Bis(3-acetyl-6-methyl-2-oxo-2H-pyran-4-olato)bis(dimethyl sulfoxide)nickel(II)
In the title compound, [Ni(C8H7O4)2{(CH3)2SO}2], the NiII atom is located on a crystallographic centre of symmetry and has a distorted octahedral coordination geometry of type MO6. The bidentate dehydroacetic acid (DHA) ligands occupy the equatorial plane of the complex in a trans configuration, and...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809034655 |
| _version_ | 1828854430082007040 |
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| author | Amel Djedouani Sihem Boufas Abderrahmen Bendaas Magali Allain Gilles Bouet |
| author_facet | Amel Djedouani Sihem Boufas Abderrahmen Bendaas Magali Allain Gilles Bouet |
| author_sort | Amel Djedouani |
| collection | DOAJ |
| description | In the title compound, [Ni(C8H7O4)2{(CH3)2SO}2], the NiII atom is located on a crystallographic centre of symmetry and has a distorted octahedral coordination geometry of type MO6. The bidentate dehydroacetic acid (DHA) ligands occupy the equatorial plane of the complex in a trans configuration, and the dimethyl sulfoxide (DMSO) ligands are weakly coordinated through their O atoms in the axial positions. |
| first_indexed | 2024-12-13T00:32:47Z |
| format | Article |
| id | doaj.art-07d14de0ddc34703b9072d5fcda7884a |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T00:32:47Z |
| publishDate | 2009-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-07d14de0ddc34703b9072d5fcda7884a2022-12-22T00:05:16ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-10-016510m1205m120610.1107/S1600536809034655Bis(3-acetyl-6-methyl-2-oxo-2H-pyran-4-olato)bis(dimethyl sulfoxide)nickel(II)Amel DjedouaniSihem BoufasAbderrahmen BendaasMagali AllainGilles BouetIn the title compound, [Ni(C8H7O4)2{(CH3)2SO}2], the NiII atom is located on a crystallographic centre of symmetry and has a distorted octahedral coordination geometry of type MO6. The bidentate dehydroacetic acid (DHA) ligands occupy the equatorial plane of the complex in a trans configuration, and the dimethyl sulfoxide (DMSO) ligands are weakly coordinated through their O atoms in the axial positions.http://scripts.iucr.org/cgi-bin/paper?S1600536809034655 |
| spellingShingle | Amel Djedouani Sihem Boufas Abderrahmen Bendaas Magali Allain Gilles Bouet Bis(3-acetyl-6-methyl-2-oxo-2H-pyran-4-olato)bis(dimethyl sulfoxide)nickel(II) Acta Crystallographica Section E |
| title | Bis(3-acetyl-6-methyl-2-oxo-2H-pyran-4-olato)bis(dimethyl sulfoxide)nickel(II) |
| title_full | Bis(3-acetyl-6-methyl-2-oxo-2H-pyran-4-olato)bis(dimethyl sulfoxide)nickel(II) |
| title_fullStr | Bis(3-acetyl-6-methyl-2-oxo-2H-pyran-4-olato)bis(dimethyl sulfoxide)nickel(II) |
| title_full_unstemmed | Bis(3-acetyl-6-methyl-2-oxo-2H-pyran-4-olato)bis(dimethyl sulfoxide)nickel(II) |
| title_short | Bis(3-acetyl-6-methyl-2-oxo-2H-pyran-4-olato)bis(dimethyl sulfoxide)nickel(II) |
| title_sort | bis 3 acetyl 6 methyl 2 oxo 2h pyran 4 olato bis dimethyl sulfoxide nickel ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809034655 |
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