Pore Filling Effect of Forced Carbonation Reactions Using Carbon Dioxide Nanobubbles

Various methods for repairing and modifying concrete surfaces have been proposed and applied to improve the durability of existing concrete structures. Surface modification through forced carbonation is a method of densification that forms calcium carbonate in the pores on the surface of concrete to...

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Main Authors: Jihoon Kim, Ryoma Kitagaki, Heesup Choi
Format: Article
Language:English
Published: MDPI AG 2020-09-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/13/19/4343
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author Jihoon Kim
Ryoma Kitagaki
Heesup Choi
author_facet Jihoon Kim
Ryoma Kitagaki
Heesup Choi
author_sort Jihoon Kim
collection DOAJ
description Various methods for repairing and modifying concrete surfaces have been proposed and applied to improve the durability of existing concrete structures. Surface modification through forced carbonation is a method of densification that forms calcium carbonate in the pores on the surface of concrete to improve its durability. In this study, to evaluate the applicability of this surface modification method to existing buildings, a series of experiments was conducted in which mortar specimens were repeatedly immersed in a carbon dioxide nanobubble aqueous solution. By evaluating the weight change and absorption rate, it was determined that the higher the water/cement ratio of the mortar specimen, the higher the pore filling effect owing to immersion in the carbon dioxide nanobubble aqueous solution. In addition, the effect of clogged pores generated by the precipitation of calcium carbonate was confirmed, and it was found that the higher the water/cement ratio of the mortar specimen, the higher the pore filling effect due to clogging. We believe that our findings contribute to the development of research and construction practices associated with concrete repair and restoration.
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spelling doaj.art-087cacf80d8c4d52ae8dc954995518792023-11-20T15:34:14ZengMDPI AGMaterials1996-19442020-09-011319434310.3390/ma13194343Pore Filling Effect of Forced Carbonation Reactions Using Carbon Dioxide NanobubblesJihoon Kim0Ryoma Kitagaki1Heesup Choi2Department of Civil Engineering and Architecture, Muroran Institute of Technology, Hokkaido 0508585, JapanDivision of Human Environmental System, Hokkaido University, Hokkaido 0600808, JapanDepartment of Civil and Environmental Engineering, Kitami Institute of Technology, Hokkaido 0908507, JapanVarious methods for repairing and modifying concrete surfaces have been proposed and applied to improve the durability of existing concrete structures. Surface modification through forced carbonation is a method of densification that forms calcium carbonate in the pores on the surface of concrete to improve its durability. In this study, to evaluate the applicability of this surface modification method to existing buildings, a series of experiments was conducted in which mortar specimens were repeatedly immersed in a carbon dioxide nanobubble aqueous solution. By evaluating the weight change and absorption rate, it was determined that the higher the water/cement ratio of the mortar specimen, the higher the pore filling effect owing to immersion in the carbon dioxide nanobubble aqueous solution. In addition, the effect of clogged pores generated by the precipitation of calcium carbonate was confirmed, and it was found that the higher the water/cement ratio of the mortar specimen, the higher the pore filling effect due to clogging. We believe that our findings contribute to the development of research and construction practices associated with concrete repair and restoration.https://www.mdpi.com/1996-1944/13/19/4343cementitious materialsnanosized ultrafine CO<sub>2</sub> bubbleCaCO<sub>3</sub>forced carbonationsurface modification
spellingShingle Jihoon Kim
Ryoma Kitagaki
Heesup Choi
Pore Filling Effect of Forced Carbonation Reactions Using Carbon Dioxide Nanobubbles
Materials
cementitious materials
nanosized ultrafine CO<sub>2</sub> bubble
CaCO<sub>3</sub>
forced carbonation
surface modification
title Pore Filling Effect of Forced Carbonation Reactions Using Carbon Dioxide Nanobubbles
title_full Pore Filling Effect of Forced Carbonation Reactions Using Carbon Dioxide Nanobubbles
title_fullStr Pore Filling Effect of Forced Carbonation Reactions Using Carbon Dioxide Nanobubbles
title_full_unstemmed Pore Filling Effect of Forced Carbonation Reactions Using Carbon Dioxide Nanobubbles
title_short Pore Filling Effect of Forced Carbonation Reactions Using Carbon Dioxide Nanobubbles
title_sort pore filling effect of forced carbonation reactions using carbon dioxide nanobubbles
topic cementitious materials
nanosized ultrafine CO<sub>2</sub> bubble
CaCO<sub>3</sub>
forced carbonation
surface modification
url https://www.mdpi.com/1996-1944/13/19/4343
work_keys_str_mv AT jihoonkim porefillingeffectofforcedcarbonationreactionsusingcarbondioxidenanobubbles
AT ryomakitagaki porefillingeffectofforcedcarbonationreactionsusingcarbondioxidenanobubbles
AT heesupchoi porefillingeffectofforcedcarbonationreactionsusingcarbondioxidenanobubbles