Effects of Different Types of Clays and Maleic Anhydride Modified Polystyrene on Polystyrene/Clay Nanocomposites

Polymer/clay nanocomposites are considered as a new subject of research in Iran and the world. Addition of a minimum amount of clay (2-5wt%) can improve the mechanical properties, enhance barrier properties and reduce flammability dramatically. Polystyrene (PS) exhibits high strength, high modulus a...

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Main Authors: M. Mehrabzadeh, M.R. Kamal
Format: Article
Language:fas
Published: Iran Polymer and Petrochemical Institute 2013-01-01
Series:علوم و تکنولوژی پلیمر
Subjects:
Online Access:http://jips.ippi.ac.ir/article_632_f0c4757cb5002b93c20c86d92c55242c.pdf
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author M. Mehrabzadeh
M.R. Kamal
author_facet M. Mehrabzadeh
M.R. Kamal
author_sort M. Mehrabzadeh
collection DOAJ
description Polymer/clay nanocomposites are considered as a new subject of research in Iran and the world. Addition of a minimum amount of clay (2-5wt%) can improve the mechanical properties, enhance barrier properties and reduce flammability dramatically. Polystyrene (PS) exhibits high strength, high modulus and excellent dimensional stability, but it has poor ductility, elongation, and flexural modulus. By incorporating clay into polystyrene these properties can be improved. In this study preparation of polystyrene/clay nanocomposite, effects of different types of clays (Cloisite 10A andNanomer I.30TC) and maleic anhydride modified polystyrene on mechanical properties of the prepared polystyrene/clay nanocomposites were evaluated. Samples were prepared by a twin screw extruder. Transmission electron microscopy (TEM) and X-ray diffraction (XRD) techniques were employed to evaluate the extent of intercalation and exfoliation of silicate layers in the nanocomposites. Mechanical tests show that by addition of clay and maleic anhydride modified polystyrene the flexural modulus (~30%) and elongation-at-break (~40%) of prepared nanocomposites have been improved. XRD and TEM results show that nanocomposite have an intercalated structure with ability to change to further exfoliation structure.
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spelling doaj.art-0876f7c1fe6e4a9eb64079c6fef849472022-12-21T18:40:02ZfasIran Polymer and Petrochemical Instituteعلوم و تکنولوژی پلیمر1016-32552008-08832013-01-0122215115710.22063/jipst.2013.632632Effects of Different Types of Clays and Maleic Anhydride Modified Polystyrene on Polystyrene/Clay NanocompositesM. MehrabzadehM.R. KamalPolymer/clay nanocomposites are considered as a new subject of research in Iran and the world. Addition of a minimum amount of clay (2-5wt%) can improve the mechanical properties, enhance barrier properties and reduce flammability dramatically. Polystyrene (PS) exhibits high strength, high modulus and excellent dimensional stability, but it has poor ductility, elongation, and flexural modulus. By incorporating clay into polystyrene these properties can be improved. In this study preparation of polystyrene/clay nanocomposite, effects of different types of clays (Cloisite 10A andNanomer I.30TC) and maleic anhydride modified polystyrene on mechanical properties of the prepared polystyrene/clay nanocomposites were evaluated. Samples were prepared by a twin screw extruder. Transmission electron microscopy (TEM) and X-ray diffraction (XRD) techniques were employed to evaluate the extent of intercalation and exfoliation of silicate layers in the nanocomposites. Mechanical tests show that by addition of clay and maleic anhydride modified polystyrene the flexural modulus (~30%) and elongation-at-break (~40%) of prepared nanocomposites have been improved. XRD and TEM results show that nanocomposite have an intercalated structure with ability to change to further exfoliation structure.http://jips.ippi.ac.ir/article_632_f0c4757cb5002b93c20c86d92c55242c.pdfnanocompositepolystyrenemodified polystyreneclayexfoliation
spellingShingle M. Mehrabzadeh
M.R. Kamal
Effects of Different Types of Clays and Maleic Anhydride Modified Polystyrene on Polystyrene/Clay Nanocomposites
علوم و تکنولوژی پلیمر
nanocomposite
polystyrene
modified polystyrene
clay
exfoliation
title Effects of Different Types of Clays and Maleic Anhydride Modified Polystyrene on Polystyrene/Clay Nanocomposites
title_full Effects of Different Types of Clays and Maleic Anhydride Modified Polystyrene on Polystyrene/Clay Nanocomposites
title_fullStr Effects of Different Types of Clays and Maleic Anhydride Modified Polystyrene on Polystyrene/Clay Nanocomposites
title_full_unstemmed Effects of Different Types of Clays and Maleic Anhydride Modified Polystyrene on Polystyrene/Clay Nanocomposites
title_short Effects of Different Types of Clays and Maleic Anhydride Modified Polystyrene on Polystyrene/Clay Nanocomposites
title_sort effects of different types of clays and maleic anhydride modified polystyrene on polystyrene clay nanocomposites
topic nanocomposite
polystyrene
modified polystyrene
clay
exfoliation
url http://jips.ippi.ac.ir/article_632_f0c4757cb5002b93c20c86d92c55242c.pdf
work_keys_str_mv AT mmehrabzadeh effectsofdifferenttypesofclaysandmaleicanhydridemodifiedpolystyreneonpolystyreneclaynanocomposites
AT mrkamal effectsofdifferenttypesofclaysandmaleicanhydridemodifiedpolystyreneonpolystyreneclaynanocomposites