ZnO Nano-swirlings for Azo Dye AR183 photocatalytic degradation and antimycotic activity

Abstract The sol-gel technique was used to fabricate ZnO Nano-swirlings (ZNsw) at a predetermined agitation rate (of >> 1900 rpm), with around 21.94 gm of zinc acetate dihydrate and 0.2 g cetyltrimethylammoniumbromide (CTAB) and a cationic surfactant (drop-wise). The impact of the predetermine...

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Main Authors: Khalid Umar, Manar Fawzi Bani Mfarrej, Qazi Inamur Rahman, Mohammad Zuhaib, Amir Khan, Qamar Zia, Saeed Banawas, Hera Nadeem, Mohd. Farhan Khan, Faheem Ahmad
Format: Article
Language:English
Published: Nature Portfolio 2022-08-01
Series:Scientific Reports
Online Access:https://doi.org/10.1038/s41598-022-17924-3
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author Khalid Umar
Manar Fawzi Bani Mfarrej
Qazi Inamur Rahman
Mohammad Zuhaib
Amir Khan
Qamar Zia
Saeed Banawas
Hera Nadeem
Mohd. Farhan Khan
Faheem Ahmad
author_facet Khalid Umar
Manar Fawzi Bani Mfarrej
Qazi Inamur Rahman
Mohammad Zuhaib
Amir Khan
Qamar Zia
Saeed Banawas
Hera Nadeem
Mohd. Farhan Khan
Faheem Ahmad
author_sort Khalid Umar
collection DOAJ
description Abstract The sol-gel technique was used to fabricate ZnO Nano-swirlings (ZNsw) at a predetermined agitation rate (of >> 1900 rpm), with around 21.94 gm of zinc acetate dihydrate and 0.2 g cetyltrimethylammoniumbromide (CTAB) and a cationic surfactant (drop-wise). The impact of the predetermined agitation condition on the molecular size and morphology of ZNsw is examined, and the outcomes are dissected by useful characterization tools and techniques viz. XRD, SEM embedded with EDS, TEM, FT-IR and UV–visible. The SEM and TEM results suggest that the product formed into a big cluster of adequate ZNsw, containing a significant quantity of folded long thread-lengths. Each group indicated a fair amount of the volume of these lengths. The photocatalytic process of ZNsw was carried out as a result of the irradiation time due to the deterioration of Azo Dye AR183, resulting in approximately 79 percent dye discoloration following an 80-min UV light irradiation in the presence of ZNsw. Additionally, the synthesized ZNsw was tested for antagonistic activity, and the growth hindrance of two plant pathogenic fungal strains found. Per cent inhibition in growth of Rhizoctonia solani and Alternaria alternata were observed in response to ZNsw.
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spelling doaj.art-0865781672a04997924e1b479fb5907b2022-12-22T02:15:21ZengNature PortfolioScientific Reports2045-23222022-08-0112111110.1038/s41598-022-17924-3ZnO Nano-swirlings for Azo Dye AR183 photocatalytic degradation and antimycotic activityKhalid Umar0Manar Fawzi Bani Mfarrej1Qazi Inamur Rahman2Mohammad Zuhaib3Amir Khan4Qamar Zia5Saeed Banawas6Hera Nadeem7Mohd. Farhan Khan8Faheem Ahmad9School of Chemical Sciences, Universiti Sains MalaysiaDepartment of Life and Environmental Sciences, College of Natural and Health Sciences, Zayed UniversityDepartment of Chemistry, Integral UniversityDepartment of Agriculture, School of Sciences, Noida International UniversityDepartment of Botany, Aligarh Muslim UniversityHealth and Basic Science Research Centre, Majmaah UniversityHealth and Basic Science Research Centre, Majmaah UniversityDepartment of Botany, Aligarh Muslim UniversityDepartment of Science, Gagan College of Management and TechnologyDepartment of Botany, Aligarh Muslim UniversityAbstract The sol-gel technique was used to fabricate ZnO Nano-swirlings (ZNsw) at a predetermined agitation rate (of >> 1900 rpm), with around 21.94 gm of zinc acetate dihydrate and 0.2 g cetyltrimethylammoniumbromide (CTAB) and a cationic surfactant (drop-wise). The impact of the predetermined agitation condition on the molecular size and morphology of ZNsw is examined, and the outcomes are dissected by useful characterization tools and techniques viz. XRD, SEM embedded with EDS, TEM, FT-IR and UV–visible. The SEM and TEM results suggest that the product formed into a big cluster of adequate ZNsw, containing a significant quantity of folded long thread-lengths. Each group indicated a fair amount of the volume of these lengths. The photocatalytic process of ZNsw was carried out as a result of the irradiation time due to the deterioration of Azo Dye AR183, resulting in approximately 79 percent dye discoloration following an 80-min UV light irradiation in the presence of ZNsw. Additionally, the synthesized ZNsw was tested for antagonistic activity, and the growth hindrance of two plant pathogenic fungal strains found. Per cent inhibition in growth of Rhizoctonia solani and Alternaria alternata were observed in response to ZNsw.https://doi.org/10.1038/s41598-022-17924-3
spellingShingle Khalid Umar
Manar Fawzi Bani Mfarrej
Qazi Inamur Rahman
Mohammad Zuhaib
Amir Khan
Qamar Zia
Saeed Banawas
Hera Nadeem
Mohd. Farhan Khan
Faheem Ahmad
ZnO Nano-swirlings for Azo Dye AR183 photocatalytic degradation and antimycotic activity
Scientific Reports
title ZnO Nano-swirlings for Azo Dye AR183 photocatalytic degradation and antimycotic activity
title_full ZnO Nano-swirlings for Azo Dye AR183 photocatalytic degradation and antimycotic activity
title_fullStr ZnO Nano-swirlings for Azo Dye AR183 photocatalytic degradation and antimycotic activity
title_full_unstemmed ZnO Nano-swirlings for Azo Dye AR183 photocatalytic degradation and antimycotic activity
title_short ZnO Nano-swirlings for Azo Dye AR183 photocatalytic degradation and antimycotic activity
title_sort zno nano swirlings for azo dye ar183 photocatalytic degradation and antimycotic activity
url https://doi.org/10.1038/s41598-022-17924-3
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