Major element concentrations in Mangrove Pore Water, Sepetiba Bay, Brazil

Concentrations of cations and anions of major elements (Na+, Ca2+, Mg2+, K+, Cl-, SO4 2-) were analyzed in the pore water of a mangrove habitat. Site specific major element concentrations were identified along a four piezometric well transect, which were placed in distinct geobotanic facies. Evapotr...

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Main Authors: Christian J. Sanders, Renato G. S. Barcellos, Emmanoel V. Silva-Filho
Format: Article
Language:English
Published: Universidade de São Paulo 2012-03-01
Series:Brazilian Journal of Oceanography
Subjects:
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1679-87592012000100004
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author Christian J. Sanders
Renato G. S. Barcellos
Emmanoel V. Silva-Filho
author_facet Christian J. Sanders
Renato G. S. Barcellos
Emmanoel V. Silva-Filho
author_sort Christian J. Sanders
collection DOAJ
description Concentrations of cations and anions of major elements (Na+, Ca2+, Mg2+, K+, Cl-, SO4 2-) were analyzed in the pore water of a mangrove habitat. Site specific major element concentrations were identified along a four piezometric well transect, which were placed in distinct geobotanic facies. Evapotranspiration was evident in the apicum station, given the high salinity and major element concentrations. The station landward of an apicum was where major element/Cl- ratios standard deviations are greatest, suggesting intense in situ diagenesis. Molar ratios in the most continental station (4) are significantly lower than the nearby freshwater source, indicating a strong influence of sea water flux into the outer reaches of the mangrove ecosystem and encroaching on the Atlantic rain forest. Indeed, the SO4 2-/Cl- and Ca2+/Cl- ratios suggest limited SO4 2- reduction and relatively high Ca2+/Cl- ratios indicate a region of recent saltwater contact.<br>As concentrações dos elementos maiores (Na+, Ca2+, Mg2+, K+, Cl-, SO4(2-)) foram analisadas na água intersticial de poços piezométricos localizados em diferentes fácies geobotânicas ao longo de um transecto num ecossistema de manguezal na Baía de Sepetiba - Rio de Janeiro. Maiores salinidades e concentrações dos íons maiores são evidencias de evapotranspiração no fácies apicum. Ainda no apicum foram observados os maiores desvios padrão da razão elemento/Cl&#8722; durante o período do estudo, indicando intensa diagênese in situ. Razões molares no piezômetro, localizado na borda do manguezal foram consideravelmente menores do que a fonte de água doce, indicando forte influência do fluxo de água marinha. Os resultados das razões molares, SO4(2-)/Cl&#8722; e Ca2+/Cl&#8722; na borda do manguezal adjacente ao continente sugerem limitada redução de SO4(2-) enquanto os valores relativamente altos na razão Ca2+/Cl&#8722; indicam contacto recente com água marinha.
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spelling doaj.art-08f6c6a7e400447f9c5318c5e686b7ef2022-12-22T03:06:11ZengUniversidade de São PauloBrazilian Journal of Oceanography1679-87591982-436X2012-03-01601333910.1590/S1679-87592012000100004Major element concentrations in Mangrove Pore Water, Sepetiba Bay, BrazilChristian J. SandersRenato G. S. BarcellosEmmanoel V. Silva-FilhoConcentrations of cations and anions of major elements (Na+, Ca2+, Mg2+, K+, Cl-, SO4 2-) were analyzed in the pore water of a mangrove habitat. Site specific major element concentrations were identified along a four piezometric well transect, which were placed in distinct geobotanic facies. Evapotranspiration was evident in the apicum station, given the high salinity and major element concentrations. The station landward of an apicum was where major element/Cl- ratios standard deviations are greatest, suggesting intense in situ diagenesis. Molar ratios in the most continental station (4) are significantly lower than the nearby freshwater source, indicating a strong influence of sea water flux into the outer reaches of the mangrove ecosystem and encroaching on the Atlantic rain forest. Indeed, the SO4 2-/Cl- and Ca2+/Cl- ratios suggest limited SO4 2- reduction and relatively high Ca2+/Cl- ratios indicate a region of recent saltwater contact.<br>As concentrações dos elementos maiores (Na+, Ca2+, Mg2+, K+, Cl-, SO4(2-)) foram analisadas na água intersticial de poços piezométricos localizados em diferentes fácies geobotânicas ao longo de um transecto num ecossistema de manguezal na Baía de Sepetiba - Rio de Janeiro. Maiores salinidades e concentrações dos íons maiores são evidencias de evapotranspiração no fácies apicum. Ainda no apicum foram observados os maiores desvios padrão da razão elemento/Cl&#8722; durante o período do estudo, indicando intensa diagênese in situ. Razões molares no piezômetro, localizado na borda do manguezal foram consideravelmente menores do que a fonte de água doce, indicando forte influência do fluxo de água marinha. Os resultados das razões molares, SO4(2-)/Cl&#8722; e Ca2+/Cl&#8722; na borda do manguezal adjacente ao continente sugerem limitada redução de SO4(2-) enquanto os valores relativamente altos na razão Ca2+/Cl&#8722; indicam contacto recente com água marinha.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1679-87592012000100004EvapotranspiraçãoÁgua intersticialRazão Elemento Principal/ClDiagêneseEvapotranspirationGroundwaterMajor Element/Cl RatioDiagenesis
spellingShingle Christian J. Sanders
Renato G. S. Barcellos
Emmanoel V. Silva-Filho
Major element concentrations in Mangrove Pore Water, Sepetiba Bay, Brazil
Brazilian Journal of Oceanography
Evapotranspiração
Água intersticial
Razão Elemento Principal/Cl
Diagênese
Evapotranspiration
Groundwater
Major Element/Cl Ratio
Diagenesis
title Major element concentrations in Mangrove Pore Water, Sepetiba Bay, Brazil
title_full Major element concentrations in Mangrove Pore Water, Sepetiba Bay, Brazil
title_fullStr Major element concentrations in Mangrove Pore Water, Sepetiba Bay, Brazil
title_full_unstemmed Major element concentrations in Mangrove Pore Water, Sepetiba Bay, Brazil
title_short Major element concentrations in Mangrove Pore Water, Sepetiba Bay, Brazil
title_sort major element concentrations in mangrove pore water sepetiba bay brazil
topic Evapotranspiração
Água intersticial
Razão Elemento Principal/Cl
Diagênese
Evapotranspiration
Groundwater
Major Element/Cl Ratio
Diagenesis
url http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1679-87592012000100004
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