Catalytic properties of Al13TM4 complex intermetallics: influence of the transition metal and the surface orientation on butadiene hydrogenation

Catalytic properties of Al13TM4 complex intermetallics: influence of the transition metal and the surface orientation on butadiene hydrogenation

Complex intermetallic compounds such as transition metal (TM) aluminides are promising alternatives to expensive Pd-based catalysts, in particular for the semi-hydrogenation of alkynes or alkadienes. Here, we compare the gas-phase butadiene hydrogenation performances of o-Al13Co4(100), m-Al13Fe4(010...

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Bibliographic Details
Main Authors: Laurent Piccolo, Corentin Chatelier, Marie-Cécile De Weerd, Franck Morfin, Julian Ledieu, Vincent Fournée, Peter Gille, Emilie Gaudry
Format: Article
Language:English
Published: Taylor & Francis Group 2019-12-01
Series:Science and Technology of Advanced Materials
Subjects:
complex intermetallic compounds
al13fe4
al13co4
al13ru4
heterogeneous catalysis
hydrogenation
butadiene
density functional theory
single-crystal surfaces
Online Access:http://dx.doi.org/10.1080/14686996.2019.1608792

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