Chloridobis(2,9-diethoxy-1,10-phenanthroline-κ2N,N′)copper(II) perchlorate
In the title complex, [CuCl(C16H16N2O2)2]ClO4, the CuII ion is coordinated by four N atoms from two chelating 2,9-diethoxy-1,10-phenanthroline ligands and one chloride ion in a slightly disorted trigonal-bipyramidal environment. Two N atoms and the Cl atom are in equatorial positions while the remai...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-01-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053680804138X |
| _version_ | 1819002656787529728 |
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| author | Lei Meng Chao-Ling Feng Chun-Hong Kou Cao-Yuan Niu Xin-Sheng Wan |
| author_facet | Lei Meng Chao-Ling Feng Chun-Hong Kou Cao-Yuan Niu Xin-Sheng Wan |
| author_sort | Lei Meng |
| collection | DOAJ |
| description | In the title complex, [CuCl(C16H16N2O2)2]ClO4, the CuII ion is coordinated by four N atoms from two chelating 2,9-diethoxy-1,10-phenanthroline ligands and one chloride ion in a slightly disorted trigonal-bipyramidal environment. Two N atoms and the Cl atom are in equatorial positions while the remaining two N atoms occupy apical sites, the equatorial Cu—N bonds being significantly longer than the two apical Cu—N bonds. The N=C—O—C torsion angles involving the four ethoxy groups are in the range 161.5 (8) to 177.0 (5)°. In the crystal structure, there are significant π–π stacking interactions between inversion-related rings of phenanthroline groups with centroid–centroid distances in the range 3.649 (4)–3.790 (4) Å. |
| first_indexed | 2024-12-20T23:08:35Z |
| format | Article |
| id | doaj.art-08be05de5b484745b2382a47201909c5 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T23:08:35Z |
| publishDate | 2009-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-08be05de5b484745b2382a47201909c52022-12-21T19:23:47ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-01-01651m50m5010.1107/S160053680804138XChloridobis(2,9-diethoxy-1,10-phenanthroline-κ2N,N′)copper(II) perchlorateLei MengChao-Ling FengChun-Hong KouCao-Yuan NiuXin-Sheng WanIn the title complex, [CuCl(C16H16N2O2)2]ClO4, the CuII ion is coordinated by four N atoms from two chelating 2,9-diethoxy-1,10-phenanthroline ligands and one chloride ion in a slightly disorted trigonal-bipyramidal environment. Two N atoms and the Cl atom are in equatorial positions while the remaining two N atoms occupy apical sites, the equatorial Cu—N bonds being significantly longer than the two apical Cu—N bonds. The N=C—O—C torsion angles involving the four ethoxy groups are in the range 161.5 (8) to 177.0 (5)°. In the crystal structure, there are significant π–π stacking interactions between inversion-related rings of phenanthroline groups with centroid–centroid distances in the range 3.649 (4)–3.790 (4) Å.http://scripts.iucr.org/cgi-bin/paper?S160053680804138X |
| spellingShingle | Lei Meng Chao-Ling Feng Chun-Hong Kou Cao-Yuan Niu Xin-Sheng Wan Chloridobis(2,9-diethoxy-1,10-phenanthroline-κ2N,N′)copper(II) perchlorate Acta Crystallographica Section E |
| title | Chloridobis(2,9-diethoxy-1,10-phenanthroline-κ2N,N′)copper(II) perchlorate |
| title_full | Chloridobis(2,9-diethoxy-1,10-phenanthroline-κ2N,N′)copper(II) perchlorate |
| title_fullStr | Chloridobis(2,9-diethoxy-1,10-phenanthroline-κ2N,N′)copper(II) perchlorate |
| title_full_unstemmed | Chloridobis(2,9-diethoxy-1,10-phenanthroline-κ2N,N′)copper(II) perchlorate |
| title_short | Chloridobis(2,9-diethoxy-1,10-phenanthroline-κ2N,N′)copper(II) perchlorate |
| title_sort | chloridobis 2 9 diethoxy 1 10 phenanthroline 954 2n n 8242 copper ii perchlorate |
| url | http://scripts.iucr.org/cgi-bin/paper?S160053680804138X |
| work_keys_str_mv | AT leimeng chloridobis29diethoxy110phenanthroline9542nn8242copperiiperchlorate AT chaolingfeng chloridobis29diethoxy110phenanthroline9542nn8242copperiiperchlorate AT chunhongkou chloridobis29diethoxy110phenanthroline9542nn8242copperiiperchlorate AT caoyuanniu chloridobis29diethoxy110phenanthroline9542nn8242copperiiperchlorate AT xinshengwan chloridobis29diethoxy110phenanthroline9542nn8242copperiiperchlorate |