Research of thermal destruction of aliphatic alcohols in pure state and dissolved in water
By the method of isothermal pressure increasing in a closed system starting temperatures (TS) of thermal decomposition of aliphatic alcohols (methanol, ethanol, 1-propanol and 1-butanol) in their water solutions depending on composition are obtained. Values of TS depending on composition (x) and num...
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| Format: | Article |
| Language: | Russian |
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MIREA - Russian Technological University
2013-12-01
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| Series: | Тонкие химические технологии |
| Subjects: | |
| Online Access: | https://www.finechem-mirea.ru/jour/article/view/509 |
| _version_ | 1797882085659115520 |
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| author | T. A. Dzhapparov A. R. Bazaev |
| author_facet | T. A. Dzhapparov A. R. Bazaev |
| author_sort | T. A. Dzhapparov |
| collection | DOAJ |
| description | By the method of isothermal pressure increasing in a closed system starting temperatures (TS) of thermal decomposition of aliphatic alcohols (methanol, ethanol, 1-propanol and 1-butanol) in their water solutions depending on composition are obtained. Values of TS depending on composition (x) and number of carbon atom (C) are described by the polynomial equation: 544.258 2 28.826 10 3 2 65.617 6.378 10 2 ( , ) 23.622 + − + ⋅ − T x N = x − x + ⋅ N N . It is shown that the rate of alcohol decomposition depends on temperature and concentration (in water-alcohol solution). To estimate rate of thermal decomposition of alcohols we used change of pressure of system in a unit of time at constant temperature and volume (closed system). Reaction rate constant was calculated by formula: dτ dp p k = 1 ⋅ , where k – reaction rate constant; p – pressure; τ – time; dp/dτ – rate of reaction. Values of kinetic and activation parameters of alcohol decomposition in the range of temperatures 583.15–663.15 К are estimated. |
| first_indexed | 2024-04-10T03:30:26Z |
| format | Article |
| id | doaj.art-083b75f1810a465f88579f68aa2b737a |
| institution | Directory Open Access Journal |
| issn | 2410-6593 2686-7575 |
| language | Russian |
| last_indexed | 2024-04-10T03:30:26Z |
| publishDate | 2013-12-01 |
| publisher | MIREA - Russian Technological University |
| record_format | Article |
| series | Тонкие химические технологии |
| spelling | doaj.art-083b75f1810a465f88579f68aa2b737a2023-03-13T07:25:34ZrusMIREA - Russian Technological UniversityТонкие химические технологии2410-65932686-75752013-12-018642461265Research of thermal destruction of aliphatic alcohols in pure state and dissolved in waterT. A. Dzhapparov0A. R. Bazaev1Институт проблем геотермии ДНЦ РАН, Махачкала, 367003Institute of Problems of Geothermy, Daghestan Scientific Center RAS, Makhachkala, 367003 Republic of DaghestanBy the method of isothermal pressure increasing in a closed system starting temperatures (TS) of thermal decomposition of aliphatic alcohols (methanol, ethanol, 1-propanol and 1-butanol) in their water solutions depending on composition are obtained. Values of TS depending on composition (x) and number of carbon atom (C) are described by the polynomial equation: 544.258 2 28.826 10 3 2 65.617 6.378 10 2 ( , ) 23.622 + − + ⋅ − T x N = x − x + ⋅ N N . It is shown that the rate of alcohol decomposition depends on temperature and concentration (in water-alcohol solution). To estimate rate of thermal decomposition of alcohols we used change of pressure of system in a unit of time at constant temperature and volume (closed system). Reaction rate constant was calculated by formula: dτ dp p k = 1 ⋅ , where k – reaction rate constant; p – pressure; τ – time; dp/dτ – rate of reaction. Values of kinetic and activation parameters of alcohol decomposition in the range of temperatures 583.15–663.15 К are estimated.https://www.finechem-mirea.ru/jour/article/view/509temperature, pressure, solutions, concentration, thermal destruction, kinetic parameters |
| spellingShingle | T. A. Dzhapparov A. R. Bazaev Research of thermal destruction of aliphatic alcohols in pure state and dissolved in water Тонкие химические технологии temperature, pressure, solutions, concentration, thermal destruction, kinetic parameters |
| title | Research of thermal destruction of aliphatic alcohols in pure state and dissolved in water |
| title_full | Research of thermal destruction of aliphatic alcohols in pure state and dissolved in water |
| title_fullStr | Research of thermal destruction of aliphatic alcohols in pure state and dissolved in water |
| title_full_unstemmed | Research of thermal destruction of aliphatic alcohols in pure state and dissolved in water |
| title_short | Research of thermal destruction of aliphatic alcohols in pure state and dissolved in water |
| title_sort | research of thermal destruction of aliphatic alcohols in pure state and dissolved in water |
| topic | temperature, pressure, solutions, concentration, thermal destruction, kinetic parameters |
| url | https://www.finechem-mirea.ru/jour/article/view/509 |
| work_keys_str_mv | AT tadzhapparov researchofthermaldestructionofaliphaticalcoholsinpurestateanddissolvedinwater AT arbazaev researchofthermaldestructionofaliphaticalcoholsinpurestateanddissolvedinwater |