Formation of a nonanuclear copper(II) cluster with 3,5-dimethylpyrazolate starting from an NHC complex of copper(I) chloride

Formation of a nonanuclear copper(II) cluster with 3,5-dimethylpyrazolate starting from an NHC complex of copper(I) chloride

The complete nonanuclear cluster in bis[1,3-bis(2,6-dimethylphenyl)imidazolium] di-μ-chlorido-tetrachloridooctakis(μ-3,5-dimethylpyrazolato)hexa-μ3-hydroxido-nonacopper(II) chloroform disolvate, [HIXy]2[Cu9(μ-pz*)8(μ3-OH)6(μ2-Cl)2Cl4]·2CHCl3 or (C19H21N2)2[Cu9(C5H7N2)8Cl6(OH)6]·2CHCl3, where pz* is...

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Bibliographic Details
Main Authors: Christopher A. Dodds, Alan R. Kennedy
Format: Article
Language:English
Published: International Union of Crystallography 2020-09-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
copper
n-heterocyclic carbene
cluster
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989020011275

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