Bis{μ-2,2′-[1,1′-(ethane-1,2-diyldinitrilo)diethylidyne]diphenolato-κ5O,N,N′,O′:O}bis[chloridomanganese(III)]
The title compound, [Mn2(C18H18N2O2)2Cl2], was synthesized by the reaction between manganese(II) o-chlorobenzoate and the Schiff base generated in situ by the condensation of ethane-1,2-diamine and o-hydroxyacetophenone. The centrosymmetric dimer contains two Jahn–Teller-distorted manganes...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808000226 |
| _version_ | 1798031447603281920 |
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| author | Robert D. Pike T. Radhakrishnan V. S. Thampidas |
| author_facet | Robert D. Pike T. Radhakrishnan V. S. Thampidas |
| author_sort | Robert D. Pike |
| collection | DOAJ |
| description | The title compound, [Mn2(C18H18N2O2)2Cl2], was synthesized by the reaction between manganese(II) o-chlorobenzoate and the Schiff base generated in situ by the condensation of ethane-1,2-diamine and o-hydroxyacetophenone. The centrosymmetric dimer contains two Jahn–Teller-distorted manganese(III) ions, each in an octahedral geometry, connected through two phenoxy bridges from two ligands. |
| first_indexed | 2024-04-11T19:57:40Z |
| format | Article |
| id | doaj.art-07b59be854f142cabd8428642cdf2dab |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T19:57:40Z |
| publishDate | 2008-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-07b59be854f142cabd8428642cdf2dab2022-12-22T04:05:53ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-02-01642m307m30710.1107/S1600536808000226Bis{μ-2,2′-[1,1′-(ethane-1,2-diyldinitrilo)diethylidyne]diphenolato-κ5O,N,N′,O′:O}bis[chloridomanganese(III)]Robert D. PikeT. RadhakrishnanV. S. ThampidasThe title compound, [Mn2(C18H18N2O2)2Cl2], was synthesized by the reaction between manganese(II) o-chlorobenzoate and the Schiff base generated in situ by the condensation of ethane-1,2-diamine and o-hydroxyacetophenone. The centrosymmetric dimer contains two Jahn–Teller-distorted manganese(III) ions, each in an octahedral geometry, connected through two phenoxy bridges from two ligands.http://scripts.iucr.org/cgi-bin/paper?S1600536808000226 |
| spellingShingle | Robert D. Pike T. Radhakrishnan V. S. Thampidas Bis{μ-2,2′-[1,1′-(ethane-1,2-diyldinitrilo)diethylidyne]diphenolato-κ5O,N,N′,O′:O}bis[chloridomanganese(III)] Acta Crystallographica Section E |
| title | Bis{μ-2,2′-[1,1′-(ethane-1,2-diyldinitrilo)diethylidyne]diphenolato-κ5O,N,N′,O′:O}bis[chloridomanganese(III)] |
| title_full | Bis{μ-2,2′-[1,1′-(ethane-1,2-diyldinitrilo)diethylidyne]diphenolato-κ5O,N,N′,O′:O}bis[chloridomanganese(III)] |
| title_fullStr | Bis{μ-2,2′-[1,1′-(ethane-1,2-diyldinitrilo)diethylidyne]diphenolato-κ5O,N,N′,O′:O}bis[chloridomanganese(III)] |
| title_full_unstemmed | Bis{μ-2,2′-[1,1′-(ethane-1,2-diyldinitrilo)diethylidyne]diphenolato-κ5O,N,N′,O′:O}bis[chloridomanganese(III)] |
| title_short | Bis{μ-2,2′-[1,1′-(ethane-1,2-diyldinitrilo)diethylidyne]diphenolato-κ5O,N,N′,O′:O}bis[chloridomanganese(III)] |
| title_sort | bis 956 2 2 8242 1 1 8242 ethane 1 2 diyldinitrilo diethylidyne diphenolato 954 5o n n 8242 o 8242 o bis chloridomanganese iii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808000226 |
| work_keys_str_mv | AT robertdpike bis956228242118242ethane12diyldinitrilodiethylidynediphenolato9545onn8242o8242obischloridomanganeseiii AT tradhakrishnan bis956228242118242ethane12diyldinitrilodiethylidynediphenolato9545onn8242o8242obischloridomanganeseiii AT vsthampidas bis956228242118242ethane12diyldinitrilodiethylidynediphenolato9545onn8242o8242obischloridomanganeseiii |