – THE HEAT OF VAPORIZATION » |
| title_sort | quantitative correlation structure of alkynes c2h2 c9h16 the heat of vaporization |
| topic | additive schemes alkynes the heat of vaporization multiple non-bonded interactions additive-group method |
| url | http://physchemaspects.ru/archives/2013/%D0%A4%D0%A5-2013%20%D0%93%D1%80%D0%B5%D0%B1%D0%B5%D1%88%D0%BA%D0%BE%D0%B2%20%D0%92%D0%92.pdf |
| work_keys_str_mv | AT vvgrebeshkov quantitativecorrelationstructureofalkynesc2h2c9h16theheatofvaporization AT vmsmolyakov quantitativecorrelationstructureofalkynesc2h2c9h16theheatofvaporization |