Synthesis of hetero- and homo-multinuclear complexes with a tetracyanonickelate anion: structural characterization [Cu(bcen)Ni(CN)4]2
Two new complexes [Cu(bcen)Ni(CN)4]2 (1) and [Ni(bcen)Ni(CN)4] (2) where bcen is 4,7-diazadecanediamide, were synthesized by reaction of equimolar amounts of M(NO3)2 (M = Cu and Ni), bcen ligand and K2[Ni(CN)4]. Single-crystal X-ray diffraction analysis of compound 1, shows that the bcen ligand acts...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
Slovenian Chemical Society
2017-09-01
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| Series: | Acta Chimica Slovenica |
| Subjects: | |
| Online Access: | https://journals.matheo.si/index.php/ACSi/article/view/3577 |