Pt1 enhanced C-H activation synergistic with Ptn catalysis for glycerol cascade oxidation to glyceric acid

The selective oxidation of glycerol to glyceric acid is an important value-added cascade catalytic process. Here the authors report a cascade synergistic catalysis strategy by atomic and low-coordinated cluster Pt on well-defined Cu-CuZrOx to simultaneously achieve high activity and selectivity.

Bibliographic Details
Main Authors: Zhe An, Zilong Zhang, Zeyu Huang, Hongbo Han, Binbin Song, Jian Zhang, Qi Ping, Yanru Zhu, Hongyan Song, Bin Wang, Lirong Zheng, Jing He
Format: Article
Language:English
Published: Nature Portfolio 2022-09-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-022-33038-w
_version_ 1811267540131774464
author Zhe An
Zilong Zhang
Zeyu Huang
Hongbo Han
Binbin Song
Jian Zhang
Qi Ping
Yanru Zhu
Hongyan Song
Bin Wang
Lirong Zheng
Jing He
author_facet Zhe An
Zilong Zhang
Zeyu Huang
Hongbo Han
Binbin Song
Jian Zhang
Qi Ping
Yanru Zhu
Hongyan Song
Bin Wang
Lirong Zheng
Jing He
author_sort Zhe An
collection DOAJ
description The selective oxidation of glycerol to glyceric acid is an important value-added cascade catalytic process. Here the authors report a cascade synergistic catalysis strategy by atomic and low-coordinated cluster Pt on well-defined Cu-CuZrOx to simultaneously achieve high activity and selectivity.
first_indexed 2024-04-12T21:04:20Z
format Article
id doaj.art-08c9b7d9cb424e2b9dc6113397ae79b3
institution Directory Open Access Journal
issn 2041-1723
language English
last_indexed 2024-04-12T21:04:20Z
publishDate 2022-09-01
publisher Nature Portfolio
record_format Article
series Nature Communications
spelling doaj.art-08c9b7d9cb424e2b9dc6113397ae79b32022-12-22T03:16:45ZengNature PortfolioNature Communications2041-17232022-09-0113111310.1038/s41467-022-33038-wPt1 enhanced C-H activation synergistic with Ptn catalysis for glycerol cascade oxidation to glyceric acidZhe An0Zilong Zhang1Zeyu Huang2Hongbo Han3Binbin Song4Jian Zhang5Qi Ping6Yanru Zhu7Hongyan Song8Bin Wang9Lirong Zheng10Jing He11State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical TechnologyState Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical TechnologyState Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical TechnologyState Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical TechnologyState Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical TechnologyState Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical TechnologyState Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical TechnologyState Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical TechnologyState Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical TechnologyBeijing Research Institute of Chemical Industry, Sinopec GroupTechnology Institute of High Energy Physics, Chinese Academy of SciencesState Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical TechnologyThe selective oxidation of glycerol to glyceric acid is an important value-added cascade catalytic process. Here the authors report a cascade synergistic catalysis strategy by atomic and low-coordinated cluster Pt on well-defined Cu-CuZrOx to simultaneously achieve high activity and selectivity.https://doi.org/10.1038/s41467-022-33038-w
spellingShingle Zhe An
Zilong Zhang
Zeyu Huang
Hongbo Han
Binbin Song
Jian Zhang
Qi Ping
Yanru Zhu
Hongyan Song
Bin Wang
Lirong Zheng
Jing He
Pt1 enhanced C-H activation synergistic with Ptn catalysis for glycerol cascade oxidation to glyceric acid
Nature Communications
title Pt1 enhanced C-H activation synergistic with Ptn catalysis for glycerol cascade oxidation to glyceric acid
title_full Pt1 enhanced C-H activation synergistic with Ptn catalysis for glycerol cascade oxidation to glyceric acid
title_fullStr Pt1 enhanced C-H activation synergistic with Ptn catalysis for glycerol cascade oxidation to glyceric acid
title_full_unstemmed Pt1 enhanced C-H activation synergistic with Ptn catalysis for glycerol cascade oxidation to glyceric acid
title_short Pt1 enhanced C-H activation synergistic with Ptn catalysis for glycerol cascade oxidation to glyceric acid
title_sort pt1 enhanced c h activation synergistic with ptn catalysis for glycerol cascade oxidation to glyceric acid
url https://doi.org/10.1038/s41467-022-33038-w
work_keys_str_mv AT zhean pt1enhancedchactivationsynergisticwithptncatalysisforglycerolcascadeoxidationtoglycericacid
AT zilongzhang pt1enhancedchactivationsynergisticwithptncatalysisforglycerolcascadeoxidationtoglycericacid
AT zeyuhuang pt1enhancedchactivationsynergisticwithptncatalysisforglycerolcascadeoxidationtoglycericacid
AT hongbohan pt1enhancedchactivationsynergisticwithptncatalysisforglycerolcascadeoxidationtoglycericacid
AT binbinsong pt1enhancedchactivationsynergisticwithptncatalysisforglycerolcascadeoxidationtoglycericacid
AT jianzhang pt1enhancedchactivationsynergisticwithptncatalysisforglycerolcascadeoxidationtoglycericacid
AT qiping pt1enhancedchactivationsynergisticwithptncatalysisforglycerolcascadeoxidationtoglycericacid
AT yanruzhu pt1enhancedchactivationsynergisticwithptncatalysisforglycerolcascadeoxidationtoglycericacid
AT hongyansong pt1enhancedchactivationsynergisticwithptncatalysisforglycerolcascadeoxidationtoglycericacid
AT binwang pt1enhancedchactivationsynergisticwithptncatalysisforglycerolcascadeoxidationtoglycericacid
AT lirongzheng pt1enhancedchactivationsynergisticwithptncatalysisforglycerolcascadeoxidationtoglycericacid
AT jinghe pt1enhancedchactivationsynergisticwithptncatalysisforglycerolcascadeoxidationtoglycericacid