[1,5-Bis(4-fluorophenyl)thiocarbazonato-κ2N5,S]phenylmercury(II) dichloromethane hemisolvate

[1,5-Bis(4-fluorophenyl)thiocarbazonato-κ2N5,S]phenylmercury(II) dichloromethane hemisolvate

In the title compound, [Hg(C6H5)(C13H9F2N4S)]·0.5CH2Cl2, the Hg(C6H5) units are twisted out of the planes of the thiocarbazonate ligands by 61.49 (10) and 67.79 (11)° in the two complex molecules comprising the asymmetric unit. Important geometri...

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Bibliographic Details
Main Authors: Karel G. von Eschwege, Fabian Muller, Alfred Muller
Format: Article
Language:English
Published: International Union of Crystallography 2011-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811050331
Description
Summary:In the title compound, [Hg(C6H5)(C13H9F2N4S)]·0.5CH2Cl2, the Hg(C6H5) units are twisted out of the planes of the thiocarbazonate ligands by 61.49 (10) and 67.79 (11)° in the two complex molecules comprising the asymmetric unit. Important geometrical parameters include Hg—C = 2.079 (4) and 2.087 (4) Å, Hg—S = 2.3869 (10) and 2.3889 (11) Å, and C—Hg—S = 166.42 (12) and 168.09 (13)°. Weak intramolecular Hg—N bonding interactions of 2.589 (4) and 2.626 (4) Å are observed. In the crystal, C—H...Cl, C—H...F, C—H...N, C—H...π and π–π [centroid–centroid distances = 3.648 (3) and 3.641 (3) Å] interactions, create parallel planes along [101].
ISSN:1600-5368

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