Dimethylammonium tetraaqua(hydrogensulfato)sulfatocuprate(II)
In the title salt, [(CH3)2NH2][Cu(HSO4)(SO4)(H2O)4], one type of cation and anion is present in the asymmetric unit. The CuII atom in the complex anion, [Cu(HSO4)(SO4)(H2O)4]−, has a tetragonal bipyramidal [4 + 2] coordination caused by a Jahn–Teller distortion, with the aqua ligands in equatorial a...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2014-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536814004486 |
| Summary: | In the title salt, [(CH3)2NH2][Cu(HSO4)(SO4)(H2O)4], one type of cation and anion is present in the asymmetric unit. The CuII atom in the complex anion, [Cu(HSO4)(SO4)(H2O)4]−, has a tetragonal bipyramidal [4 + 2] coordination caused by a Jahn–Teller distortion, with the aqua ligands in equatorial and two O atoms of tetrahedral HSO4 and SO4 units in apical positions. Both types of ions form sheets parallel to (010). The interconnection within and between the sheets is reinforced by O—H...O and N—H...O hydrogen bonds, respectively, involving the water molecules, the two types of sulfate anions and the ammonium groups. |
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| ISSN: | 1600-5368 |