Potassium N-bromo-2-methylbenzenesulfonamidate sesquihydrate
In the structure of the title compound, K+·C7H7BrNO2S−·1.5H2O, the K+ ion is heptacoordinated by three O atoms from water molecules and by four sulfonyl O atoms of N-bromo-2-methylbenzenesulfonamide anions. The S—N distance of 1.577&#8197...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811025153 |
| _version_ | 1818959372481462272 |
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| author | B. Thimme Gowda Sabine Foro K. Shakuntala |
| author_facet | B. Thimme Gowda Sabine Foro K. Shakuntala |
| author_sort | B. Thimme Gowda |
| collection | DOAJ |
| description | In the structure of the title compound, K+·C7H7BrNO2S−·1.5H2O, the K+ ion is heptacoordinated by three O atoms from water molecules and by four sulfonyl O atoms of N-bromo-2-methylbenzenesulfonamide anions. The S—N distance of 1.577 (5) Å is consistent with an S=N double bond. The crystal structure comprises sheets in the ac plane which are further stabilized by O—H...Br and O—H...N hydrogen bonds. |
| first_indexed | 2024-12-20T11:40:36Z |
| format | Article |
| id | doaj.art-09119f95adfd43849701a8537b9c87a3 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T11:40:36Z |
| publishDate | 2011-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-09119f95adfd43849701a8537b9c87a32022-12-21T19:41:59ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-08-01678m1015m101510.1107/S1600536811025153Potassium N-bromo-2-methylbenzenesulfonamidate sesquihydrateB. Thimme GowdaSabine ForoK. ShakuntalaIn the structure of the title compound, K+·C7H7BrNO2S−·1.5H2O, the K+ ion is heptacoordinated by three O atoms from water molecules and by four sulfonyl O atoms of N-bromo-2-methylbenzenesulfonamide anions. The S—N distance of 1.577 (5) Å is consistent with an S=N double bond. The crystal structure comprises sheets in the ac plane which are further stabilized by O—H...Br and O—H...N hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536811025153 |
| spellingShingle | B. Thimme Gowda Sabine Foro K. Shakuntala Potassium N-bromo-2-methylbenzenesulfonamidate sesquihydrate Acta Crystallographica Section E |
| title | Potassium N-bromo-2-methylbenzenesulfonamidate sesquihydrate |
| title_full | Potassium N-bromo-2-methylbenzenesulfonamidate sesquihydrate |
| title_fullStr | Potassium N-bromo-2-methylbenzenesulfonamidate sesquihydrate |
| title_full_unstemmed | Potassium N-bromo-2-methylbenzenesulfonamidate sesquihydrate |
| title_short | Potassium N-bromo-2-methylbenzenesulfonamidate sesquihydrate |
| title_sort | potassium n bromo 2 methylbenzenesulfonamidate sesquihydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811025153 |
| work_keys_str_mv | AT bthimmegowda potassiumnbromo2methylbenzenesulfonamidatesesquihydrate AT sabineforo potassiumnbromo2methylbenzenesulfonamidatesesquihydrate AT kshakuntala potassiumnbromo2methylbenzenesulfonamidatesesquihydrate |