Synthesis of Analcime Zeolite Using Al and Si from Waste Resources for the Removal of Pb/Cd Ions from Aqueous Solution

Zeolites, minerals with the formula Mx/n[AlO2]x(SiO2)y] zH2O, are environmentally friendly materials used as water treatment adsorbents, gas adsorbents, and petrochemical catalysts. This study used a mixture of aluminum black dross and waste glass to synthesize zeolites via a hydrothermal synthesis...

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Main Authors: Yubin Kang, Byoungyong Im, Jin-Ju Choi, Jin-Ho Yoon, Dae-Guen Kim
Format: Article
Language:English
Published: Polish Academy of Sciences 2022-02-01
Series:Archives of Metallurgy and Materials
Subjects:
Online Access:https://journals.pan.pl/Content/122507/PDF/AMM-2022-1-08-Kim.pdf
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author Yubin Kang
Byoungyong Im
Jin-Ju Choi
Jin-Ho Yoon
Dae-Guen Kim
author_facet Yubin Kang
Byoungyong Im
Jin-Ju Choi
Jin-Ho Yoon
Dae-Guen Kim
author_sort Yubin Kang
collection DOAJ
description Zeolites, minerals with the formula Mx/n[AlO2]x(SiO2)y] zH2O, are environmentally friendly materials used as water treatment adsorbents, gas adsorbents, and petrochemical catalysts. This study used a mixture of aluminum black dross and waste glass to synthesize zeolites via a hydrothermal synthesis and analyzed the effects of varying reaction time on phase changes under different synthesis conditions. With increased reaction times, a phase change from zeolite Na-P1 to analcime was observed; on employing hydrothermal synthesis at 150°C for 96 h, the majority of the crystalline structures changed into analcime. Heavy metal cation adsorption was tested to assess the applicability of the synthesized analcime to water treatment. Zeolite adsorption of at least 95% was observed for both Pd and Cd ions. Although a higher level of adsorption was observed for Pb ion than Cd ion, Cd ion was demonstrated to undergo relatively faster adsorption when tested under optimal pulp density at the same level of adsorption (95%).
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spelling doaj.art-08b8cc0e90604908bf4e8632f124d5e52022-12-22T03:41:46ZengPolish Academy of SciencesArchives of Metallurgy and Materials2300-19092022-02-01vol. 67No 16772https://doi.org/10.24425/amm.2022.137473Synthesis of Analcime Zeolite Using Al and Si from Waste Resources for the Removal of Pb/Cd Ions from Aqueous SolutionYubin Kang0https://orcid.org/0000-0002-4020-9840Byoungyong Im1https://orcid.org/0000-0002-5197-2702Jin-Ju Choi2https://orcid.org/0000-0002-0459-6476Jin-Ho Yoon3https://orcid.org/0000-0002-7247-0111Dae-Guen Kim4https://orcid.org/0000-0002-2861-8510Institute For Advanced Engineering, 17180, Goan-ro, 51 Beon-gil, Baegam-myeon, Cheoin-gu, Yongin-si, Gyeonggi-do, KoreaInstitute For Advanced Engineering, 17180, Goan-ro, 51 Beon-gil, Baegam-myeon, Cheoin-gu, Yongin-si, Gyeonggi-do, KoreaInstitute For Advanced Engineering, 17180, Goan-ro, 51 Beon-gil, Baegam-myeon, Cheoin-gu, Yongin-si, Gyeonggi-do, KoreaInstitute For Advanced Engineering, 17180, Goan-ro, 51 Beon-gil, Baegam-myeon, Cheoin-gu, Yongin-si, Gyeonggi-do, KoreaInstitute For Advanced Engineering, 17180, Goan-ro, 51 Beon-gil, Baegam-myeon, Cheoin-gu, Yongin-si, Gyeonggi-do, KoreaZeolites, minerals with the formula Mx/n[AlO2]x(SiO2)y] zH2O, are environmentally friendly materials used as water treatment adsorbents, gas adsorbents, and petrochemical catalysts. This study used a mixture of aluminum black dross and waste glass to synthesize zeolites via a hydrothermal synthesis and analyzed the effects of varying reaction time on phase changes under different synthesis conditions. With increased reaction times, a phase change from zeolite Na-P1 to analcime was observed; on employing hydrothermal synthesis at 150°C for 96 h, the majority of the crystalline structures changed into analcime. Heavy metal cation adsorption was tested to assess the applicability of the synthesized analcime to water treatment. Zeolite adsorption of at least 95% was observed for both Pd and Cd ions. Although a higher level of adsorption was observed for Pb ion than Cd ion, Cd ion was demonstrated to undergo relatively faster adsorption when tested under optimal pulp density at the same level of adsorption (95%).https://journals.pan.pl/Content/122507/PDF/AMM-2022-1-08-Kim.pdfzeoliteanalcimewaste resourcesrecyclingheavy metal removal
spellingShingle Yubin Kang
Byoungyong Im
Jin-Ju Choi
Jin-Ho Yoon
Dae-Guen Kim
Synthesis of Analcime Zeolite Using Al and Si from Waste Resources for the Removal of Pb/Cd Ions from Aqueous Solution
Archives of Metallurgy and Materials
zeolite
analcime
waste resources
recycling
heavy metal removal
title Synthesis of Analcime Zeolite Using Al and Si from Waste Resources for the Removal of Pb/Cd Ions from Aqueous Solution
title_full Synthesis of Analcime Zeolite Using Al and Si from Waste Resources for the Removal of Pb/Cd Ions from Aqueous Solution
title_fullStr Synthesis of Analcime Zeolite Using Al and Si from Waste Resources for the Removal of Pb/Cd Ions from Aqueous Solution
title_full_unstemmed Synthesis of Analcime Zeolite Using Al and Si from Waste Resources for the Removal of Pb/Cd Ions from Aqueous Solution
title_short Synthesis of Analcime Zeolite Using Al and Si from Waste Resources for the Removal of Pb/Cd Ions from Aqueous Solution
title_sort synthesis of analcime zeolite using al and si from waste resources for the removal of pb cd ions from aqueous solution
topic zeolite
analcime
waste resources
recycling
heavy metal removal
url https://journals.pan.pl/Content/122507/PDF/AMM-2022-1-08-Kim.pdf
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