Anchoring Tri(8-Quinolinolato)Iron Onto Sba-15 for Partial Oxidation of Benzyl Alcohol Using Water as the Solvent
Tri(8-quinolinolato)iron complex immobilized onto SBA-15 catalyst has been synthesized through a stepwise procedure. The characterization results indicated that the BET surface area, total pore volume and average pore width decrease after stepwise modification of SBA-15, while the structure keeps in...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Sciendo
2014-09-01
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| Series: | Polish Journal of Chemical Technology |
| Subjects: | |
| Online Access: | https://doi.org/10.2478/pjct-2014-0043 |
| _version_ | 1819115163112964096 |
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| author | Yang Xiaoyuan Liu Jing Kan Qiubin Guan Jingqi |
| author_facet | Yang Xiaoyuan Liu Jing Kan Qiubin Guan Jingqi |
| author_sort | Yang Xiaoyuan |
| collection | DOAJ |
| description | Tri(8-quinolinolato)iron complex immobilized onto SBA-15 catalyst has been synthesized through a stepwise procedure. The characterization results indicated that the BET surface area, total pore volume and average pore width decrease after stepwise modification of SBA-15, while the structure keeps intact. Catalytic tests showed that FeQ3-SBA-15 catalyzes the oxidation reaction well with 34.8% conversion of benzyl alcohol and 74.7% selectivity to benzaldehyde when water is used as the solvent after 1 h reaction. In addition, homogeneous catalyst tri(8-quinolinolato)iron exhibits very bad catalytic behavior using water as the solvent. |
| first_indexed | 2024-12-22T04:56:49Z |
| format | Article |
| id | doaj.art-0962bc1259fd46de9215b4b24d847c38 |
| institution | Directory Open Access Journal |
| issn | 1899-4741 |
| language | English |
| last_indexed | 2024-12-22T04:56:49Z |
| publishDate | 2014-09-01 |
| publisher | Sciendo |
| record_format | Article |
| series | Polish Journal of Chemical Technology |
| spelling | doaj.art-0962bc1259fd46de9215b4b24d847c382022-12-21T18:38:21ZengSciendoPolish Journal of Chemical Technology1899-47412014-09-01163121710.2478/pjct-2014-0043pjct-2014-0043Anchoring Tri(8-Quinolinolato)Iron Onto Sba-15 for Partial Oxidation of Benzyl Alcohol Using Water as the SolventYang Xiaoyuan0Liu Jing1Kan Qiubin2Guan Jingqi3Jilin University, Key Laboratory of Surface and Interface Chemistry of Jilin Province, College of Chemistry, Changchun, 130023, PR ChinaJilin University, Key Laboratory of Surface and Interface Chemistry of Jilin Province, College of Chemistry, Changchun, 130023, PR ChinaJilin University, Key Laboratory of Surface and Interface Chemistry of Jilin Province, College of Chemistry, Changchun, 130023, PR ChinaJilin University, Key Laboratory of Surface and Interface Chemistry of Jilin Province, College of Chemistry, Changchun, 130023, PR ChinaTri(8-quinolinolato)iron complex immobilized onto SBA-15 catalyst has been synthesized through a stepwise procedure. The characterization results indicated that the BET surface area, total pore volume and average pore width decrease after stepwise modification of SBA-15, while the structure keeps intact. Catalytic tests showed that FeQ3-SBA-15 catalyzes the oxidation reaction well with 34.8% conversion of benzyl alcohol and 74.7% selectivity to benzaldehyde when water is used as the solvent after 1 h reaction. In addition, homogeneous catalyst tri(8-quinolinolato)iron exhibits very bad catalytic behavior using water as the solvent.https://doi.org/10.2478/pjct-2014-0043sba-158-quinolinolironbenzyl alcoholbenzaldehyde |
| spellingShingle | Yang Xiaoyuan Liu Jing Kan Qiubin Guan Jingqi Anchoring Tri(8-Quinolinolato)Iron Onto Sba-15 for Partial Oxidation of Benzyl Alcohol Using Water as the Solvent Polish Journal of Chemical Technology sba-15 8-quinolinol iron benzyl alcohol benzaldehyde |
| title | Anchoring Tri(8-Quinolinolato)Iron Onto Sba-15 for Partial Oxidation of Benzyl Alcohol Using Water as the Solvent |
| title_full | Anchoring Tri(8-Quinolinolato)Iron Onto Sba-15 for Partial Oxidation of Benzyl Alcohol Using Water as the Solvent |
| title_fullStr | Anchoring Tri(8-Quinolinolato)Iron Onto Sba-15 for Partial Oxidation of Benzyl Alcohol Using Water as the Solvent |
| title_full_unstemmed | Anchoring Tri(8-Quinolinolato)Iron Onto Sba-15 for Partial Oxidation of Benzyl Alcohol Using Water as the Solvent |
| title_short | Anchoring Tri(8-Quinolinolato)Iron Onto Sba-15 for Partial Oxidation of Benzyl Alcohol Using Water as the Solvent |
| title_sort | anchoring tri 8 quinolinolato iron onto sba 15 for partial oxidation of benzyl alcohol using water as the solvent |
| topic | sba-15 8-quinolinol iron benzyl alcohol benzaldehyde |
| url | https://doi.org/10.2478/pjct-2014-0043 |
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