Fast elimination of emerging contaminates in complicated water environment medium over the resource conversion product of chicken manure biochar triggered by peroxymonosulfate
Abstract An innovative strategy for synthesizing novel dual-reaction-center (DRC) catalysts from chicken manure (CM) biochar to purify wastewater that contained emerging contaminants (ECs) is proposed to synchronously address the release of ECs and improper disposal of livestock manure. A series of...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
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Springer
2024-01-01
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| Series: | Carbon Research |
| Subjects: | |
| Online Access: | https://doi.org/10.1007/s44246-023-00096-8 |
| _version_ | 1797276235181588480 |
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| author | Yingtao Sun Yuting Gu Meiyi Li Hongqiang Wang Chun Hu Lai Lyu |
| author_facet | Yingtao Sun Yuting Gu Meiyi Li Hongqiang Wang Chun Hu Lai Lyu |
| author_sort | Yingtao Sun |
| collection | DOAJ |
| description | Abstract An innovative strategy for synthesizing novel dual-reaction-center (DRC) catalysts from chicken manure (CM) biochar to purify wastewater that contained emerging contaminants (ECs) is proposed to synchronously address the release of ECs and improper disposal of livestock manure. A series of characterization techniques reveal the formation of a special C-O-Ca bond bridge (cation-π) structure on resourcelized CM nanosheets (RCM NSs). RCM NSs exhibit distinct selectivity and anti-interference capability for various ECs removal in complex matrices, and the water purification system remains stable after 1735 hours (equivalent to 3470 cycles) of operation. Density Functional Tomography (DFT) calculations reveal that trace of peroxymonosulfate as an inducer initiates the continuous donation of electrons from electron-rich ECs and the C-O-Ca bond bridges provide a favorable pathway for electron transfer, which facilitates the electron capture effect of dissolved oxygen in the system. This study provides a novel strategy to convert livestock manure into DRC-catalysts for developing energy-saving and high-efficiency environmental remediation technologies. Graphical Abstract |
| first_indexed | 2024-03-07T15:25:25Z |
| format | Article |
| id | doaj.art-08c0e7462e13433daa1875ce2c50479c |
| institution | Directory Open Access Journal |
| issn | 2731-6696 |
| language | English |
| last_indexed | 2024-03-07T15:25:25Z |
| publishDate | 2024-01-01 |
| publisher | Springer |
| record_format | Article |
| series | Carbon Research |
| spelling | doaj.art-08c0e7462e13433daa1875ce2c50479c2024-03-05T17:07:05ZengSpringerCarbon Research2731-66962024-01-013111310.1007/s44246-023-00096-8Fast elimination of emerging contaminates in complicated water environment medium over the resource conversion product of chicken manure biochar triggered by peroxymonosulfateYingtao Sun0Yuting Gu1Meiyi Li2Hongqiang Wang3Chun Hu4Lai Lyu5Key Laboratory for Water Quality and Conservation of the Pearl River Delta, Ministry of Education, Institute of Environmental Research at Greater Bay, Guangzhou UniversityKey Laboratory for Water Quality and Conservation of the Pearl River Delta, Ministry of Education, Institute of Environmental Research at Greater Bay, Guangzhou UniversityKey Laboratory for Water Quality and Conservation of the Pearl River Delta, Ministry of Education, Institute of Environmental Research at Greater Bay, Guangzhou UniversityKey Laboratory for Water Quality and Conservation of the Pearl River Delta, Ministry of Education, Institute of Environmental Research at Greater Bay, Guangzhou UniversityKey Laboratory for Water Quality and Conservation of the Pearl River Delta, Ministry of Education, Institute of Environmental Research at Greater Bay, Guangzhou UniversityKey Laboratory for Water Quality and Conservation of the Pearl River Delta, Ministry of Education, Institute of Environmental Research at Greater Bay, Guangzhou UniversityAbstract An innovative strategy for synthesizing novel dual-reaction-center (DRC) catalysts from chicken manure (CM) biochar to purify wastewater that contained emerging contaminants (ECs) is proposed to synchronously address the release of ECs and improper disposal of livestock manure. A series of characterization techniques reveal the formation of a special C-O-Ca bond bridge (cation-π) structure on resourcelized CM nanosheets (RCM NSs). RCM NSs exhibit distinct selectivity and anti-interference capability for various ECs removal in complex matrices, and the water purification system remains stable after 1735 hours (equivalent to 3470 cycles) of operation. Density Functional Tomography (DFT) calculations reveal that trace of peroxymonosulfate as an inducer initiates the continuous donation of electrons from electron-rich ECs and the C-O-Ca bond bridges provide a favorable pathway for electron transfer, which facilitates the electron capture effect of dissolved oxygen in the system. This study provides a novel strategy to convert livestock manure into DRC-catalysts for developing energy-saving and high-efficiency environmental remediation technologies. Graphical Abstracthttps://doi.org/10.1007/s44246-023-00096-8Emerging contaminatsBiocharResource conversionPeroxymonosulfate triggerWater purification |
| spellingShingle | Yingtao Sun Yuting Gu Meiyi Li Hongqiang Wang Chun Hu Lai Lyu Fast elimination of emerging contaminates in complicated water environment medium over the resource conversion product of chicken manure biochar triggered by peroxymonosulfate Carbon Research Emerging contaminats Biochar Resource conversion Peroxymonosulfate trigger Water purification |
| title | Fast elimination of emerging contaminates in complicated water environment medium over the resource conversion product of chicken manure biochar triggered by peroxymonosulfate |
| title_full | Fast elimination of emerging contaminates in complicated water environment medium over the resource conversion product of chicken manure biochar triggered by peroxymonosulfate |
| title_fullStr | Fast elimination of emerging contaminates in complicated water environment medium over the resource conversion product of chicken manure biochar triggered by peroxymonosulfate |
| title_full_unstemmed | Fast elimination of emerging contaminates in complicated water environment medium over the resource conversion product of chicken manure biochar triggered by peroxymonosulfate |
| title_short | Fast elimination of emerging contaminates in complicated water environment medium over the resource conversion product of chicken manure biochar triggered by peroxymonosulfate |
| title_sort | fast elimination of emerging contaminates in complicated water environment medium over the resource conversion product of chicken manure biochar triggered by peroxymonosulfate |
| topic | Emerging contaminats Biochar Resource conversion Peroxymonosulfate trigger Water purification |
| url | https://doi.org/10.1007/s44246-023-00096-8 |
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