Solubilization of palladium in molten mixture of sodium borates and sodium carbonate

Solubility of palladium in water was enhanced by heating metallic palladium in a molten mixture of sodium borates and sodium carbonate at 1000 °C for 2 h. When 17Na2O − 83B2O3 was used as the sodium borate, 21% of palladium in the obtained product was extracted in water. The solubilization efficienc...

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Main Authors: Takashi Okada, Yoshiya Taniguchi, Fumihiro Nishimura, Susumu Yonezawa
Format: Article
Language:English
Published: Elsevier 2019-06-01
Series:Results in Physics
Online Access:http://www.sciencedirect.com/science/article/pii/S2211379719308551
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author Takashi Okada
Yoshiya Taniguchi
Fumihiro Nishimura
Susumu Yonezawa
author_facet Takashi Okada
Yoshiya Taniguchi
Fumihiro Nishimura
Susumu Yonezawa
author_sort Takashi Okada
collection DOAJ
description Solubility of palladium in water was enhanced by heating metallic palladium in a molten mixture of sodium borates and sodium carbonate at 1000 °C for 2 h. When 17Na2O − 83B2O3 was used as the sodium borate, 21% of palladium in the obtained product was extracted in water. The solubilization efficiencies differed depending on the chemical composition of the sodium borate. During the heat treatment, oxidation occurred on the palladium surface and the oxidized palladium dissolved in the media. Keywords: Solubilization, Palladium, Heat treatment
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spelling doaj.art-092354aab5324b4b84fbe79d321622b22022-12-22T02:44:53ZengElsevierResults in Physics2211-37972019-06-0113Solubilization of palladium in molten mixture of sodium borates and sodium carbonateTakashi Okada0Yoshiya Taniguchi1Fumihiro Nishimura2Susumu Yonezawa3Department of Materials Science and Engineering, Faculty of Engineering, University of Fukui, Bunkyo 3-9-1, Fukui 910-8507, Japan; Corresponding author.Department of Materials Science and Engineering, Faculty of Engineering, University of Fukui, Bunkyo 3-9-1, Fukui 910-8507, JapanHeadquarters for Innovative Society-Academic Cooperation, University of Fukui, Bunkyo 3-9-1, Fukui 910-8507, JapanHeadquarters for Innovative Society-Academic Cooperation, University of Fukui, Bunkyo 3-9-1, Fukui 910-8507, JapanSolubility of palladium in water was enhanced by heating metallic palladium in a molten mixture of sodium borates and sodium carbonate at 1000 °C for 2 h. When 17Na2O − 83B2O3 was used as the sodium borate, 21% of palladium in the obtained product was extracted in water. The solubilization efficiencies differed depending on the chemical composition of the sodium borate. During the heat treatment, oxidation occurred on the palladium surface and the oxidized palladium dissolved in the media. Keywords: Solubilization, Palladium, Heat treatmenthttp://www.sciencedirect.com/science/article/pii/S2211379719308551
spellingShingle Takashi Okada
Yoshiya Taniguchi
Fumihiro Nishimura
Susumu Yonezawa
Solubilization of palladium in molten mixture of sodium borates and sodium carbonate
Results in Physics
title Solubilization of palladium in molten mixture of sodium borates and sodium carbonate
title_full Solubilization of palladium in molten mixture of sodium borates and sodium carbonate
title_fullStr Solubilization of palladium in molten mixture of sodium borates and sodium carbonate
title_full_unstemmed Solubilization of palladium in molten mixture of sodium borates and sodium carbonate
title_short Solubilization of palladium in molten mixture of sodium borates and sodium carbonate
title_sort solubilization of palladium in molten mixture of sodium borates and sodium carbonate
url http://www.sciencedirect.com/science/article/pii/S2211379719308551
work_keys_str_mv AT takashiokada solubilizationofpalladiuminmoltenmixtureofsodiumboratesandsodiumcarbonate
AT yoshiyataniguchi solubilizationofpalladiuminmoltenmixtureofsodiumboratesandsodiumcarbonate
AT fumihironishimura solubilizationofpalladiuminmoltenmixtureofsodiumboratesandsodiumcarbonate
AT susumuyonezawa solubilizationofpalladiuminmoltenmixtureofsodiumboratesandsodiumcarbonate