Chromium–niobium co-doped vanadium dioxide films: Large temperature coefficient of resistance and practically no thermal hysteresis of the metal–insulator transition

We investigated the effects of chromium (Cr) and niobium (Nb) co-doping on the temperature coefficient of resistance (TCR) and the thermal hysteresis of the metal–insulator transition of vanadium dioxide (VO2) films. We determined the TCR and thermal-hysteresis-width diagram of the V1−x−yCrxNbyO2 fi...

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Main Authors: Kenichi Miyazaki, Keisuke Shibuya, Megumi Suzuki, Kenichi Sakai, Jun-ichi Fujita, Akihito Sawa
Format: Article
Language:English
Published: AIP Publishing LLC 2016-05-01
Series:AIP Advances
Online Access:http://dx.doi.org/10.1063/1.4949757
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author Kenichi Miyazaki
Keisuke Shibuya
Megumi Suzuki
Kenichi Sakai
Jun-ichi Fujita
Akihito Sawa
author_facet Kenichi Miyazaki
Keisuke Shibuya
Megumi Suzuki
Kenichi Sakai
Jun-ichi Fujita
Akihito Sawa
author_sort Kenichi Miyazaki
collection DOAJ
description We investigated the effects of chromium (Cr) and niobium (Nb) co-doping on the temperature coefficient of resistance (TCR) and the thermal hysteresis of the metal–insulator transition of vanadium dioxide (VO2) films. We determined the TCR and thermal-hysteresis-width diagram of the V1−x−yCrxNbyO2 films by electrical-transport measurements and we found that the doping conditions x ≳ y and x + y ≥ 0.1 are appropriate for simultaneously realizing a large TCR value and an absence of thermal hysteresis in the films. By using these findings, we developed a V0.90Cr0.06Nb0.04O2 film grown on a TiO2-buffered SiO2/Si substrate that showed practically no thermal hysteresis while retaining a large TCR of 11.9%/K. This study has potential applications in the development of VO2-based uncooled bolometers.
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spelling doaj.art-096028ff29aa41b09960a132419785662022-12-21T18:23:26ZengAIP Publishing LLCAIP Advances2158-32262016-05-0165055012055012-710.1063/1.4949757037605ADVChromium–niobium co-doped vanadium dioxide films: Large temperature coefficient of resistance and practically no thermal hysteresis of the metal–insulator transitionKenichi Miyazaki0Keisuke Shibuya1Megumi Suzuki2Kenichi Sakai3Jun-ichi Fujita4Akihito Sawa5Denso Corporation, Aichi 470-0111, JapanNational Institute of Advanced Industrial Science and Technology (AIST), Tsukuba 305-8565, JapanDenso Corporation, Aichi 470-0111, JapanDenso Corporation, Aichi 470-0111, JapanUniversity of Tsukuba, Tsukuba 305-8571, JapanNational Institute of Advanced Industrial Science and Technology (AIST), Tsukuba 305-8565, JapanWe investigated the effects of chromium (Cr) and niobium (Nb) co-doping on the temperature coefficient of resistance (TCR) and the thermal hysteresis of the metal–insulator transition of vanadium dioxide (VO2) films. We determined the TCR and thermal-hysteresis-width diagram of the V1−x−yCrxNbyO2 films by electrical-transport measurements and we found that the doping conditions x ≳ y and x + y ≥ 0.1 are appropriate for simultaneously realizing a large TCR value and an absence of thermal hysteresis in the films. By using these findings, we developed a V0.90Cr0.06Nb0.04O2 film grown on a TiO2-buffered SiO2/Si substrate that showed practically no thermal hysteresis while retaining a large TCR of 11.9%/K. This study has potential applications in the development of VO2-based uncooled bolometers.http://dx.doi.org/10.1063/1.4949757
spellingShingle Kenichi Miyazaki
Keisuke Shibuya
Megumi Suzuki
Kenichi Sakai
Jun-ichi Fujita
Akihito Sawa
Chromium–niobium co-doped vanadium dioxide films: Large temperature coefficient of resistance and practically no thermal hysteresis of the metal–insulator transition
AIP Advances
title Chromium–niobium co-doped vanadium dioxide films: Large temperature coefficient of resistance and practically no thermal hysteresis of the metal–insulator transition
title_full Chromium–niobium co-doped vanadium dioxide films: Large temperature coefficient of resistance and practically no thermal hysteresis of the metal–insulator transition
title_fullStr Chromium–niobium co-doped vanadium dioxide films: Large temperature coefficient of resistance and practically no thermal hysteresis of the metal–insulator transition
title_full_unstemmed Chromium–niobium co-doped vanadium dioxide films: Large temperature coefficient of resistance and practically no thermal hysteresis of the metal–insulator transition
title_short Chromium–niobium co-doped vanadium dioxide films: Large temperature coefficient of resistance and practically no thermal hysteresis of the metal–insulator transition
title_sort chromium niobium co doped vanadium dioxide films large temperature coefficient of resistance and practically no thermal hysteresis of the metal insulator transition
url http://dx.doi.org/10.1063/1.4949757
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