Rare-Earth Calcium Oxyborate Piezoelectric Crystals ReCa4O(BO3)3: Growth and Piezoelectric Characterizations

Rare-earth calcium oxyborate crystals, ReCa4O(BO3)3 (ReCOB, Re = Er, Y, Gd, Sm, Nd, Pr, and La ), are potential piezoelectric materials for ultrahigh temperature sensor applications, due to their high electrical resistivity at elevated temperature, high piezoelectric sensitivity and temperature stab...

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Main Authors: Fapeng Yu, Xiulan Duan, Shujun Zhang, Qingming Lu, Xian Zhao
Format: Article
Language:English
Published: MDPI AG 2014-07-01
Series:Crystals
Subjects:
Online Access:http://www.mdpi.com/2073-4352/4/3/241
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author Fapeng Yu
Xiulan Duan
Shujun Zhang
Qingming Lu
Xian Zhao
author_facet Fapeng Yu
Xiulan Duan
Shujun Zhang
Qingming Lu
Xian Zhao
author_sort Fapeng Yu
collection DOAJ
description Rare-earth calcium oxyborate crystals, ReCa4O(BO3)3 (ReCOB, Re = Er, Y, Gd, Sm, Nd, Pr, and La ), are potential piezoelectric materials for ultrahigh temperature sensor applications, due to their high electrical resistivity at elevated temperature, high piezoelectric sensitivity and temperature stability. In this paper, different techniques for ReCOB single-crystal growth are introduced, including the Bridgman and Czochralski pulling methods. Crystal orientations and the relationships between the crystallographic and physical axes of the monoclinic ReCOB crystals are discussed. The procedures for dielectric, elastic, electromechanical and piezoelectric property characterization, taking advantage of the impedance method, are presented. In addition, the maximum piezoelectric coefficients for different piezoelectric vibration modes are explored, and the optimized crystal cuts free of piezoelectric cross-talk are obtained by rotation calculations.
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spelling doaj.art-08c727ca6e3745b3b06b4024800deb862022-12-22T04:22:27ZengMDPI AGCrystals2073-43522014-07-014324126110.3390/cryst4030241cryst4030241Rare-Earth Calcium Oxyborate Piezoelectric Crystals ReCa4O(BO3)3: Growth and Piezoelectric CharacterizationsFapeng Yu0Xiulan Duan1Shujun Zhang2Qingming Lu3Xian Zhao4State Key Laboratory of Crystal Materials and Institute of Crystal Materials, Shandong University, Jinan 250100, Shandong, ChinaState Key Laboratory of Crystal Materials and Institute of Crystal Materials, Shandong University, Jinan 250100, Shandong, ChinaMaterials Research Institute, Pennsylvania State University, University Park, PA 16802, USASchool of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, Shandong, ChinaState Key Laboratory of Crystal Materials and Institute of Crystal Materials, Shandong University, Jinan 250100, Shandong, ChinaRare-earth calcium oxyborate crystals, ReCa4O(BO3)3 (ReCOB, Re = Er, Y, Gd, Sm, Nd, Pr, and La ), are potential piezoelectric materials for ultrahigh temperature sensor applications, due to their high electrical resistivity at elevated temperature, high piezoelectric sensitivity and temperature stability. In this paper, different techniques for ReCOB single-crystal growth are introduced, including the Bridgman and Czochralski pulling methods. Crystal orientations and the relationships between the crystallographic and physical axes of the monoclinic ReCOB crystals are discussed. The procedures for dielectric, elastic, electromechanical and piezoelectric property characterization, taking advantage of the impedance method, are presented. In addition, the maximum piezoelectric coefficients for different piezoelectric vibration modes are explored, and the optimized crystal cuts free of piezoelectric cross-talk are obtained by rotation calculations.http://www.mdpi.com/2073-4352/4/3/241ReCOB crystalscrystal growthdielectricpiezoelectricsensor
spellingShingle Fapeng Yu
Xiulan Duan
Shujun Zhang
Qingming Lu
Xian Zhao
Rare-Earth Calcium Oxyborate Piezoelectric Crystals ReCa4O(BO3)3: Growth and Piezoelectric Characterizations
Crystals
ReCOB crystals
crystal growth
dielectric
piezoelectric
sensor
title Rare-Earth Calcium Oxyborate Piezoelectric Crystals ReCa4O(BO3)3: Growth and Piezoelectric Characterizations
title_full Rare-Earth Calcium Oxyborate Piezoelectric Crystals ReCa4O(BO3)3: Growth and Piezoelectric Characterizations
title_fullStr Rare-Earth Calcium Oxyborate Piezoelectric Crystals ReCa4O(BO3)3: Growth and Piezoelectric Characterizations
title_full_unstemmed Rare-Earth Calcium Oxyborate Piezoelectric Crystals ReCa4O(BO3)3: Growth and Piezoelectric Characterizations
title_short Rare-Earth Calcium Oxyborate Piezoelectric Crystals ReCa4O(BO3)3: Growth and Piezoelectric Characterizations
title_sort rare earth calcium oxyborate piezoelectric crystals reca4o bo3 3 growth and piezoelectric characterizations
topic ReCOB crystals
crystal growth
dielectric
piezoelectric
sensor
url http://www.mdpi.com/2073-4352/4/3/241
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AT xiulanduan rareearthcalciumoxyboratepiezoelectriccrystalsreca4obo33growthandpiezoelectriccharacterizations
AT shujunzhang rareearthcalciumoxyboratepiezoelectriccrystalsreca4obo33growthandpiezoelectriccharacterizations
AT qingminglu rareearthcalciumoxyboratepiezoelectriccrystalsreca4obo33growthandpiezoelectriccharacterizations
AT xianzhao rareearthcalciumoxyboratepiezoelectriccrystalsreca4obo33growthandpiezoelectriccharacterizations