4,4′-([1,2,5]Thiadiazolo[3,4-<i>d</i>]pyridazine-4,7-diyl)bis(<i>N</i>,<i>N</i>-bis(4-methoxyphenyl)aniline)
Donor-acceptor-dyes with extended conjugation, such as D–π–A–π–D type, are being intensively investigated as components of near-infrared (NIR) organic light-emitting diodes (OLEDs). In this communication, novel D–π–A–π–D dye, 4,4′-([1,2,5]thiadiazolo[3,4-<i>d</i>]pyridazine-4,7-diyl)bis(...
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| Format: | Article |
| Language: | English |
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MDPI AG
2022-11-01
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| Series: | Molbank |
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| Online Access: | https://www.mdpi.com/1422-8599/2022/4/M1479 |
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| author | Timofey N. Chmovzh Timofey A. Kudryashev Oleg A. Rakitin |
| author_facet | Timofey N. Chmovzh Timofey A. Kudryashev Oleg A. Rakitin |
| author_sort | Timofey N. Chmovzh |
| collection | DOAJ |
| description | Donor-acceptor-dyes with extended conjugation, such as D–π–A–π–D type, are being intensively investigated as components of near-infrared (NIR) organic light-emitting diodes (OLEDs). In this communication, novel D–π–A–π–D dye, 4,4′-([1,2,5]thiadiazolo[3,4-<i>d</i>]pyridazine-4,7-diyl)bis(<i>N</i>,<i>N</i>-bis(4-methoxyphenyl)aniline), was synthesized by Stille cross-coupling reaction of 4,7-dibromo-[1,2,5]thiadiazolo[3,4-<i>d</i>]pyridazine. The structure of newly synthesized compounds was established by elemental analysis, high-resolution mass-spectrometry, <sup>1</sup>H, <sup>13</sup>C NMR, IR, and UV spectroscopy. The photophysical properties of the title compound were studied. |
| first_indexed | 2024-03-09T16:02:52Z |
| format | Article |
| id | doaj.art-08a2616a31424024b23c57eb30b870f7 |
| institution | Directory Open Access Journal |
| issn | 1422-8599 |
| language | English |
| last_indexed | 2024-03-09T16:02:52Z |
| publishDate | 2022-11-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molbank |
| spelling | doaj.art-08a2616a31424024b23c57eb30b870f72023-11-24T16:53:59ZengMDPI AGMolbank1422-85992022-11-0120224M147910.3390/M14794,4′-([1,2,5]Thiadiazolo[3,4-<i>d</i>]pyridazine-4,7-diyl)bis(<i>N</i>,<i>N</i>-bis(4-methoxyphenyl)aniline)Timofey N. Chmovzh0Timofey A. Kudryashev1Oleg A. Rakitin2N. D. Zelinsky Institute of Organic Chemistry Russian Academy of Sciences, 119991 Moscow, RussiaN. D. Zelinsky Institute of Organic Chemistry Russian Academy of Sciences, 119991 Moscow, RussiaN. D. Zelinsky Institute of Organic Chemistry Russian Academy of Sciences, 119991 Moscow, RussiaDonor-acceptor-dyes with extended conjugation, such as D–π–A–π–D type, are being intensively investigated as components of near-infrared (NIR) organic light-emitting diodes (OLEDs). In this communication, novel D–π–A–π–D dye, 4,4′-([1,2,5]thiadiazolo[3,4-<i>d</i>]pyridazine-4,7-diyl)bis(<i>N</i>,<i>N</i>-bis(4-methoxyphenyl)aniline), was synthesized by Stille cross-coupling reaction of 4,7-dibromo-[1,2,5]thiadiazolo[3,4-<i>d</i>]pyridazine. The structure of newly synthesized compounds was established by elemental analysis, high-resolution mass-spectrometry, <sup>1</sup>H, <sup>13</sup>C NMR, IR, and UV spectroscopy. The photophysical properties of the title compound were studied.https://www.mdpi.com/1422-8599/2022/4/M1479donor-acceptor molecules[1,2,5]thiadiazolo[3,4-<i>d</i>]pyridazinesStille cross-coupling reactionluminescent properties |
| spellingShingle | Timofey N. Chmovzh Timofey A. Kudryashev Oleg A. Rakitin 4,4′-([1,2,5]Thiadiazolo[3,4-<i>d</i>]pyridazine-4,7-diyl)bis(<i>N</i>,<i>N</i>-bis(4-methoxyphenyl)aniline) Molbank donor-acceptor molecules [1,2,5]thiadiazolo[3,4-<i>d</i>]pyridazines Stille cross-coupling reaction luminescent properties |
| title | 4,4′-([1,2,5]Thiadiazolo[3,4-<i>d</i>]pyridazine-4,7-diyl)bis(<i>N</i>,<i>N</i>-bis(4-methoxyphenyl)aniline) |
| title_full | 4,4′-([1,2,5]Thiadiazolo[3,4-<i>d</i>]pyridazine-4,7-diyl)bis(<i>N</i>,<i>N</i>-bis(4-methoxyphenyl)aniline) |
| title_fullStr | 4,4′-([1,2,5]Thiadiazolo[3,4-<i>d</i>]pyridazine-4,7-diyl)bis(<i>N</i>,<i>N</i>-bis(4-methoxyphenyl)aniline) |
| title_full_unstemmed | 4,4′-([1,2,5]Thiadiazolo[3,4-<i>d</i>]pyridazine-4,7-diyl)bis(<i>N</i>,<i>N</i>-bis(4-methoxyphenyl)aniline) |
| title_short | 4,4′-([1,2,5]Thiadiazolo[3,4-<i>d</i>]pyridazine-4,7-diyl)bis(<i>N</i>,<i>N</i>-bis(4-methoxyphenyl)aniline) |
| title_sort | 4 4 1 2 5 thiadiazolo 3 4 i d i pyridazine 4 7 diyl bis i n i i n i bis 4 methoxyphenyl aniline |
| topic | donor-acceptor molecules [1,2,5]thiadiazolo[3,4-<i>d</i>]pyridazines Stille cross-coupling reaction luminescent properties |
| url | https://www.mdpi.com/1422-8599/2022/4/M1479 |
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