Synthesis of hetero- and homo-multinuclear complexes with a tetracyanonickelate anion: structural characterization [Cu(bcen)Ni(CN)4]2
Two new complexes [Cu(bcen)Ni(CN)4]2 (1) and [Ni(bcen)Ni(CN)4] (2) where bcen is 4,7-diazadecanediamide, were synthesized by reaction of equimolar amounts of M(NO3)2 (M = Cu and Ni), bcen ligand and K2[Ni(CN)4]. Single-crystal X-ray diffraction analysis of compound 1, shows that the bcen ligand acts...
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| Format: | Article |
| Language: | English |
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Slovenian Chemical Society
2017-09-01
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| Series: | Acta Chimica Slovenica |
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| Online Access: | https://journals.matheo.si/index.php/ACSi/article/view/3577 |
| _version_ | 1828749100940525568 |
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| author | Rasoul Vafazadeh Amin Dehghani-Firouzabadi Anthony C. Willis |
| author_facet | Rasoul Vafazadeh Amin Dehghani-Firouzabadi Anthony C. Willis |
| author_sort | Rasoul Vafazadeh |
| collection | DOAJ |
| description | Two new complexes [Cu(bcen)Ni(CN)4]2 (1) and [Ni(bcen)Ni(CN)4] (2) where bcen is 4,7-diazadecanediamide, were synthesized by reaction of equimolar amounts of M(NO3)2 (M = Cu and Ni), bcen ligand and K2[Ni(CN)4]. Single-crystal X-ray diffraction analysis of compound 1, shows that the bcen ligand acts as a tridentate chelate, coordinating to the Cu(II) ion via the two nitrogen atoms of the amine groups and one oxygen atom of one amide group, and the other amide unit is left uncoordinated. The coordination geometry around the Cu(II) ions is five coordinate with a distorted square pyramid geometry, comprising two nitrogen atoms and one oxygen atom belonging to the bcen ligand and two nitrogen atoms of the cyano groups of two Ni(CN)42– units. The distance between the copper ion and the amide oxygen of the dangling arm of an adjacent tetranuclear species is within the expected range for an axial Cu–O bond, and hence suggests that the amide oxygen of an adjacent tetranuclear complex may weakly coordinate to the copper ion in an axial position. These contacts link the tetranuclear species into infinite chain polymers. |
| first_indexed | 2024-12-10T11:46:39Z |
| format | Article |
| id | doaj.art-081d391a65594d28934f5bf72b2d74b9 |
| institution | Directory Open Access Journal |
| issn | 1318-0207 1580-3155 |
| language | English |
| last_indexed | 2024-12-10T11:46:39Z |
| publishDate | 2017-09-01 |
| publisher | Slovenian Chemical Society |
| record_format | Article |
| series | Acta Chimica Slovenica |
| spelling | doaj.art-081d391a65594d28934f5bf72b2d74b92022-12-22T01:50:03ZengSlovenian Chemical SocietyActa Chimica Slovenica1318-02071580-31552017-09-0164368669110.17344/acsi.2017.3577495Synthesis of hetero- and homo-multinuclear complexes with a tetracyanonickelate anion: structural characterization [Cu(bcen)Ni(CN)4]2Rasoul Vafazadeh0Amin Dehghani-FirouzabadiAnthony C. WillisYazd UniversityTwo new complexes [Cu(bcen)Ni(CN)4]2 (1) and [Ni(bcen)Ni(CN)4] (2) where bcen is 4,7-diazadecanediamide, were synthesized by reaction of equimolar amounts of M(NO3)2 (M = Cu and Ni), bcen ligand and K2[Ni(CN)4]. Single-crystal X-ray diffraction analysis of compound 1, shows that the bcen ligand acts as a tridentate chelate, coordinating to the Cu(II) ion via the two nitrogen atoms of the amine groups and one oxygen atom of one amide group, and the other amide unit is left uncoordinated. The coordination geometry around the Cu(II) ions is five coordinate with a distorted square pyramid geometry, comprising two nitrogen atoms and one oxygen atom belonging to the bcen ligand and two nitrogen atoms of the cyano groups of two Ni(CN)42– units. The distance between the copper ion and the amide oxygen of the dangling arm of an adjacent tetranuclear species is within the expected range for an axial Cu–O bond, and hence suggests that the amide oxygen of an adjacent tetranuclear complex may weakly coordinate to the copper ion in an axial position. These contacts link the tetranuclear species into infinite chain polymers.https://journals.matheo.si/index.php/ACSi/article/view/3577Cyano bridgedMultinucleardiamine-diamideCrystal structuretetracyanonickelate |
| spellingShingle | Rasoul Vafazadeh Amin Dehghani-Firouzabadi Anthony C. Willis Synthesis of hetero- and homo-multinuclear complexes with a tetracyanonickelate anion: structural characterization [Cu(bcen)Ni(CN)4]2 Acta Chimica Slovenica Cyano bridged Multinuclear diamine-diamide Crystal structure tetracyanonickelate |
| title | Synthesis of hetero- and homo-multinuclear complexes with a tetracyanonickelate anion: structural characterization [Cu(bcen)Ni(CN)4]2 |
| title_full | Synthesis of hetero- and homo-multinuclear complexes with a tetracyanonickelate anion: structural characterization [Cu(bcen)Ni(CN)4]2 |
| title_fullStr | Synthesis of hetero- and homo-multinuclear complexes with a tetracyanonickelate anion: structural characterization [Cu(bcen)Ni(CN)4]2 |
| title_full_unstemmed | Synthesis of hetero- and homo-multinuclear complexes with a tetracyanonickelate anion: structural characterization [Cu(bcen)Ni(CN)4]2 |
| title_short | Synthesis of hetero- and homo-multinuclear complexes with a tetracyanonickelate anion: structural characterization [Cu(bcen)Ni(CN)4]2 |
| title_sort | synthesis of hetero and homo multinuclear complexes with a tetracyanonickelate anion structural characterization cu bcen ni cn 4 2 |
| topic | Cyano bridged Multinuclear diamine-diamide Crystal structure tetracyanonickelate |
| url | https://journals.matheo.si/index.php/ACSi/article/view/3577 |
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