M-type Gd2[Si2O7]
The title compound, digadolinium(III) oxidodisilicate, Gd2[Si2O7], was obtained in its M-type crystal structure after attempts to synthesize Gd5Br3[AsO3]4 as a by-product from fused silica ampoules. It crystallizes isotypically with M-type Eu2[Si2O7]. This structure consists of layers of eclipticall...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2023-08-01
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| Series: | IUCrData |
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314623006545 |
| _version_ | 1797690613716484096 |
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| author | Ralf Jules Christian Locke Thomas Schleid |
| author_facet | Ralf Jules Christian Locke Thomas Schleid |
| author_sort | Ralf Jules Christian Locke |
| collection | DOAJ |
| description | The title compound, digadolinium(III) oxidodisilicate, Gd2[Si2O7], was obtained in its M-type crystal structure after attempts to synthesize Gd5Br3[AsO3]4 as a by-product from fused silica ampoules. It crystallizes isotypically with M-type Eu2[Si2O7]. This structure consists of layers of ecliptically arranged oxidodisilicate [Si2O7]6− units separated from each other by bilayers consisting of GdIII cations. |
| first_indexed | 2024-03-12T02:01:50Z |
| format | Article |
| id | doaj.art-07f2b4fb427a4f409bf4d7783e2a0141 |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-03-12T02:01:50Z |
| publishDate | 2023-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-07f2b4fb427a4f409bf4d7783e2a01412023-09-07T10:28:54ZengInternational Union of CrystallographyIUCrData2414-31462023-08-0188x23065410.1107/S2414314623006545wm4193M-type Gd2[Si2O7]Ralf Jules Christian Locke0Thomas Schleid1Institut für Anorganische Chemie, Universität Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart, GermanyInstitut für Anorganische Chemie, Universität Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart, GermanyThe title compound, digadolinium(III) oxidodisilicate, Gd2[Si2O7], was obtained in its M-type crystal structure after attempts to synthesize Gd5Br3[AsO3]4 as a by-product from fused silica ampoules. It crystallizes isotypically with M-type Eu2[Si2O7]. This structure consists of layers of ecliptically arranged oxidodisilicate [Si2O7]6− units separated from each other by bilayers consisting of GdIII cations.http://scripts.iucr.org/cgi-bin/paper?S2414314623006545crystal structureoxidodisilicaterare-earth metalgadoliniumisotypism |
| spellingShingle | Ralf Jules Christian Locke Thomas Schleid M-type Gd2[Si2O7] IUCrData crystal structure oxidodisilicate rare-earth metal gadolinium isotypism |
| title | M-type Gd2[Si2O7] |
| title_full | M-type Gd2[Si2O7] |
| title_fullStr | M-type Gd2[Si2O7] |
| title_full_unstemmed | M-type Gd2[Si2O7] |
| title_short | M-type Gd2[Si2O7] |
| title_sort | m type gd2 si2o7 |
| topic | crystal structure oxidodisilicate rare-earth metal gadolinium isotypism |
| url | http://scripts.iucr.org/cgi-bin/paper?S2414314623006545 |
| work_keys_str_mv | AT ralfjuleschristianlocke mtypegd2si2o7 AT thomasschleid mtypegd2si2o7 |