Recovery of the Dye Intermediate DNDS from Aqueous Solution by Adsorption onto Resins

Four kinds of resins were investigated for the recovery of 4,4‘-dinitrostilbene-2,2’-disulphonic acid (DNDS), which is present as a pollutant in wastewater, and their adsorption behaviour and mechanisms assessed. One of the resins, YWB-38, exhibited much better adsorption properties towards DNDS tha...

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Main Authors: Wei-Ben Yang, Jun Fan, Aimin Li, Quanxing Zhang
Format: Article
Language:English
Published: SAGE Publications 2006-12-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1260/026361707781422004
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author Wei-Ben Yang
Jun Fan
Aimin Li
Quanxing Zhang
author_facet Wei-Ben Yang
Jun Fan
Aimin Li
Quanxing Zhang
author_sort Wei-Ben Yang
collection DOAJ
description Four kinds of resins were investigated for the recovery of 4,4‘-dinitrostilbene-2,2’-disulphonic acid (DNDS), which is present as a pollutant in wastewater, and their adsorption behaviour and mechanisms assessed. One of the resins, YWB-38, exhibited much better adsorption properties towards DNDS than the other two commercial acrylic ester resins XAD-7 and HP2MG. The Langmuir and Freundlich adsorption models were fitted to the experimental equilibrium data when the Langmuir model was found to provide a better fit for all resins over the temperature range studied. The investigation indicates that hydrophobic interaction provides the main mechanism in the adsorption of DNDS onto XAD-4 resin and that such interaction decreases significantly when additional methanol (10%) is added to the DNDS solutions. While the main interaction between the acrylic ester resin and adsorbate is hydrogen bonding, this can be enhanced to some extent by increasing acid concentration. Adsorption dynamics, column adsorption and desorption processes were also investigated to explore the differences in adsorption behaviour and mechanism on the polystyrene resin XAD-4 and acrylic ester resins.
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spelling doaj.art-0867f487038346958bb079868b6214642024-03-03T00:54:10ZengSAGE PublicationsAdsorption Science & Technology0263-61742048-40382006-12-012410.1260/026361707781422004Recovery of the Dye Intermediate DNDS from Aqueous Solution by Adsorption onto ResinsWei-Ben Yang0Jun Fan1Aimin Li2Quanxing Zhang3 Jiangsu Engineering & Technology Research Center for Organic Toxicant Control and Resource Reuse, Nanjing 210038, P. R. China Jiangsu Engineering & Technology Research Center for Organic Toxicant Control and Resource Reuse, Nanjing 210038, P. R. China Jiangsu Engineering & Technology Research Center for Organic Toxicant Control and Resource Reuse, Nanjing 210038, P. R. China Jiangsu Engineering & Technology Research Center for Organic Toxicant Control and Resource Reuse, Nanjing 210038, P. R. ChinaFour kinds of resins were investigated for the recovery of 4,4‘-dinitrostilbene-2,2’-disulphonic acid (DNDS), which is present as a pollutant in wastewater, and their adsorption behaviour and mechanisms assessed. One of the resins, YWB-38, exhibited much better adsorption properties towards DNDS than the other two commercial acrylic ester resins XAD-7 and HP2MG. The Langmuir and Freundlich adsorption models were fitted to the experimental equilibrium data when the Langmuir model was found to provide a better fit for all resins over the temperature range studied. The investigation indicates that hydrophobic interaction provides the main mechanism in the adsorption of DNDS onto XAD-4 resin and that such interaction decreases significantly when additional methanol (10%) is added to the DNDS solutions. While the main interaction between the acrylic ester resin and adsorbate is hydrogen bonding, this can be enhanced to some extent by increasing acid concentration. Adsorption dynamics, column adsorption and desorption processes were also investigated to explore the differences in adsorption behaviour and mechanism on the polystyrene resin XAD-4 and acrylic ester resins.https://doi.org/10.1260/026361707781422004
spellingShingle Wei-Ben Yang
Jun Fan
Aimin Li
Quanxing Zhang
Recovery of the Dye Intermediate DNDS from Aqueous Solution by Adsorption onto Resins
Adsorption Science & Technology
title Recovery of the Dye Intermediate DNDS from Aqueous Solution by Adsorption onto Resins
title_full Recovery of the Dye Intermediate DNDS from Aqueous Solution by Adsorption onto Resins
title_fullStr Recovery of the Dye Intermediate DNDS from Aqueous Solution by Adsorption onto Resins
title_full_unstemmed Recovery of the Dye Intermediate DNDS from Aqueous Solution by Adsorption onto Resins
title_short Recovery of the Dye Intermediate DNDS from Aqueous Solution by Adsorption onto Resins
title_sort recovery of the dye intermediate dnds from aqueous solution by adsorption onto resins
url https://doi.org/10.1260/026361707781422004
work_keys_str_mv AT weibenyang recoveryofthedyeintermediatedndsfromaqueoussolutionbyadsorptionontoresins
AT junfan recoveryofthedyeintermediatedndsfromaqueoussolutionbyadsorptionontoresins
AT aiminli recoveryofthedyeintermediatedndsfromaqueoussolutionbyadsorptionontoresins
AT quanxingzhang recoveryofthedyeintermediatedndsfromaqueoussolutionbyadsorptionontoresins