(1R,2R)-N,N′-Bis(ferrocenylmethyl)-1,2-diphenylethane-1,2-diamine
The title compound, [Fe2(C5H5)2(C26H26N2)], was synthesized from a chiral diamine and ferrocenecarboxaldehyde and subsequent reduction with NaBH4. It has two chiral centers which both exhibit an R configuration. Two ferrocene groups are present in the molecular structure, with their cyclopentadienyl...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-08-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810024293 |
| _version_ | 1819279755919228928 |
|---|---|
| author | Yi Guo Jianfeng Wang Chixiao Zhang Shuping Luo |
| author_facet | Yi Guo Jianfeng Wang Chixiao Zhang Shuping Luo |
| author_sort | Yi Guo |
| collection | DOAJ |
| description | The title compound, [Fe2(C5H5)2(C26H26N2)], was synthesized from a chiral diamine and ferrocenecarboxaldehyde and subsequent reduction with NaBH4. It has two chiral centers which both exhibit an R configuration. Two ferrocene groups are present in the molecular structure, with their cyclopentadienyl ring planes showing an almost perpendicular arrangement [dihedral angle 88.6 (1)°]. |
| first_indexed | 2024-12-24T00:32:57Z |
| format | Article |
| id | doaj.art-088f6546e8ec48679788ec062589df8c |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T00:32:57Z |
| publishDate | 2010-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-088f6546e8ec48679788ec062589df8c2022-12-21T17:24:12ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-08-01668m989m98910.1107/S1600536810024293(1R,2R)-N,N′-Bis(ferrocenylmethyl)-1,2-diphenylethane-1,2-diamineYi GuoJianfeng WangChixiao ZhangShuping LuoThe title compound, [Fe2(C5H5)2(C26H26N2)], was synthesized from a chiral diamine and ferrocenecarboxaldehyde and subsequent reduction with NaBH4. It has two chiral centers which both exhibit an R configuration. Two ferrocene groups are present in the molecular structure, with their cyclopentadienyl ring planes showing an almost perpendicular arrangement [dihedral angle 88.6 (1)°].http://scripts.iucr.org/cgi-bin/paper?S1600536810024293 |
| spellingShingle | Yi Guo Jianfeng Wang Chixiao Zhang Shuping Luo (1R,2R)-N,N′-Bis(ferrocenylmethyl)-1,2-diphenylethane-1,2-diamine Acta Crystallographica Section E |
| title | (1R,2R)-N,N′-Bis(ferrocenylmethyl)-1,2-diphenylethane-1,2-diamine |
| title_full | (1R,2R)-N,N′-Bis(ferrocenylmethyl)-1,2-diphenylethane-1,2-diamine |
| title_fullStr | (1R,2R)-N,N′-Bis(ferrocenylmethyl)-1,2-diphenylethane-1,2-diamine |
| title_full_unstemmed | (1R,2R)-N,N′-Bis(ferrocenylmethyl)-1,2-diphenylethane-1,2-diamine |
| title_short | (1R,2R)-N,N′-Bis(ferrocenylmethyl)-1,2-diphenylethane-1,2-diamine |
| title_sort | 1r 2r n n amp 8242 bis ferrocenylmethyl 1 2 diphenylethane 1 2 diamine |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810024293 |
| work_keys_str_mv | AT yiguo 1r2rnnamp8242bisferrocenylmethyl12diphenylethane12diamine AT jianfengwang 1r2rnnamp8242bisferrocenylmethyl12diphenylethane12diamine AT chixiaozhang 1r2rnnamp8242bisferrocenylmethyl12diphenylethane12diamine AT shupingluo 1r2rnnamp8242bisferrocenylmethyl12diphenylethane12diamine |