Highly Diastereoselective Chelation-Controlled 1,3-<i>anti</i>-Allylation of (<i>S</i>)-3-(Methoxymethyl)hexanal Enabled by Hydrate of Scandium Triflate
En route to the total synthesis of (+)-Neopeltolide, we explored Lewis acid-assisted diastereoselective allylation of MOM-protected 3-hydroxylhexanal with β-(2,2-diethoxyethyl)-substituted (allyl)tributylstannane. The hydrated form of scandium triflate was found to be essential for attaining high 1,...
Main Authors: | Uladzimir S. Masiuk, Iryna V. Mineyeva, Dzmitry G. Kananovich |
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Format: | Article |
Language: | English |
Published: |
MDPI AG
2021-03-01
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Series: | Symmetry |
Subjects: | |
Online Access: | https://www.mdpi.com/2073-8994/13/3/470 |
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