Effects of the Operating Ambiance and Active Layer Treatments on the Performance of Magnesium Fluoride Based Bipolar RRAM

This study investigates switching characteristics of the magnesium fluoride (MgF<sub>x</sub>)-based bipolar resistive random-access memory (RRAM) devices at different operating ambiances (open-air and vacuum). Operating ambiances alter the elemental composition of the amorphous MgF<su...

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Main Authors: Nayan C. Das, Minjae Kim, Dong-uk Kwak, Jarnardhanan R. Rani, Sung-Min Hong, Jae-Hyung Jang
Format: Article
Language:English
Published: MDPI AG 2022-02-01
Series:Nanomaterials
Subjects:
Online Access:https://www.mdpi.com/2079-4991/12/4/605
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author Nayan C. Das
Minjae Kim
Dong-uk Kwak
Jarnardhanan R. Rani
Sung-Min Hong
Jae-Hyung Jang
author_facet Nayan C. Das
Minjae Kim
Dong-uk Kwak
Jarnardhanan R. Rani
Sung-Min Hong
Jae-Hyung Jang
author_sort Nayan C. Das
collection DOAJ
description This study investigates switching characteristics of the magnesium fluoride (MgF<sub>x</sub>)-based bipolar resistive random-access memory (RRAM) devices at different operating ambiances (open-air and vacuum). Operating ambiances alter the elemental composition of the amorphous MgF<sub>x</sub> active layer and Ti/MgF<sub>x</sub> interface region, which affects the overall device performance. The experimental results indicate that filament type resistive switching takes place at the interface of Ti/MgF<sub>x</sub> and trap-controlled space charge limited conduction (SCLC) mechanisms is dominant in both the low and high resistance states in the bulk MgF<sub>x</sub> layer. RRAM device performances at different operating ambiances are also altered by MgF<sub>x</sub> active layer treatments (air exposure and annealing). Devices show the better uniformity, stability, and a higher on/off current ratio in vacuum compared to an open-air environment. The Ti/MgF<sub>x</sub>/Pt memory devices have great potential for future vacuum electronic applications.
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spelling doaj.art-0868fcf64a3545aeb5bde48d28c652b82023-11-23T21:25:12ZengMDPI AGNanomaterials2079-49912022-02-0112460510.3390/nano12040605Effects of the Operating Ambiance and Active Layer Treatments on the Performance of Magnesium Fluoride Based Bipolar RRAMNayan C. Das0Minjae Kim1Dong-uk Kwak2Jarnardhanan R. Rani3Sung-Min Hong4Jae-Hyung Jang5School of Electrical Engineering and Computer Science, Gwangju Institute of Science and Technology, Gwangju 61005, KoreaSchool of Electrical Engineering and Computer Science, Gwangju Institute of Science and Technology, Gwangju 61005, KoreaSchool of Electrical Engineering and Computer Science, Gwangju Institute of Science and Technology, Gwangju 61005, KoreaSchool of Electrical Engineering and Computer Science, Gwangju Institute of Science and Technology, Gwangju 61005, KoreaSchool of Electrical Engineering and Computer Science, Gwangju Institute of Science and Technology, Gwangju 61005, KoreaSchool of Energy Engineering, Korea Institute of Energy Technology, Naju 58330, KoreaThis study investigates switching characteristics of the magnesium fluoride (MgF<sub>x</sub>)-based bipolar resistive random-access memory (RRAM) devices at different operating ambiances (open-air and vacuum). Operating ambiances alter the elemental composition of the amorphous MgF<sub>x</sub> active layer and Ti/MgF<sub>x</sub> interface region, which affects the overall device performance. The experimental results indicate that filament type resistive switching takes place at the interface of Ti/MgF<sub>x</sub> and trap-controlled space charge limited conduction (SCLC) mechanisms is dominant in both the low and high resistance states in the bulk MgF<sub>x</sub> layer. RRAM device performances at different operating ambiances are also altered by MgF<sub>x</sub> active layer treatments (air exposure and annealing). Devices show the better uniformity, stability, and a higher on/off current ratio in vacuum compared to an open-air environment. The Ti/MgF<sub>x</sub>/Pt memory devices have great potential for future vacuum electronic applications.https://www.mdpi.com/2079-4991/12/4/605bipolaroperating environmentannealingfilament type resistive switchingRRAM
spellingShingle Nayan C. Das
Minjae Kim
Dong-uk Kwak
Jarnardhanan R. Rani
Sung-Min Hong
Jae-Hyung Jang
Effects of the Operating Ambiance and Active Layer Treatments on the Performance of Magnesium Fluoride Based Bipolar RRAM
Nanomaterials
bipolar
operating environment
annealing
filament type resistive switching
RRAM
title Effects of the Operating Ambiance and Active Layer Treatments on the Performance of Magnesium Fluoride Based Bipolar RRAM
title_full Effects of the Operating Ambiance and Active Layer Treatments on the Performance of Magnesium Fluoride Based Bipolar RRAM
title_fullStr Effects of the Operating Ambiance and Active Layer Treatments on the Performance of Magnesium Fluoride Based Bipolar RRAM
title_full_unstemmed Effects of the Operating Ambiance and Active Layer Treatments on the Performance of Magnesium Fluoride Based Bipolar RRAM
title_short Effects of the Operating Ambiance and Active Layer Treatments on the Performance of Magnesium Fluoride Based Bipolar RRAM
title_sort effects of the operating ambiance and active layer treatments on the performance of magnesium fluoride based bipolar rram
topic bipolar
operating environment
annealing
filament type resistive switching
RRAM
url https://www.mdpi.com/2079-4991/12/4/605
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