Chlorido[1-(pyridin-2-yl)ethanone oximato-κ2N,N′][1-(2-pyridyl)ethanone oxime-κ2N,N′]copper(II) trihydrate
In the title compound, [Cu(C7H7N2O)Cl(C7H8N2O)]·3H2O, the metal ion is five-coordinated by the N atoms from the 1-(pyridin-2-yl)ethanone oximate and 1-(pyridin-2-yl)ethanone oxime ligands and by the chloride anion in a distorted square-pyramidal geometry. The distortion parameter is 0.1...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811049129 |
| _version_ | 1818997425352736768 |
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| author | Xiumin Qiu Leilei Li Dacheng Li |
| author_facet | Xiumin Qiu Leilei Li Dacheng Li |
| author_sort | Xiumin Qiu |
| collection | DOAJ |
| description | In the title compound, [Cu(C7H7N2O)Cl(C7H8N2O)]·3H2O, the metal ion is five-coordinated by the N atoms from the 1-(pyridin-2-yl)ethanone oximate and 1-(pyridin-2-yl)ethanone oxime ligands and by the chloride anion in a distorted square-pyramidal geometry. The distortion parameter is 0.192. The two organic ligands are linked by an intramolecular O—H...O hydrogen bond. In the crystal, molecules are linked by O—H...O and O—H...Cl hydrogen bonds. The title compound is the hydrated form of a previously reported structure [Wu & Wu (2008). Acta Cryst. E64, m828]. There are only slight variations in the molecular geometries of the two compounds. |
| first_indexed | 2024-12-20T21:45:26Z |
| format | Article |
| id | doaj.art-0898fa8e43bf4454913ab2630df054e2 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T21:45:26Z |
| publishDate | 2011-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-0898fa8e43bf4454913ab2630df054e22022-12-21T19:25:41ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-12-016712m1810m181110.1107/S1600536811049129Chlorido[1-(pyridin-2-yl)ethanone oximato-κ2N,N′][1-(2-pyridyl)ethanone oxime-κ2N,N′]copper(II) trihydrateXiumin QiuLeilei LiDacheng LiIn the title compound, [Cu(C7H7N2O)Cl(C7H8N2O)]·3H2O, the metal ion is five-coordinated by the N atoms from the 1-(pyridin-2-yl)ethanone oximate and 1-(pyridin-2-yl)ethanone oxime ligands and by the chloride anion in a distorted square-pyramidal geometry. The distortion parameter is 0.192. The two organic ligands are linked by an intramolecular O—H...O hydrogen bond. In the crystal, molecules are linked by O—H...O and O—H...Cl hydrogen bonds. The title compound is the hydrated form of a previously reported structure [Wu & Wu (2008). Acta Cryst. E64, m828]. There are only slight variations in the molecular geometries of the two compounds.http://scripts.iucr.org/cgi-bin/paper?S1600536811049129 |
| spellingShingle | Xiumin Qiu Leilei Li Dacheng Li Chlorido[1-(pyridin-2-yl)ethanone oximato-κ2N,N′][1-(2-pyridyl)ethanone oxime-κ2N,N′]copper(II) trihydrate Acta Crystallographica Section E |
| title | Chlorido[1-(pyridin-2-yl)ethanone oximato-κ2N,N′][1-(2-pyridyl)ethanone oxime-κ2N,N′]copper(II) trihydrate |
| title_full | Chlorido[1-(pyridin-2-yl)ethanone oximato-κ2N,N′][1-(2-pyridyl)ethanone oxime-κ2N,N′]copper(II) trihydrate |
| title_fullStr | Chlorido[1-(pyridin-2-yl)ethanone oximato-κ2N,N′][1-(2-pyridyl)ethanone oxime-κ2N,N′]copper(II) trihydrate |
| title_full_unstemmed | Chlorido[1-(pyridin-2-yl)ethanone oximato-κ2N,N′][1-(2-pyridyl)ethanone oxime-κ2N,N′]copper(II) trihydrate |
| title_short | Chlorido[1-(pyridin-2-yl)ethanone oximato-κ2N,N′][1-(2-pyridyl)ethanone oxime-κ2N,N′]copper(II) trihydrate |
| title_sort | chlorido 1 pyridin 2 yl ethanone oximato amp 954 2n n amp 8242 1 2 pyridyl ethanone oxime amp 954 2n n amp 8242 copper ii trihydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811049129 |
| work_keys_str_mv | AT xiuminqiu chlorido1pyridin2ylethanoneoximatoamp9542nnamp824212pyridylethanoneoximeamp9542nnamp8242copperiitrihydrate AT leileili chlorido1pyridin2ylethanoneoximatoamp9542nnamp824212pyridylethanoneoximeamp9542nnamp8242copperiitrihydrate AT dachengli chlorido1pyridin2ylethanoneoximatoamp9542nnamp824212pyridylethanoneoximeamp9542nnamp8242copperiitrihydrate |