Influence of pH and ionic strength on the floc-magnetic separation: Selective flocculation of fine iron ore

This study proposes the application of floc-magnetic separation to enhance the recovery of fine iron (Fe) ores from the Musan mine. The X-ray diffraction analysis revealed the predominant composition of raw samples to be magnetite (Fe3O4) and quartz (SiO2). Conventional magnetic separation indicated...

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Main Authors: Junhyun Choi, Sang Bae Kim
Format: Article
Language:English
Published: Elsevier 2023-12-01
Series:Results in Engineering
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2590123023005686
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author Junhyun Choi
Sang Bae Kim
author_facet Junhyun Choi
Sang Bae Kim
author_sort Junhyun Choi
collection DOAJ
description This study proposes the application of floc-magnetic separation to enhance the recovery of fine iron (Fe) ores from the Musan mine. The X-ray diffraction analysis revealed the predominant composition of raw samples to be magnetite (Fe3O4) and quartz (SiO2). Conventional magnetic separation indicated an increasing efficiency of Fe separation with increasing magnetic intensity. However, this method exhibited shortcomings in effectively separating fine particles. Consequently, supplementary floc-magnetic separation was undertaken. The introduction of sodium oleate and kerosene as flocculants increased the efficiency of Fe separation. This enhancement was attributed to the alteration of the hydrophobic surface properties of fine iron particles, leading to the formation of larger aggregates that could be readily separated. Furthermore, floc-magnetic separation was performed in the presence of salt solutions. The heightened ionic strength facilitated the aggregation of iron fine particles by compressing the electrical double layer around them. This reduction in the energy barrier between iron fine particles and flocculants facilitated a more favorable interaction in the presence of salt solutions than in their absence. The experimental findings indicate that the floc-magnetic separation method reinforced by the addition of flocculants and salt solutions demonstrates enhanced efficiency in separating iron minerals from raw ores. This is particularly notable for addressing the challenge posed by fine particles that remained unresolved in conventional magnetic separation processes.
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spelling doaj.art-087b1bb734bf4b38b0dc6d598d7737d82023-12-20T07:35:43ZengElsevierResults in Engineering2590-12302023-12-0120101441Influence of pH and ionic strength on the floc-magnetic separation: Selective flocculation of fine iron oreJunhyun Choi0Sang Bae Kim1Korea Institute of Geoscience and Mineral Resources (KIGAM), 124, Gwahak-ro, Yuseong-gu, Daejeon, 34132, Republic of KoreaCorresponding author.; Korea Institute of Geoscience and Mineral Resources (KIGAM), 124, Gwahak-ro, Yuseong-gu, Daejeon, 34132, Republic of KoreaThis study proposes the application of floc-magnetic separation to enhance the recovery of fine iron (Fe) ores from the Musan mine. The X-ray diffraction analysis revealed the predominant composition of raw samples to be magnetite (Fe3O4) and quartz (SiO2). Conventional magnetic separation indicated an increasing efficiency of Fe separation with increasing magnetic intensity. However, this method exhibited shortcomings in effectively separating fine particles. Consequently, supplementary floc-magnetic separation was undertaken. The introduction of sodium oleate and kerosene as flocculants increased the efficiency of Fe separation. This enhancement was attributed to the alteration of the hydrophobic surface properties of fine iron particles, leading to the formation of larger aggregates that could be readily separated. Furthermore, floc-magnetic separation was performed in the presence of salt solutions. The heightened ionic strength facilitated the aggregation of iron fine particles by compressing the electrical double layer around them. This reduction in the energy barrier between iron fine particles and flocculants facilitated a more favorable interaction in the presence of salt solutions than in their absence. The experimental findings indicate that the floc-magnetic separation method reinforced by the addition of flocculants and salt solutions demonstrates enhanced efficiency in separating iron minerals from raw ores. This is particularly notable for addressing the challenge posed by fine particles that remained unresolved in conventional magnetic separation processes.http://www.sciencedirect.com/science/article/pii/S2590123023005686Conventional magnetic separationFloc-magnetic separationFlocculantsHigh ionic strength
spellingShingle Junhyun Choi
Sang Bae Kim
Influence of pH and ionic strength on the floc-magnetic separation: Selective flocculation of fine iron ore
Results in Engineering
Conventional magnetic separation
Floc-magnetic separation
Flocculants
High ionic strength
title Influence of pH and ionic strength on the floc-magnetic separation: Selective flocculation of fine iron ore
title_full Influence of pH and ionic strength on the floc-magnetic separation: Selective flocculation of fine iron ore
title_fullStr Influence of pH and ionic strength on the floc-magnetic separation: Selective flocculation of fine iron ore
title_full_unstemmed Influence of pH and ionic strength on the floc-magnetic separation: Selective flocculation of fine iron ore
title_short Influence of pH and ionic strength on the floc-magnetic separation: Selective flocculation of fine iron ore
title_sort influence of ph and ionic strength on the floc magnetic separation selective flocculation of fine iron ore
topic Conventional magnetic separation
Floc-magnetic separation
Flocculants
High ionic strength
url http://www.sciencedirect.com/science/article/pii/S2590123023005686
work_keys_str_mv AT junhyunchoi influenceofphandionicstrengthontheflocmagneticseparationselectiveflocculationoffineironore
AT sangbaekim influenceofphandionicstrengthontheflocmagneticseparationselectiveflocculationoffineironore