COLOR STABILITY FOR WOOD PRODUCTS DURING USE: EFFECTS OF INORGANIC NANOPARTICLES

Despite significant progress having been achieved in recent years to improve wood’s durability, additional developments are still necessary to increase its color stability. ZnO and CeO2 nanoparticles were compared to UV absorbers (Tinuvin 477 DW, 292 and 5151) commonly used to stabilize the wood pro...

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Main Authors: Vincent Blanchard, Pierre Blanchet
Format: Article
Language:English
Published: North Carolina State University 2011-04-01
Series:BioResources
Subjects:
Online Access:http://www.ncsu.edu/bioresources/BioRes_06/BioRes_06_2_1219_Blanchard_B_Color_Stability_Wood_Inorg_Nanoparticles_1404.pdf
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author Vincent Blanchard
Pierre Blanchet
author_facet Vincent Blanchard
Pierre Blanchet
author_sort Vincent Blanchard
collection DOAJ
description Despite significant progress having been achieved in recent years to improve wood’s durability, additional developments are still necessary to increase its color stability. ZnO and CeO2 nanoparticles were compared to UV absorbers (Tinuvin 477 DW, 292 and 5151) commonly used to stabilize the wood products color. Nanoparticles, with concentrations in the range 1 to 2 wt%, and UV absorbers, using concentrations advised by the manufacturer, were dispersed in a waterborne UV curable polyurethane/polyacrylate resin. Dispersions were carried out with a high speed mixer at 2,500 RPM with micro glass beads or not, depending on the form of the nanoparticles. Nanocomposite coatings were aged with a weather-o-meter (CI 3000+ - Atlas) according ASTM G155. Color variations were measured with a colorimeter (BYK Gardner – Color Guide 45/0) working with the CIE L*a*b* system. The aim of the present study was to assess the effects of inorganic UV absorbers on the stabilization of color under indoor conditions. Results showed that nanoparticles (ZnO, CeO2) absorbed UV light frequencies in a manner similar to common organic molecules. Their efficiency was better at medium durations of light exposure, for which they could achieve the action of organic absorbers. Finally, the simultaneous use of both absorbers seems to create a protective synergy when degradation is due to UV energy alone.
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spelling doaj.art-084dbe73181644ae928dfffaf4ae220c2022-12-21T22:59:01ZengNorth Carolina State UniversityBioResources1930-21262011-04-016212191229COLOR STABILITY FOR WOOD PRODUCTS DURING USE: EFFECTS OF INORGANIC NANOPARTICLESVincent BlanchardPierre BlanchetDespite significant progress having been achieved in recent years to improve wood’s durability, additional developments are still necessary to increase its color stability. ZnO and CeO2 nanoparticles were compared to UV absorbers (Tinuvin 477 DW, 292 and 5151) commonly used to stabilize the wood products color. Nanoparticles, with concentrations in the range 1 to 2 wt%, and UV absorbers, using concentrations advised by the manufacturer, were dispersed in a waterborne UV curable polyurethane/polyacrylate resin. Dispersions were carried out with a high speed mixer at 2,500 RPM with micro glass beads or not, depending on the form of the nanoparticles. Nanocomposite coatings were aged with a weather-o-meter (CI 3000+ - Atlas) according ASTM G155. Color variations were measured with a colorimeter (BYK Gardner – Color Guide 45/0) working with the CIE L*a*b* system. The aim of the present study was to assess the effects of inorganic UV absorbers on the stabilization of color under indoor conditions. Results showed that nanoparticles (ZnO, CeO2) absorbed UV light frequencies in a manner similar to common organic molecules. Their efficiency was better at medium durations of light exposure, for which they could achieve the action of organic absorbers. Finally, the simultaneous use of both absorbers seems to create a protective synergy when degradation is due to UV energy alone.www.ncsu.edu/bioresources/BioRes_06/BioRes_06_2_1219_Blanchard_B_Color_Stability_Wood_Inorg_Nanoparticles_1404.pdfNanoparticlesWood colorColor stabilityPhoto-oxidationPhoto-degradationZnOCeO2Ultra-violet light
spellingShingle Vincent Blanchard
Pierre Blanchet
COLOR STABILITY FOR WOOD PRODUCTS DURING USE: EFFECTS OF INORGANIC NANOPARTICLES
BioResources
Nanoparticles
Wood color
Color stability
Photo-oxidation
Photo-degradation
ZnO
CeO2
Ultra-violet light
title COLOR STABILITY FOR WOOD PRODUCTS DURING USE: EFFECTS OF INORGANIC NANOPARTICLES
title_full COLOR STABILITY FOR WOOD PRODUCTS DURING USE: EFFECTS OF INORGANIC NANOPARTICLES
title_fullStr COLOR STABILITY FOR WOOD PRODUCTS DURING USE: EFFECTS OF INORGANIC NANOPARTICLES
title_full_unstemmed COLOR STABILITY FOR WOOD PRODUCTS DURING USE: EFFECTS OF INORGANIC NANOPARTICLES
title_short COLOR STABILITY FOR WOOD PRODUCTS DURING USE: EFFECTS OF INORGANIC NANOPARTICLES
title_sort color stability for wood products during use effects of inorganic nanoparticles
topic Nanoparticles
Wood color
Color stability
Photo-oxidation
Photo-degradation
ZnO
CeO2
Ultra-violet light
url http://www.ncsu.edu/bioresources/BioRes_06/BioRes_06_2_1219_Blanchard_B_Color_Stability_Wood_Inorg_Nanoparticles_1404.pdf
work_keys_str_mv AT vincentblanchard colorstabilityforwoodproductsduringuseeffectsofinorganicnanoparticles
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