The influence of phthalocyanine aggregation in complexes with CdSe/ZnS quantum dots on the photophysical properties of the complexes

The formation of nonluminescent aggregates of aluminium sulfonated phthalocyanine in complexes with CdSe/ZnS quantum dots causes a decrease of the intracomplex energy transfer efficiency with increasing phthalocyanine concentration. This was confirmed by steady-state absorption and photoluminescent...

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Main Authors: Irina V. Martynenko, Anna O. Orlova, Vladimir G. Maslov, Anatoly V. Fedorov, Kevin Berwick, Alexander V. Baranov
Format: Article
Language:English
Published: Beilstein-Institut 2016-07-01
Series:Beilstein Journal of Nanotechnology
Subjects:
Online Access:https://doi.org/10.3762/bjnano.7.94
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author Irina V. Martynenko
Anna O. Orlova
Vladimir G. Maslov
Anatoly V. Fedorov
Kevin Berwick
Alexander V. Baranov
author_facet Irina V. Martynenko
Anna O. Orlova
Vladimir G. Maslov
Anatoly V. Fedorov
Kevin Berwick
Alexander V. Baranov
author_sort Irina V. Martynenko
collection DOAJ
description The formation of nonluminescent aggregates of aluminium sulfonated phthalocyanine in complexes with CdSe/ZnS quantum dots causes a decrease of the intracomplex energy transfer efficiency with increasing phthalocyanine concentration. This was confirmed by steady-state absorption and photoluminescent spectroscopy. A corresponding physical model was developed that describes well the experimental data. The results can be used at designing of QD/molecule systems with the desired spatial arrangement for photodynamic therapy.
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spelling doaj.art-08a05eabbc2945dab5ed3fa9567f60f52022-12-22T00:50:42ZengBeilstein-InstitutBeilstein Journal of Nanotechnology2190-42862016-07-01711018102710.3762/bjnano.7.942190-4286-7-94The influence of phthalocyanine aggregation in complexes with CdSe/ZnS quantum dots on the photophysical properties of the complexesIrina V. Martynenko0Anna O. Orlova1Vladimir G. Maslov2Anatoly V. Fedorov3Kevin Berwick4Alexander V. Baranov5Department of optical physics and modern natural science, ITMO University, 197101 Saint Petersburg, RussiaDepartment of optical physics and modern natural science, ITMO University, 197101 Saint Petersburg, RussiaDepartment of optical physics and modern natural science, ITMO University, 197101 Saint Petersburg, RussiaDepartment of optical physics and modern natural science, ITMO University, 197101 Saint Petersburg, RussiaDepartment of Electronic and Communications Engineering, Dublin Institute of Technology, Dublin 8, IrelandDepartment of optical physics and modern natural science, ITMO University, 197101 Saint Petersburg, RussiaThe formation of nonluminescent aggregates of aluminium sulfonated phthalocyanine in complexes with CdSe/ZnS quantum dots causes a decrease of the intracomplex energy transfer efficiency with increasing phthalocyanine concentration. This was confirmed by steady-state absorption and photoluminescent spectroscopy. A corresponding physical model was developed that describes well the experimental data. The results can be used at designing of QD/molecule systems with the desired spatial arrangement for photodynamic therapy.https://doi.org/10.3762/bjnano.7.94aggregationFörster resonance energy transferphotosensitizersemiconductor nanocrystalstetrapyrroles
spellingShingle Irina V. Martynenko
Anna O. Orlova
Vladimir G. Maslov
Anatoly V. Fedorov
Kevin Berwick
Alexander V. Baranov
The influence of phthalocyanine aggregation in complexes with CdSe/ZnS quantum dots on the photophysical properties of the complexes
Beilstein Journal of Nanotechnology
aggregation
Förster resonance energy transfer
photosensitizer
semiconductor nanocrystals
tetrapyrroles
title The influence of phthalocyanine aggregation in complexes with CdSe/ZnS quantum dots on the photophysical properties of the complexes
title_full The influence of phthalocyanine aggregation in complexes with CdSe/ZnS quantum dots on the photophysical properties of the complexes
title_fullStr The influence of phthalocyanine aggregation in complexes with CdSe/ZnS quantum dots on the photophysical properties of the complexes
title_full_unstemmed The influence of phthalocyanine aggregation in complexes with CdSe/ZnS quantum dots on the photophysical properties of the complexes
title_short The influence of phthalocyanine aggregation in complexes with CdSe/ZnS quantum dots on the photophysical properties of the complexes
title_sort influence of phthalocyanine aggregation in complexes with cdse zns quantum dots on the photophysical properties of the complexes
topic aggregation
Förster resonance energy transfer
photosensitizer
semiconductor nanocrystals
tetrapyrroles
url https://doi.org/10.3762/bjnano.7.94
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