Effects of the Operating Ambiance and Active Layer Treatments on the Performance of Magnesium Fluoride Based Bipolar RRAM

This study investigates switching characteristics of the magnesium fluoride (MgF<sub>x</sub>)-based bipolar resistive random-access memory (RRAM) devices at different operating ambiances (open-air and vacuum). Operating ambiances alter the elemental composition of the amorphous MgF<su...

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Bibliographic Details
Main Authors: Nayan C. Das, Minjae Kim, Dong-uk Kwak, Jarnardhanan R. Rani, Sung-Min Hong, Jae-Hyung Jang
Format: Article
Language:English
Published: MDPI AG 2022-02-01
Series:Nanomaterials
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Online Access:https://www.mdpi.com/2079-4991/12/4/605
Description
Summary:This study investigates switching characteristics of the magnesium fluoride (MgF<sub>x</sub>)-based bipolar resistive random-access memory (RRAM) devices at different operating ambiances (open-air and vacuum). Operating ambiances alter the elemental composition of the amorphous MgF<sub>x</sub> active layer and Ti/MgF<sub>x</sub> interface region, which affects the overall device performance. The experimental results indicate that filament type resistive switching takes place at the interface of Ti/MgF<sub>x</sub> and trap-controlled space charge limited conduction (SCLC) mechanisms is dominant in both the low and high resistance states in the bulk MgF<sub>x</sub> layer. RRAM device performances at different operating ambiances are also altered by MgF<sub>x</sub> active layer treatments (air exposure and annealing). Devices show the better uniformity, stability, and a higher on/off current ratio in vacuum compared to an open-air environment. The Ti/MgF<sub>x</sub>/Pt memory devices have great potential for future vacuum electronic applications.
ISSN:2079-4991