Synthesis, Crystal Structure, and Catalytic Activity of a Calcium(II) Complex with 4-Formylbenzene-1,3-disulfonate-isonicotinic Acid Hydrazone
A new calcium(II) complex was synthesized by one-pot synthesis method from disodium 4-formylbenzene-1,3-disulfonate, isonicotinic acid hydrazide and Ca(ClO4)2•2H2O. The structure of calcium(II) complex was determined by elemental analysis, IR and single crystal X-ray diffraction. The results show th...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)
2018-12-01
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| Series: | Bulletin of Chemical Reaction Engineering & Catalysis |
| Subjects: | |
| Online Access: | https://journal.bcrec.id/index.php/bcrec/article/view/1961 |
| _version_ | 1811153884536635392 |
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| author | Xi-Shi Tai Peng-Fei Li Li-Li Liu |
| author_facet | Xi-Shi Tai Peng-Fei Li Li-Li Liu |
| author_sort | Xi-Shi Tai |
| collection | DOAJ |
| description | A new calcium(II) complex was synthesized by one-pot synthesis method from disodium 4-formylbenzene-1,3-disulfonate, isonicotinic acid hydrazide and Ca(ClO4)2•2H2O. The structure of calcium(II) complex was determined by elemental analysis, IR and single crystal X-ray diffraction. The results show that the Ca(II) complex molecules form 3D network structure by the interactions of π-π stacking and hydrogen bonds. The Ca(II) complex catalyst could efficiently catalyse oxidation of benzylic alcohol with good conversion of benzyl alcohol (78 %) and excellent selectivity of benzaldehyde (98 %). |
| first_indexed | 2024-03-11T22:50:21Z |
| format | Article |
| id | doaj.art-094854d2406a42f58f4365bd9e963f66 |
| institution | Directory Open Access Journal |
| issn | 1978-2993 |
| language | English |
| last_indexed | 2024-03-11T22:50:21Z |
| publishDate | 2018-12-01 |
| publisher | Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS) |
| record_format | Article |
| series | Bulletin of Chemical Reaction Engineering & Catalysis |
| spelling | doaj.art-094854d2406a42f58f4365bd9e963f662023-09-22T03:45:30ZengMasyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)Bulletin of Chemical Reaction Engineering & Catalysis1978-29932018-12-0113342943510.9767/bcrec.13.3.1961.429-4351435Synthesis, Crystal Structure, and Catalytic Activity of a Calcium(II) Complex with 4-Formylbenzene-1,3-disulfonate-isonicotinic Acid HydrazoneXi-Shi Tai0Peng-Fei Li1Li-Li Liu2College of Chemistry and Chemical Engineering, Weifang University, Weifang 261061, ChinaCollege of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266061, ChinaCollege of Chemistry and Chemical Engineering, Weifang University, Weifang 261061, ChinaA new calcium(II) complex was synthesized by one-pot synthesis method from disodium 4-formylbenzene-1,3-disulfonate, isonicotinic acid hydrazide and Ca(ClO4)2•2H2O. The structure of calcium(II) complex was determined by elemental analysis, IR and single crystal X-ray diffraction. The results show that the Ca(II) complex molecules form 3D network structure by the interactions of π-π stacking and hydrogen bonds. The Ca(II) complex catalyst could efficiently catalyse oxidation of benzylic alcohol with good conversion of benzyl alcohol (78 %) and excellent selectivity of benzaldehyde (98 %).https://journal.bcrec.id/index.php/bcrec/article/view/1961ca(ii) complex catalystsynthesisstructural characterizationcatalytic activity |
| spellingShingle | Xi-Shi Tai Peng-Fei Li Li-Li Liu Synthesis, Crystal Structure, and Catalytic Activity of a Calcium(II) Complex with 4-Formylbenzene-1,3-disulfonate-isonicotinic Acid Hydrazone Bulletin of Chemical Reaction Engineering & Catalysis ca(ii) complex catalyst synthesis structural characterization catalytic activity |
| title | Synthesis, Crystal Structure, and Catalytic Activity of a Calcium(II) Complex with 4-Formylbenzene-1,3-disulfonate-isonicotinic Acid Hydrazone |
| title_full | Synthesis, Crystal Structure, and Catalytic Activity of a Calcium(II) Complex with 4-Formylbenzene-1,3-disulfonate-isonicotinic Acid Hydrazone |
| title_fullStr | Synthesis, Crystal Structure, and Catalytic Activity of a Calcium(II) Complex with 4-Formylbenzene-1,3-disulfonate-isonicotinic Acid Hydrazone |
| title_full_unstemmed | Synthesis, Crystal Structure, and Catalytic Activity of a Calcium(II) Complex with 4-Formylbenzene-1,3-disulfonate-isonicotinic Acid Hydrazone |
| title_short | Synthesis, Crystal Structure, and Catalytic Activity of a Calcium(II) Complex with 4-Formylbenzene-1,3-disulfonate-isonicotinic Acid Hydrazone |
| title_sort | synthesis crystal structure and catalytic activity of a calcium ii complex with 4 formylbenzene 1 3 disulfonate isonicotinic acid hydrazone |
| topic | ca(ii) complex catalyst synthesis structural characterization catalytic activity |
| url | https://journal.bcrec.id/index.php/bcrec/article/view/1961 |
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